IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v199y2022icp157-168.html
   My bibliography  Save this article

Brewer's spent grain pyrolysis kinetics and evolved gas analysis for the sustainable phenolic compounds and fatty acids recovery potential

Author

Listed:
  • Sobek, S.
  • Zeng, K.
  • Werle, S.
  • Junga, R.
  • Sajdak, M.

Abstract

Within the presented paper, a thermochemical conversion via pyrolysis of spent grain from the local brewery (Alternatywa, Ruda Śląska, Poland) for phenolic compounds and fatty acids recovery is presented. Thermogravimetric pyrolysis was carried out at non-isothermal conditions (1, 2, and 4 K/min), under an inert N2 atmosphere. Deconvolution procedure for the kinetic modeling was implemented using own algorithm based on Gaussian function, using 3-stage kinetic mechanism, ascribed to the independent decomposition of the pseudo-components i.e., hemicellulose, cellulose, and bulk lignin-extractives. Released volatiles during pyrolysis was evaluated and recognized using gas chromatography-mass spectrometry and Fourier-transform infrared spectroscopy analysis, which confirmed the high content of fatty acids, phenolic compounds, and nitrogen compounds, with shares of 23.95%, 13.94%, and 25.10% respectively. Linkage of the desired product formations to the modeled kinetic stages of the BSG pyrolysis is a complex subject, and it is encouraged for future studies.

