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Characterization of woodstove briquettes from torrefied biomass and coal

Author

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  • Trubetskaya, Anna
  • Leahy, James J.
  • Yazhenskikh, Elena
  • Müller, Michael
  • Layden, Peter
  • Johnson, Robert
  • Ståhl, Kenny
  • Monaghan, Rory F.D.

Abstract

Using waste biomass materials offers the potential to reduce the greenhouse gas emissions from fossil fuels. Torrefaction is very useful for improving the fuel properties of biomass in order to better match those of coal. The aim of this work is to compare the properties of torrefied low quality biomass briquettes against coal equivalents. The composition of the briquettes was characterized by 13C CP/MAS, proximate analysis, and X-ray diffraction and the results were compared with equilibrium calculations. In addition to these techniques, we report for the first time on the use of XμCT for characterizing such materials. The XμCT analysis showed that the briquette structure contains carbon, binder and inorganic matter, with quartz retained from the original feedstock in torrefied biomass and coal briquettes. The CO2 reactivity of pulverized briquettes was investigated by thermogravimetric analysis. Results showed that the inorganic matter influences the reactivity less than the organic composition and porosity. Importantly from a technological standpoint, the increase in binder concentration and replacement of starch with resin binder did not influence the reactivity and calorific value of a pulverized briquette.

Suggested Citation

  • Trubetskaya, Anna & Leahy, James J. & Yazhenskikh, Elena & Müller, Michael & Layden, Peter & Johnson, Robert & Ståhl, Kenny & Monaghan, Rory F.D., 2019. "Characterization of woodstove briquettes from torrefied biomass and coal," Energy, Elsevier, vol. 171(C), pages 853-865.
    • Handle: RePEc:eee:energy:v:171:y:2019:i:c:p:853-865
    DOI: 10.1016/j.energy.2019.01.064
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    References listed on IDEAS

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    1. Rudolfsson, Magnus & Borén, Eleonora & Pommer, Linda & Nordin, Anders & Lestander, Torbjörn A., 2017. "Combined effects of torrefaction and pelletization parameters on the quality of pellets produced from torrefied biomass," Applied Energy, Elsevier, vol. 191(C), pages 414-424.
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    1. Gouws, S.M. & Carrier, M. & Bunt, J.R. & Neomagus, H.W.J.P., 2021. "Co-pyrolysis of coal and raw/torrefied biomass: A review on chemistry, kinetics and implementation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    2. Trubetskaya, Anna & Grams, Jacek & Leahy, James J. & Johnson, Robert & Gallagher, Paul & Monaghan, Rory F.D. & Kwapinska, Marzena, 2020. "The effect of particle size, temperature and residence time on the yields and reactivity of olive stones from torrefaction," Renewable Energy, Elsevier, vol. 160(C), pages 998-1011.
    3. Shuren Chen & Yunfei Zhao & Zhong Tang & Hantao Ding & Zhan Su & Zhao Ding, 2022. "Structural Model of Straw Briquetting Machine with Vertical Ring Die and Optimization of Briquetting Performance," Agriculture, MDPI, vol. 12(5), pages 1-15, May.
    4. Tabakaev, Roman & Kahn, Victor & Dubinin, Yury & Rudmin, Maxim & Yazykov, Nikolay & Skugarov, Artem & Alekseenko, Eduard & Zavorin, Alexander & Preis, Sergei, 2022. "High-strength fuel pellets made of flour milling and coal slack wastes," Energy, Elsevier, vol. 243(C).
    5. Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    6. Oscar Araque & Nelson Arzola & Laura Gallego, 2022. "Mechanical Behavior of Briquettes Made from a Mixture of Sawdust and Rice Husks for Commercialization," Resources, MDPI, vol. 11(3), pages 1-18, March.
    7. Sunday Yusuf Kpalo & Mohamad Faiz Zainuddin & Latifah Abd Manaf & Ahmad Muhaimin Roslan, 2020. "Production and Characterization of Hybrid Briquettes from Corncobs and Oil Palm Trunk Bark under a Low Pressure Densification Technique," Sustainability, MDPI, vol. 12(6), pages 1-16, March.
    8. Sunday Yusuf Kpalo & Mohamad Faiz Zainuddin & Latifah Abd Manaf & Ahmad Muhaimin Roslan, 2020. "A Review of Technical and Economic Aspects of Biomass Briquetting," Sustainability, MDPI, vol. 12(11), pages 1-30, June.
    9. Surup, Gerrit Ralf & Leahy, James J. & Timko, Michael T. & Trubetskaya, Anna, 2020. "Hydrothermal carbonization of olive wastes to produce renewable, binder-free pellets for use as metallurgical reducing agents," Renewable Energy, Elsevier, vol. 155(C), pages 347-357.
    10. Rosa Martins & Haylemar de Nazaret Cardenas-Rodriguez & Levy Ely Lacerda Oliveira & Erik Leandro Bonaldi & Frederico de Oliveira Assuncao & Germano Lambert-Torres & Helcio Francisco Villa-Nova & Wilso, 2022. "Technical and Economic Analysis of the Implementation of a Self-Sustainable Briquetting Process for Electric Generation," Energies, MDPI, vol. 15(6), pages 1-14, March.
    11. Surup, Gerrit Ralf & Nielsen, Henrik Kofoed & Großarth, Marius & Deike, Rüdiger & Van den Bulcke, Jan & Kibleur, Pierre & Müller, Michael & Ziegner, Mirko & Yazhenskikh, Elena & Beloshapkin, Sergey & , 2020. "Effect of operating conditions and feedstock composition on the properties of manganese oxide or quartz charcoal pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 193(C).

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