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Insights into algae-plastic pyrolysis: Thermogravimetric and kinetic approaches for renewable energy

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  • Ong, Mei Yin
  • Milano, Jassinnee
  • Nomanbhay, Saifuddin
  • Palanisamy, Kumaran
  • Tan, Yeong Hwang
  • Ong, Hwai Chyuan

Abstract

With the rising demand for sustainable energy, biomass pyrolysis has gained significant attention. This study investigates the pyrolytic and kinetic characteristics of Chaetomorpha sp. Algae, three types of plastic waste—polypropylene (PP), high-density polyethylene (HDPE), and polyethylene terephthalate (PET)—and their blends as co-feedstocks. Thermogravimetric analysis (TGA) and the Coats-Redfern kinetic model were utilized to evaluate thermal behavior, synergistic effects, and activation energy. This study is crucial for successful experimental design, facilitating commercial scale-up, and ensuring efficient biomass utilization. Results revealed significant synergistic effects between algae and plastic feedstocks, with mass loss improvements of up to 48.35 % and heating value enhancements of up to 17.53 %. The interaction between feedstocks optimized thermal decomposition and improved energy output, with stronger synergistic effects observed when the degradation temperature ranges of the feedstocks were closely aligned, in which PP > HDPE > PET. This insight serves as a guideline for selecting optimal co-feedstocks in future experiments although further verification is needed by using other feedstocks. Moreover, the addition of plastic waste increased the highest activation energy from 29 kJ/mol to 44 kJ/mol, a value still lower than that of most terrestrial biomass and pure plastics, highlighting the potential of algae-plastic blends for producing biofuel and biopolymer. In conclusion, integrating macroalgae and plastic waste in pyrolysis presents a promising pathway for sustainable energy and waste management, offering valuable insights for scientists and researchers in the field of sustainable energy and environmental sustainability toward net-zero emissions.

Suggested Citation

  • Ong, Mei Yin & Milano, Jassinnee & Nomanbhay, Saifuddin & Palanisamy, Kumaran & Tan, Yeong Hwang & Ong, Hwai Chyuan, 2025. "Insights into algae-plastic pyrolysis: Thermogravimetric and kinetic approaches for renewable energy," Energy, Elsevier, vol. 314(C).
    • Handle: RePEc:eee:energy:v:314:y:2025:i:c:s0360544224041008
    DOI: 10.1016/j.energy.2024.134322
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    1. Saddam H. Al-lwayzy & Talal Yusaf, 2013. "Chlorella protothecoides Microalgae as an Alternative Fuel for Tractor Diesel Engines," Energies, MDPI, vol. 6(2), pages 1-18, February.
    2. Wang, Qian & Wang, Rui & Li, Zixuan & Zhao, Yanhua & Cao, Qiankun & Han, Feifei & Gao, Yuze, 2024. "Kinetic, thermodynamic and artificial neural network prediction studies on co-pyrolysis of the agricultural waste and algae," Renewable Energy, Elsevier, vol. 233(C).
    3. Milano, Jassinnee & Ong, Hwai Chyuan & Masjuki, H.H. & Chong, W.T. & Lam, Man Kee & Loh, Ping Kwan & Vellayan, Viknes, 2016. "Microalgae biofuels as an alternative to fossil fuel for power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 180-197.
    4. Wen, Yuming & Zaini, Ilman Nuran & Wang, Shule & Mu, Wangzhong & Jönsson, Pär Göran & Yang, Weihong, 2021. "Synergistic effect of the co-pyrolysis of cardboard and polyethylene: A kinetic and thermodynamic study," Energy, Elsevier, vol. 229(C).
    5. Zhou, Limin & Zou, Hongbin & Wang, Yun & Le, Zhanggao & Liu, Zhirong & Adesina, Adesoji A., 2017. "Effect of potassium on thermogravimetric behavior and co-pyrolytic kinetics of wood biomass and low density polyethylene," Renewable Energy, Elsevier, vol. 102(PA), pages 134-141.
    6. Leni Maulinda & Husni Husin & Nasrul Arahman & Cut Meurah Rosnelly & Muhammad Syukri & Nurhazanah & Fahrizal Nasution & Ahmadi, 2023. "The Influence of Pyrolysis Time and Temperature on the Composition and Properties of Bio-Oil Prepared from Tanjong Leaves ( Mimusops elengi )," Sustainability, MDPI, vol. 15(18), pages 1-17, September.
    7. Kumar, Akash & Yan, Beibei & Tao, Junyu & Li, Jian & Kumari, Lata & Oba, Belay Tafa & Aborisade, Moses Akintayo & Chen, Guanyi, 2022. "Influence of waste plastic on pyrolysis of low-lipid microalgae: A study on thermokinetics, behaviors, evolved gas characteristics, and products distribution," Renewable Energy, Elsevier, vol. 185(C), pages 416-430.
    8. Burra, K.G. & Gupta, A.K., 2018. "Kinetics of synergistic effects in co-pyrolysis of biomass with plastic wastes," Applied Energy, Elsevier, vol. 220(C), pages 408-418.
    9. Rizzo, Andrea Maria & Prussi, Matteo & Bettucci, Lorenzo & Libelli, Ilaria Marsili & Chiaramonti, David, 2013. "Characterization of microalga Chlorella as a fuel and its thermogravimetric behavior," Applied Energy, Elsevier, vol. 102(C), pages 24-31.
    10. Meng Jiang & Yuheng Cao & Changgong Liu & Dingjiang Chen & Wenji Zhou & Qian Wen & Hejiang Yu & Jian Jiang & Yucheng Ren & Shanying Hu & Edgar Hertwich & Bing Zhu, 2024. "Tracing fossil-based plastics, chemicals and fertilizers production in China," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    11. Hassan, H. & Hameed, B.H. & Lim, J.K., 2020. "Co-pyrolysis of sugarcane bagasse and waste high-density polyethylene: Synergistic effect and product distributions," Energy, Elsevier, vol. 191(C).
    12. Irena Wojnowska-Baryła & Katarzyna Bernat & Magdalena Zaborowska, 2022. "Plastic Waste Degradation in Landfill Conditions: The Problem with Microplastics, and Their Direct and Indirect Environmental Effects," IJERPH, MDPI, vol. 19(20), pages 1-15, October.
    13. Stančin, H. & Mikulčić, H. & Manić, N. & Stojiljiković, D. & Vujanović, M. & Wang, X. & Duić, N., 2021. "Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis," Energy, Elsevier, vol. 237(C).
    14. Dessì, Federica & Mureddu, Mauro & Ferrara, Francesca & Fermoso, Javier & Orsini, Alessandro & Sanna, Aimaro & Pettinau, Alberto, 2021. "Thermogravimetric characterisation and kinetic analysis of Nannochloropsis sp. and Tetraselmis sp. microalgae for pyrolysis, combustion and oxy-combustion," Energy, Elsevier, vol. 217(C).
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