Suggested Citation

  • Sobek, S. & Zeng, K. & Werle, S. & Junga, R. & Sajdak, M., 2022. "Brewer's spent grain pyrolysis kinetics and evolved gas analysis for the sustainable phenolic compounds and fatty acids recovery potential," Renewable Energy, Elsevier, vol. 199(C), pages 157-168.
    • Handle: RePEc:eee:renene:v:199:y:2022:i:c:p:157-168
    DOI: 10.1016/j.renene.2022.08.114
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122012897
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.08.114?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Zeng, Kuo & Li, Rui & Minh, Doan Pham & Weiss-Hortala, Elsa & Nzihou, Ange & Zhong, Dian & Flamant, Gilles, 2020. "Characterization of char generated from solar pyrolysis of heavy metal contaminated biomass," Energy, Elsevier, vol. 206(C).
    2. Bach, Quang-Vu & Tran, Khanh-Quang & Skreiberg, Øyvind & Trinh, Thuat T., 2015. "Effects of wet torrefaction on pyrolysis of woody biomass fuels," Energy, Elsevier, vol. 88(C), pages 443-456.
    3. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba-Rec, Izabela & Szymańska-Chargot, Monika, 2020. "Upgrading of green waste into carbon-rich solid biofuel by hydrothermal carbonization: The effect of process parameters on hydrochar derived from acacia," Energy, Elsevier, vol. 202(C).
    4. Wickramaarachchi, W.A.M.K.P. & Narayana, Mahinsasa, 2020. "Pyrolysis of single biomass particle using three-dimensional Computational Fluid Dynamics modelling," Renewable Energy, Elsevier, vol. 146(C), pages 1153-1165.
    5. Artur Bieniek & Wojciech Jerzak & Małgorzata Sieradzka & Łukasz Mika & Karol Sztekler & Aneta Magdziarz, 2022. "Intermediate Pyrolysis of Brewer’s Spent Grain: Impact of Gas Atmosphere," Energies, MDPI, vol. 15(7), pages 1-17, March.
    6. Sobek, Szymon & Werle, Sebastian, 2020. "Isoconversional determination of the apparent reaction models governing pyrolysis of wood, straw and sewage sludge, with an approach to rate modelling," Renewable Energy, Elsevier, vol. 161(C), pages 972-987.
    7. Zhang, Xianwen & Deng, Hongkun & Yang, Jing & Yu, Zhenhua & Xing, Xianjun & Ma, Peiyong, 2020. "Isoconversional kinetics of pyrolysis of vaporthermally carbonized bamboo," Renewable Energy, Elsevier, vol. 149(C), pages 701-707.
    8. Dessì, Federica & Mureddu, Mauro & Ferrara, Francesca & Pettinau, Alberto, 2022. "A comprehensive pathway on the determination of the kinetic triplet and the reaction mechanism of brewer's spent grain and beech wood chips pyrolysis," Renewable Energy, Elsevier, vol. 190(C), pages 548-559.
    9. Sobek, Szymon & Werle, Sebastian, 2020. "Solar pyrolysis of waste biomass: Part 2 kinetic modeling and methodology of the determination of the kinetic parameters for solar pyrolysis of sewage sludge," Renewable Energy, Elsevier, vol. 153(C), pages 962-974.
    10. Dessì, Federica & Mureddu, Mauro & Ferrara, Francesca & Fermoso, Javier & Orsini, Alessandro & Sanna, Aimaro & Pettinau, Alberto, 2021. "Thermogravimetric characterisation and kinetic analysis of Nannochloropsis sp. and Tetraselmis sp. microalgae for pyrolysis, combustion and oxy-combustion," Energy, Elsevier, vol. 217(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liborio, Denisson O. & Arias, Santiago & Mumbach, Guilherme D. & Alves, José Luiz F. & da Silva, Jean C.G. & Silva, Jose Marcos F. & Frety, Roger & Pacheco, Jose Geraldo A., 2024. "Evaluating black wattle bark industrial residue as a new feedstock for bioenergy via pyrolysis and multicomponent kinetic modeling," Renewable Energy, Elsevier, vol. 228(C).
    2. Mlonka-Mędrala, Agata & Sobek, Szymon & Wądrzyk, Mariusz & Werle, Sebastian & Ionescu, Gabriela & Mărculescu, Cosmin & Magdziarz, Aneta, 2025. "Energy and material recovery from bone waste: Steam gasification for biochar and syngas production in a circular economy framework," Energy, Elsevier, vol. 325(C).
    3. Jerzak, Wojciech & Wądrzyk, Mariusz & Kalemba-Rec, Izabela & Bieniek, Artur & Magdziarz, Aneta, 2023. "Release of chlorine during oat straw pyrolysis doped with char and ammonium chloride," Renewable Energy, Elsevier, vol. 215(C).
    4. Sobek, Szymon & Schmölzer, Stefan & Mumtaz, Hamza & Sajdak, Marcin & Muzyka, Roksana & Werle, Sebastian, 2025. "Kinetic study of the decommissioned wind turbine blade oxidative liquefaction based on differential scanning calorimetry," Energy, Elsevier, vol. 316(C).
    5. Junga, Robert & Sobek, Szymon & Mizerna, Kamila & Wzorek, Małgorzata & Moskal-Zaucha, Hanna & Wróbel-Iwaniec, Iwona, 2024. "Evaluation of the reactivity of co-combustion of wheat straw and waste rubber thermolysis char," Renewable Energy, Elsevier, vol. 237(PB).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mlonka-Mędrala, Agata & Sobek, Szymon & Wądrzyk, Mariusz & Werle, Sebastian & Ionescu, Gabriela & Mărculescu, Cosmin & Magdziarz, Aneta, 2025. "Energy and material recovery from bone waste: Steam gasification for biochar and syngas production in a circular economy framework," Energy, Elsevier, vol. 325(C).
