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Hydrothermal carbonization of olive wastes to produce renewable, binder-free pellets for use as metallurgical reducing agents

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  • Surup, Gerrit Ralf
  • Leahy, James J.
  • Timko, Michael T.
  • Trubetskaya, Anna

Abstract

Torrefaction or hydrothermal carbonization processes were compared for conversion of olive pulp into metallurgical reducing agent. The dependence of yield, CO2 reactivity, and mechanical properties to reaction time and heat treatment temperature was investigated. Hydrochar yield increased with increasing residence time and the maximum solid yield was observed for a residence time of 15 h. On the other hand, CO2 reactivity slightly decreased with increasing heat treatment temperature at a residence time of 2 h. Notably, the CO2 reactivity of hydrochar was less than that of olive pulp char produced by torrefaction, approximating that of carbon-based reducing agents derived from non-renewable resources. An additional heat treatment improved hydrochar pellet durability to greater than 95%, whereas stable torrefied char pellets could not be produced under any set of conditions. Hydrothermal carbonization is superior to torrefaction for production of renewable reducing agents with reactivity and mechanical properties comparable to those afforded by reducing agents from non-renewable sources.

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  • Surup, Gerrit Ralf & Leahy, James J. & Timko, Michael T. & Trubetskaya, Anna, 2020. "Hydrothermal carbonization of olive wastes to produce renewable, binder-free pellets for use as metallurgical reducing agents," Renewable Energy, Elsevier, vol. 155(C), pages 347-357.
  • Handle: RePEc:eee:renene:v:155:y:2020:i:c:p:347-357
    DOI: 10.1016/j.renene.2020.03.112
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    1. Trubetskaya, Anna & Leahy, James J. & Yazhenskikh, Elena & Müller, Michael & Layden, Peter & Johnson, Robert & Ståhl, Kenny & Monaghan, Rory F.D., 2019. "Characterization of woodstove briquettes from torrefied biomass and coal," Energy, Elsevier, vol. 171(C), pages 853-865.
    2. Akbar Saba & Kyle McGaughy & M. Toufiq Reza, 2019. "Techno-Economic Assessment of Co-Hydrothermal Carbonization of a Coal-Miscanthus Blend," Energies, MDPI, vol. 12(4), pages 1-17, February.
    3. Osman, Ahmed I., 2020. "Mass spectrometry study of lignocellulosic biomass combustion and pyrolysis with NOx removal," Renewable Energy, Elsevier, vol. 146(C), pages 484-496.
    4. Ahmad, Fiaz & Silva, Edson Luiz & Varesche, Maria Bernadete Amâncio, 2018. "Hydrothermal processing of biomass for anaerobic digestion – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 108-124.
    5. Riva, Lorenzo & Surup, Gerrit Ralf & Buø, Therese Videm & Nielsen, Henrik Kofoed, 2019. "A study of densified biochar as carbon source in the silicon and ferrosilicon production," Energy, Elsevier, vol. 181(C), pages 985-996.
    6. Bach, Quang-Vu & Skreiberg, Øyvind, 2016. "Upgrading biomass fuels via wet torrefaction: A review and comparison with dry torrefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 665-677.
    7. Surup, Gerrit & Vehus, Tore & Eidem, Per-Anders & Trubetskaya, Anna & Nielsen, Henrik Kofoed, 2019. "Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 167(C), pages 337-345.
    8. Kambo, Harpreet Singh & Dutta, Animesh, 2015. "A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 359-378.
    9. Mizi Fan, 2012. "Fourier Transform Infrared Spectroscopy for Natural Fibres," Chapters, in: Salih Mohammed Salih (ed.), Fourier Transform - Materials Analysis, IntechOpen.
    10. Tripathi, Manoj & Sahu, J.N. & Ganesan, P., 2016. "Effect of process parameters on production of biochar from biomass waste through pyrolysis: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 467-481.
    11. Surup, Gerrit Ralf & Hunt, Andrew J. & Attard, Thomas & Budarin, Vitaliy L. & Forsberg, Fredrik & Arshadi, Mehrdad & Abdelsayed, Victor & Shekhawat, Dushyant & Trubetskaya, Anna, 2020. "The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries," Energy, Elsevier, vol. 193(C).
    12. Liu, Zhengang & Quek, Augustine & Balasubramanian, R., 2014. "Preparation and characterization of fuel pellets from woody biomass, agro-residues and their corresponding hydrochars," Applied Energy, Elsevier, vol. 113(C), pages 1315-1322.
    13. Silvia Román & Judy Libra & Nicole Berge & Eduardo Sabio & Kyoung Ro & Liang Li & Beatriz Ledesma & Andrés Álvarez & Sunyoung Bae, 2018. "Hydrothermal Carbonization: Modeling, Final Properties Design and Applications: A Review," Energies, MDPI, vol. 11(1), pages 1-28, January.
    14. He, Chao & Tang, Chunyan & Li, Chuanhao & Yuan, Jihui & Tran, Khanh-Quang & Bach, Quang-Vu & Qiu, Rongliang & Yang, Yanhui, 2018. "Wet torrefaction of biomass for high quality solid fuel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 259-271.
    15. Marcin Bajcar & Grzegorz Zaguła & Bogdan Saletnik & Maria Tarapatskyy & Czesław Puchalski, 2018. "Relationship between Torrefaction Parameters and Physicochemical Properties of Torrefied Products Obtained from Selected Plant Biomass," Energies, MDPI, vol. 11(11), pages 1-13, October.
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