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Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries

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  • Surup, Gerrit
  • Vehus, Tore
  • Eidem, Per-Anders
  • Trubetskaya, Anna
  • Nielsen, Henrik Kofoed

Abstract

This study investigates the effect of high-temperature pyrolysis and post-treatment processes on spruce and oak charcoal yields and CO2 reactivity in a slow pyrolysis reactor. Post-treatment processes such as co-pyrolysis of biomass and recirculated tar mixture with that to the distillation of the charcoal-tar blend gave similar increase in charcoal yields. From a technological standpoint, co-pyrolysis of charcoal and tar mixture decreased the CO2 reactivity of the charcoal approaching that of fossil-based coke. This emphasize the importance of tar addition and high temperature treatment on charcoal properties. Moreover, the findings of this work show the potential use of the tar organic fractions as a binder that can be used for the charcoal pellet preparation. The results are promising as they show that the charcoal-based pellets have comparable properties of pellets from herbaceous biomass leading to the cost reduction in charcoal transportation and storage.

Suggested Citation

  • Surup, Gerrit & Vehus, Tore & Eidem, Per-Anders & Trubetskaya, Anna & Nielsen, Henrik Kofoed, 2019. "Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 167(C), pages 337-345.
    • Handle: RePEc:eee:energy:v:167:y:2019:i:c:p:337-345
    DOI: 10.1016/j.energy.2018.10.193
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    References listed on IDEAS

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    1. Hannu Suopajärvi & Essi Dahl & Antti Kemppainen & Stanislav Gornostayev & Aki Koskela & Timo Fabritius, 2017. "Effect of Charcoal and Kraft-Lignin Addition on Coke Compression Strength and Reactivity," Energies, MDPI, vol. 10(11), pages 1-15, November.
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    3. Hu, Qiang & Shao, Jingai & Yang, Haiping & Yao, Dingding & Wang, Xianhua & Chen, Hanping, 2015. "Effects of binders on the properties of bio-char pellets," Applied Energy, Elsevier, vol. 157(C), pages 508-516.
    4. Rudolfsson, Magnus & Stelte, Wolfgang & Lestander, Torbjörn A., 2015. "Process optimization of combined biomass torrefaction and pelletization for fuel pellet production – A parametric study," Applied Energy, Elsevier, vol. 140(C), pages 378-384.
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    Cited by:

    1. Gerrit Ralf Surup & Hamideh Kaffash & Yan Ma & Anna Trubetskaya & Johan Berg Pettersen & Merete Tangstad, 2022. "Life Cycle Based Climate Emissions of Charcoal Conditioning Routes for the Use in the Ferro-Alloy Production," Energies, MDPI, vol. 15(11), pages 1-28, May.
    2. Riva, Lorenzo & Nielsen, Henrik Kofoed & Skreiberg, Øyvind & Wang, Liang & Bartocci, Pietro & Barbanera, Marco & Bidini, Gianni & Fantozzi, Francesco, 2019. "Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke," Applied Energy, Elsevier, vol. 256(C).
    3. Riva, Lorenzo & Surup, Gerrit Ralf & Buø, Therese Videm & Nielsen, Henrik Kofoed, 2019. "A study of densified biochar as carbon source in the silicon and ferrosilicon production," Energy, Elsevier, vol. 181(C), pages 985-996.
    4. Surup, Gerrit Ralf & Leahy, James J. & Timko, Michael T. & Trubetskaya, Anna, 2020. "Hydrothermal carbonization of olive wastes to produce renewable, binder-free pellets for use as metallurgical reducing agents," Renewable Energy, Elsevier, vol. 155(C), pages 347-357.
    5. Surup, Gerrit Ralf & Hunt, Andrew J. & Attard, Thomas & Budarin, Vitaliy L. & Forsberg, Fredrik & Arshadi, Mehrdad & Abdelsayed, Victor & Shekhawat, Dushyant & Trubetskaya, Anna, 2020. "The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries," Energy, Elsevier, vol. 193(C).
    6. Surup, Gerrit Ralf & Nielsen, Henrik Kofoed & Großarth, Marius & Deike, Rüdiger & Van den Bulcke, Jan & Kibleur, Pierre & Müller, Michael & Ziegner, Mirko & Yazhenskikh, Elena & Beloshapkin, Sergey & , 2020. "Effect of operating conditions and feedstock composition on the properties of manganese oxide or quartz charcoal pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 193(C).

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