    2. Zheng, Kaiyue & Hu, Song & Gong, Zhijie & Jia, Mengchuan & Xu, Kai & Xu, Jun & Jiang, Long & Wang, Yi & Su, Sheng & Xiang, Jun, 2025. "Interaction among cellulose, hemicellulose and lignin during pressurized pyrolysis: Importance of deoxygenation and aromatization reactions," Energy, Elsevier, vol. 314(C).
    3. Kaczor, Zuzanna & Buliński, Zbigniew & Werle, Sebastian, 2020. "Modelling approaches to waste biomass pyrolysis: a review," Renewable Energy, Elsevier, vol. 159(C), pages 427-443.
    4. Bartłomiej Igliński & Wojciech Kujawski & Urszula Kiełkowska, 2023. "Pyrolysis of Waste Biomass: Technical and Process Achievements, and Future Development—A Review," Energies, MDPI, vol. 16(4), pages 1-26, February.
    5. Wang, Xin & Jin, Xiaodong & Wang, Hui & Wang, Yi & Zuo, Lu & Shen, Boxiong & Yang, Jiancheng, 2023. "Catalytic pyrolysis of microalgal lipids to liquid biofuels: Metal oxide doped catalysts with hierarchically porous structure and their performance," Renewable Energy, Elsevier, vol. 212(C), pages 887-896.
    6. Śliz, Maciej & Wilk, Małgorzata, 2020. "A comprehensive investigation of hydrothermal carbonization: Energy potential of hydrochar derived from Virginia mallow," Renewable Energy, Elsevier, vol. 156(C), pages 942-950.
    7. Ong, Mei Yin & Milano, Jassinnee & Nomanbhay, Saifuddin & Palanisamy, Kumaran & Tan, Yeong Hwang & Ong, Hwai Chyuan, 2025. "Insights into algae-plastic pyrolysis: Thermogravimetric and kinetic approaches for renewable energy," Energy, Elsevier, vol. 314(C).
    8. Jaime Martín-Pascual & Joaquín Jódar & Miguel L. Rodríguez & Montserrat Zamorano, 2020. "Determination of the Optimal Operative Conditions for the Torrefaction of Olive Waste Biomass," Sustainability, MDPI, vol. 12(16), pages 1-11, August.
    9. Luo, Laipeng & Zhang, Zhiyi & Li, Chong & Nishu, & He, Fang & Zhang, Xingguang & Cai, Junmeng, 2021. "Insight into master plots method for kinetic analysis of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 233(C).
    10. Kostyniuk, Andrii & Likozar, Blaž, 2024. "Wet torrefaction of biomass waste into high quality hydrochar and value-added liquid products using different zeolite catalysts," Renewable Energy, Elsevier, vol. 227(C).
    11. Cardarelli, Alessandro & Pinzi, Sara & Barbanera, Marco, 2022. "Effect of torrefaction temperature on spent coffee grounds thermal behaviour and kinetics," Renewable Energy, Elsevier, vol. 185(C), pages 704-716.
    12. Magdziarz, Aneta & Mlonka-Mędrala, Agata & Sieradzka, Małgorzata & Aragon-Briceño, Christian & Pożarlik, Artur & Bramer, Eddy A. & Brem, Gerrit & Niedzwiecki, Łukasz & Pawlak-Kruczek, Halina, 2021. "Multiphase analysis of hydrochars obtained by anaerobic digestion of municipal solid waste organic fraction," Renewable Energy, Elsevier, vol. 175(C), pages 108-118.
    13. Gao, Qi & Ni, Liangmeng & He, Yuyu & Hou, Yanmei & Hu, Wanhe & Liu, Zhijia, 2022. "Effect of hydrothermal pretreatment on deashing and pyrolysis characteristics of bamboo shoot shells," Energy, Elsevier, vol. 247(C).
    14. Sun, Ce & Li, Wenlong & Chen, Xiaojian & Li, Changxin & Tan, Haiyan & Zhang, Yanhua, 2021. "Synergistic interactions for saving energy and promoting the co-pyrolysis of polylactic acid and wood flour," Renewable Energy, Elsevier, vol. 171(C), pages 254-265.
    15. Liang, Wang & Wang, Guangwei & Xu, Runsheng & Ning, Xiaojun & Zhang, Jianliang & Guo, Xingmin & Ye, Lian & Li, Jinhua & Jiang, Chunhe & Wang, Peng & Wang, Chuan, 2022. "Hydrothermal carbonization of forest waste into solid fuel: Mechanism and combustion behavior," Energy, Elsevier, vol. 246(C).
    16. Inamullah Mian & Noor Rehman & Xian Li & Hidayat Ullah & Abbas Khan & Chaejin Choi & Changseok Han, 2024. "Effect of Heating Rate on the Pyrolysis Behavior and Kinetics of Coconut Residue and Activated Carbon: A Comparative Study," Energies, MDPI, vol. 17(18), pages 1-11, September.
    17. Pambudi, Suluh & Jongyingcharoen, Jiraporn Sripinyowanich & Saechua, Wanphut, 2025. "Explainable machine learning for predicting thermogravimetric analysis of oxidatively torrefied spent coffee grounds combustion," Energy, Elsevier, vol. 320(C).
    18. Hamed, A.S.A. & Yusof, N.I.F.M. & Yahya, M.S. & Cardozo, E. & Munajat, N.F., 2023. "Concentrated solar pyrolysis for oil palm biomass: An exploratory review within the Malaysian context," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    19. Czerwińska, Klaudia & Śliz, Maciej & Wilk, Małgorzata, 2022. "Hydrothermal carbonization process: Fundamentals, main parameter characteristics and possible applications including an effective method of SARS-CoV-2 mitigation in sewage sludge. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    20. Przemysław Rajca & Andrzej Skibiński & Anna Biniek-Poskart & Monika Zajemska, 2022. "Review of Selected Determinants Affecting Use of Municipal Waste for Energy Purposes," Energies, MDPI, vol. 15(23), pages 1-17, November.

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:199:y:2022:i:c:p:157-168. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.