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Effects of wet torrefaction on pyrolysis of woody biomass fuels

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  • Bach, Quang-Vu
  • Tran, Khanh-Quang
  • Skreiberg, Øyvind
  • Trinh, Thuat T.

Abstract

The pyrolysis of Norway spruce and birch woods under nitrogen atmosphere was studied by means of a thermogravimetric analyzer operated in the non-isothermal mode, followed by a kinetic analysis employing a three-pseudo-component model with nth-order reactions. Raw woods and the woods treated via wet torrefaction in the conditions of various temperatures (175, 200, 225 °C) and holding times (10, 30, 60 min) were included in this work. The study showed that wet torrefaction resulted in higher pyrolysis peaks for the woods, but less mass of volatiles was released during pyrolysis. The effects of wet torrefaction on pyrolysis of the lignocellulosic components are different. The activation energy of hemicellulose was significantly reduced by wet torrefaction. However, those for cellulose and lignin were slightly increased by wet torrefaction.

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  • Bach, Quang-Vu & Tran, Khanh-Quang & Skreiberg, Øyvind & Trinh, Thuat T., 2015. "Effects of wet torrefaction on pyrolysis of woody biomass fuels," Energy, Elsevier, vol. 88(C), pages 443-456.
    • Handle: RePEc:eee:energy:v:88:y:2015:i:c:p:443-456
    DOI: 10.1016/j.energy.2015.05.062
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    4. Bach, Quang-Vu & Skreiberg, Øyvind, 2016. "Upgrading biomass fuels via wet torrefaction: A review and comparison with dry torrefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 665-677.
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    11. Zhao, Zhong & Feng, Shuo & Zhao, Yaying & Wang, Zhuozhi & Ma, Jiao & Xu, Lianfei & Yang, Jiancheng & Shen, Boxiong, 2022. "Investigation on the fuel quality and hydrophobicity of upgraded rice husk derived from various inert and oxidative torrefaction conditions," Renewable Energy, Elsevier, vol. 189(C), pages 1234-1248.
    12. Chen, Renjie & Yuan, Shijie & Wang, Xiankai & Dai, Xiaohu & Guo, Yali & Li, Chong & Wu, Haibin & Dong, Bin, 2023. "Mechanistic insight into the effect of hydrothermal treatment of sewage sludge on subsequent pyrolysis: Evolution of volatile and their interaction with pyrolysis kinetic and products compositions," Energy, Elsevier, vol. 266(C).
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    14. Kartal, Furkan & Özveren, Uğur, 2022. "Prediction of torrefied biomass properties from raw biomass," Renewable Energy, Elsevier, vol. 182(C), pages 578-591.
    15. Mahmudul Hasan & Yousef Haseli & Ernur Karadogan, 2018. "Correlations to Predict Elemental Compositions and Heating Value of Torrefied Biomass," Energies, MDPI, vol. 11(9), pages 1-15, September.
    16. Bach, Quang-Vu & Tran, Khanh-Quang & Skreiberg, Øyvind, 2017. "Combustion kinetics of wet-torrefied forest residues using the distributed activation energy model (DAEM)," Applied Energy, Elsevier, vol. 185(P2), pages 1059-1066.
    17. Bach, Quang-Vu & Tran, Khanh-Quang & Skreiberg, Øyvind, 2017. "Comparative study on the thermal degradation of dry- and wet-torrefied woods," Applied Energy, Elsevier, vol. 185(P2), pages 1051-1058.
    18. Li, Jingjing & Dou, Binlin & Zhang, Hua & Zhang, Hao & Chen, Haisheng & Xu, Yujie & Wu, Chunfei, 2021. "Pyrolysis characteristics and non-isothermal kinetics of waste wood biomass," Energy, Elsevier, vol. 226(C).

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