IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v15y2023i18p13851-d1242146.html
   My bibliography  Save this article

The Influence of Pyrolysis Time and Temperature on the Composition and Properties of Bio-Oil Prepared from Tanjong Leaves ( Mimusops elengi )

Author

Listed:
  • Leni Maulinda

    (Postgraduate School of Engineering Studies, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Department of Chemical Engineering, Faculty of Engineering, Universitas Malikussaleh, Lhokseumawe 24355, Indonesia)

  • Husni Husin

    (Postgraduate School of Engineering Studies, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Reaction Engineering and Catalysis Laboratory, Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)

  • Nasrul Arahman

    (Postgraduate School of Engineering Studies, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)

  • Cut Meurah Rosnelly

    (Postgraduate School of Engineering Studies, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)

  • Muhammad Syukri

    (Department of Physics Education, Faculty of Teacher Training and Education, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)

  • Nurhazanah

    (Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Reaction Engineering and Catalysis Laboratory, Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)

  • Fahrizal Nasution

    (Postgraduate School of Engineering Studies, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Reaction Engineering and Catalysis Laboratory, Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)

  • Ahmadi

    (Postgraduate School of Engineering Studies, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
    Reaction Engineering and Catalysis Laboratory, Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)

Abstract

This research aims to evaluate the influence of pyrolysis time and temperature on the composition and properties of bio-oil derived from Mimusops elengi . Experiments were conducted by varying the pyrolysis temperature and time from 400 to 600 °C and 30 to 120 min, respectively. Both pyrolysis temperature and time were found to significantly influence the bio-oil composition. At enhanced pyrolysis temperatures, the bio-oil yield increased while the ash and gas yields decreased. In addition, extended pyrolysis time produced a greater bio-oil yield, indicating that higher temperatures and longer durations promote additional decomposition of biomass. Functional groupings, including alcohols, phenols, ketones, esters, and aromatic compounds in the bio-oil, were identified via FT-IR analysis, indicating that the bio-oil’s diversified chemical properties make it a potential alternative feedstock. GC-MS analysis identified 26 chemical compounds in the bio-oil, of which phenol was the most abundant. However, a high phenol content can diminish bio-oil quality by enhancing acidity, decreasing heating value, and encouraging engine corrosion. Temperature and pyrolysis time are crucial factors in producing bio-oil with the desired chemical composition and physical properties. The maximum yield, 34.13%, was attained after 90 min of operation at 500 °C. The characteristics of the Mimusops elengi bio-oil produced, namely density, viscosity, pH, and HHV were 1.15 g/cm 3 , 1.60 cSt, 4.41, and 19.91 MJ/kg, respectively, in accordance with ASTM D7544. Using Mimusops elengi as a pyrolysis feedstock demonstrates its potential as an environmentally friendly energy source for a variety of industrial and environmental applications. The yield of bio-oil produced is not optimal due to the formation of tar, which results in the blockage of the output flow during the pyrolysis process.

Suggested Citation

  • Leni Maulinda & Husni Husin & Nasrul Arahman & Cut Meurah Rosnelly & Muhammad Syukri & Nurhazanah & Fahrizal Nasution & Ahmadi, 2023. "The Influence of Pyrolysis Time and Temperature on the Composition and Properties of Bio-Oil Prepared from Tanjong Leaves ( Mimusops elengi )," Sustainability, MDPI, vol. 15(18), pages 1-17, September.
  • Handle: RePEc:gam:jsusta:v:15:y:2023:i:18:p:13851-:d:1242146
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/15/18/13851/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/2071-1050/15/18/13851/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Krzysztof Mudryk & Marcin Jewiarz & Marek Wróbel & Marcin Niemiec & Arkadiusz Dyjakon, 2021. "Evaluation of Urban Tree Leaf Biomass-Potential, Physico-Mechanical and Chemical Parameters of Raw Material and Solid Biofuel," Energies, MDPI, vol. 14(4), pages 1-14, February.
    2. Noushabadi, Abolfazl Sajadi & Dashti, Amir & Ahmadijokani, Farhad & Hu, Jinguang & Mohammadi, Amir H., 2021. "Estimation of higher heating values (HHVs) of biomass fuels based on ultimate analysis using machine learning techniques and improved equation," Renewable Energy, Elsevier, vol. 179(C), pages 550-562.
    3. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    4. Sukumar, V. & Manieniyan, V. & Senthilkumar, R. & Sivaprakasam, S., 2020. "Production of bio oil from sweet lime empty fruit bunch by pyrolysis," Renewable Energy, Elsevier, vol. 146(C), pages 309-315.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Yuhan & Wang, Tiancheng & Hu, Hongyun & Yao, Dingding & Zou, Chan & Xu, Kai & Li, Xian & Yao, Hong, 2021. "Influence of partial components removal on pyrolysis behavior of lignocellulosic biowaste in molten salts," Renewable Energy, Elsevier, vol. 180(C), pages 616-625.
    2. Ayub, Yousaf & Ren, Jingzheng & Shi, Tao & Shen, Weifeng & He, Chang, 2023. "Poultry litter valorization: Development and optimization of an electro-chemical and thermal tri-generation process using an extreme gradient boosting algorithm," Energy, Elsevier, vol. 263(PC).
    3. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    4. Ye, Lian & Zhang, Jianliang & Wang, Guangwei & Wang, Chen & Mao, Xiaoming & Ning, Xiaojun & Zhang, Nan & Teng, Haipeng & Li, Jinhua & Wang, Chuan, 2023. "Feasibility analysis of plastic and biomass hydrochar for blast furnace injection," Energy, Elsevier, vol. 263(PD).
    5. Hu, Hangli & Luo, Yanru & Zou, Jianfeng & Zhang, Shukai & Yellezuome, Dominic & Rahman, Md Maksudur & Li, Yingkai & Li, Chong & Cai, Junmeng, 2022. "Exploring aging kinetic mechanisms of bio-oil from biomass pyrolysis based on change in carbonyl content," Renewable Energy, Elsevier, vol. 199(C), pages 782-790.
    6. Zhao, Ming & Memon, Muhammad Zaki & Ji, Guozhao & Yang, Xiaoxiao & Vuppaladadiyam, Arun K. & Song, Yinqiang & Raheem, Abdul & Li, Jinhui & Wang, Wei & Zhou, Hui, 2020. "Alkali metal bifunctional catalyst-sorbents enabled biomass pyrolysis for enhanced hydrogen production," Renewable Energy, Elsevier, vol. 148(C), pages 168-175.
    7. Zang, Guiyan & Zhang, Jianan & Jia, Junxi & Lora, Electo Silva & Ratner, Albert, 2020. "Life cycle assessment of power-generation systems based on biomass integrated gasification combined cycles," Renewable Energy, Elsevier, vol. 149(C), pages 336-346.
    8. Alsulami, Radi A. & El-Sayed, Saad A. & Eltaher, Mohamed A. & Mohammad, Akram & Almitani, Khalid H. & Mostafa, Mohamed E., 2023. "Pyrolysis kinetics and thermal degradation characteristics of coffee, date seed, and prickly pear wastes and their blends," Renewable Energy, Elsevier, vol. 216(C).
    9. Sitek, Tomáš & Pospíšil, Jiří & Poláčik, Ján & Špiláček, Michal & Varbanov, Petar, 2019. "Fine combustion particles released during combustion of unit mass of beechwood," Renewable Energy, Elsevier, vol. 140(C), pages 390-396.
    10. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    11. Juan García-Quezada & Ricardo Musule-Lagunes & José Angel Prieto-Ruíz & Daniel José Vega-Nieva & Artemio Carrillo-Parra, 2022. "Evaluation of Four Types of Kilns Used to Produce Charcoal from Several Tree Species in Mexico," Energies, MDPI, vol. 16(1), pages 1-22, December.
    12. Gupta, Shubhi & Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Slow pyrolysis of chemically treated walnut shell for valuable products: Effect of process parameters and in-depth product analysis," Energy, Elsevier, vol. 181(C), pages 665-676.
    13. Adnan, Muflih A. & Hossain, Mohammad M. & Kibria, Md Golam, 2020. "Biomass upgrading to high-value chemicals via gasification and electrolysis: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 162(C), pages 1367-1379.
    14. Salvilla, John Nikko V. & Ofrasio, Bjorn Ivan G. & Rollon, Analiza P. & Manegdeg, Ferdinand G. & Abarca, Ralf Ruffel M. & de Luna, Mark Daniel G., 2020. "Synergistic co-pyrolysıs of polyolefin plastics with wood and agricultural wastes for biofuel production," Applied Energy, Elsevier, vol. 279(C).
    15. Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Pyrolysis of Rapeseed Oil Press Cake and Steam Gasification of Solid Residues," Energies, MDPI, vol. 13(17), pages 1-12, August.
    16. Radoslaw Slezak & Hilal Unyay & Szymon Szufa & Stanislaw Ledakowicz, 2023. "An Extensive Review and Comparison of Modern Biomass Reactors Torrefaction vs. Biomass Pyrolizers—Part 2," Energies, MDPI, vol. 16(5), pages 1-25, February.
    17. Adrian Neacsa & Cristian Nicolae Eparu & Doru Bogdan Stoica, 2022. "Hydrogen–Natural Gas Blending in Distribution Systems—An Energy, Economic, and Environmental Assessment," Energies, MDPI, vol. 15(17), pages 1-26, August.
    18. Ge, Shengbo & Yek, Peter Nai Yuh & Cheng, Yoke Wang & Xia, Changlei & Wan Mahari, Wan Adibah & Liew, Rock Keey & Peng, Wanxi & Yuan, Tong-Qi & Tabatabaei, Meisam & Aghbashlo, Mortaza & Sonne, Christia, 2021. "Progress in microwave pyrolysis conversion of agricultural waste to value-added biofuels: A batch to continuous approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    19. Ma, Liyang & Goldfarb, Jillian L. & Ma, Qiulin, 2022. "Enabling lower temperature pyrolysis with aqueous ionic liquid pretreatment as a sustainable approach to rice husk conversion to biofuels," Renewable Energy, Elsevier, vol. 198(C), pages 712-722.
    20. Małgorzata Sieradzka & Agata Mlonka-Mędrala & Izabela Kalemba-Rec & Markus Reinmöller & Felix Küster & Wojciech Kalawa & Aneta Magdziarz, 2022. "Evaluation of Physical and Chemical Properties of Residue from Gasification of Biomass Wastes," Energies, MDPI, vol. 15(10), pages 1-19, May.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:15:y:2023:i:18:p:13851-:d:1242146. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.