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Reactivity Effects of Inorganic Content in Biomass Gasification: A Review

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  • Anna Trubetskaya

    (Department of Engineering, University of Limerick, Castletroy, V94 T9PX Limerick, Ireland)

Abstract

This review article discusses the effects of inorganic content and mechanisms on raw biomass and char during gasification. The impacts of the inherent inorganics and externally added inorganic compounds are summarized based on a literature search from the most recent 40 years. The TGA and larger-scale studies involving K-, Ca-, and Si-related mechanisms are critically reviewed with the aim of understanding the reaction mechanisms and kinetics. Differences between the reaction pathways of inorganic matter, and subsequent effects on the reactivity during gasification, are discussed. The present results illustrate the complexity of ash transformation phenomena, which have a strong impact on the design of gasifiers as well as further operation and process control. The impregnation and mixing of catalytic compounds into raw biomass are emphasized as a potential solution to avoid reactivity-related operational challenges during steam and CO 2 gasification. This review clearly identifies a gap in experimental knowledge at the micro and macro levels in the advanced modelling of inorganics transformation with respect to gasification reactivity.

Suggested Citation

  • Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:9:p:3137-:d:801940
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    References listed on IDEAS

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    1. Trubetskaya, Anna & Leahy, James J. & Yazhenskikh, Elena & Müller, Michael & Layden, Peter & Johnson, Robert & Ståhl, Kenny & Monaghan, Rory F.D., 2019. "Characterization of woodstove briquettes from torrefied biomass and coal," Energy, Elsevier, vol. 171(C), pages 853-865.
    2. González-Vázquez, M.P. & García, R. & Gil, M.V. & Pevida, C. & Rubiera, F., 2018. "Unconventional biomass fuels for steam gasification: Kinetic analysis and effect of ash composition on reactivity," Energy, Elsevier, vol. 155(C), pages 426-437.
    3. Lin, Leteng & Strand, Michael, 2013. "Investigation of the intrinsic CO2 gasification kinetics of biomass char at medium to high temperatures," Applied Energy, Elsevier, vol. 109(C), pages 220-228.
    4. Bruhn, Thomas & Naims, Henriette & Olfe-Kräutlein, Barbara, 2016. "Separating the debate on CO2 utilisation from carbon capture and storage," Environmental Science & Policy, Elsevier, vol. 60(C), pages 38-43.
    5. Nzihou, Ange & Stanmore, Brian & Sharrock, Patrick, 2013. "A review of catalysts for the gasification of biomass char, with some reference to coal," Energy, Elsevier, vol. 58(C), pages 305-317.
    6. Trubetskaya, Anna & Budarin, Vitaliy & Arshadi, Mehrdad & Magalhães, Duarte & Kazanç, Feyza & Hunt, Andrew John, 2021. "Supercritical extraction of biomass as an effective pretreatment step for the char yield control in pyrolysis," Renewable Energy, Elsevier, vol. 170(C), pages 107-117.
    7. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Gasification of lignocellulosic biomass char obtained from pyrolysis: Kinetic and evolved gas analyses," Energy, Elsevier, vol. 71(C), pages 456-467.
    8. Daniel L. Sanchez & Daniel M. Kammen, 2016. "A commercialization strategy for carbon-negative energy," Nature Energy, Nature, vol. 1(1), pages 1-4, January.
    9. Kirtania, Kawnish & Axelsson, Joel & Matsakas, Leonidas & Christakopoulos, Paul & Umeki, Kentaro & Furusjö, Erik, 2017. "Kinetic study of catalytic gasification of wood char impregnated with different alkali salts," Energy, Elsevier, vol. 118(C), pages 1055-1065.
    10. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    11. Surup, Gerrit Ralf & Nielsen, Henrik Kofoed & Großarth, Marius & Deike, Rüdiger & Van den Bulcke, Jan & Kibleur, Pierre & Müller, Michael & Ziegner, Mirko & Yazhenskikh, Elena & Beloshapkin, Sergey & , 2020. "Effect of operating conditions and feedstock composition on the properties of manganese oxide or quartz charcoal pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 193(C).
    12. Saiman Ding & Efthymios Kantarelis & Klas Engvall, 2020. "Effects of Porous Structure Development and Ash on the Steam Gasification Reactivity of Biochar Residues from a Commercial Gasifier at Different Temperatures," Energies, MDPI, vol. 13(19), pages 1-19, September.
    13. Kuba, Matthias & Kraft, Stephan & Kirnbauer, Friedrich & Maierhans, Frank & Hofbauer, Hermann, 2018. "Influence of controlled handling of solid inorganic materials and design changes on the product gas quality in dual fluid bed gasification of woody biomass," Applied Energy, Elsevier, vol. 210(C), pages 230-240.
    14. Ahmed, I.I. & Gupta, A.K., 2011. "Kinetics of woodchips char gasification with steam and carbon dioxide," Applied Energy, Elsevier, vol. 88(5), pages 1613-1619, May.
    15. Trubetskaya, Anna & Surup, Gerrit & Shapiro, Alexander & Bates, Richard B., 2017. "Modeling the influence of potassium content and heating rate on biomass pyrolysis," Applied Energy, Elsevier, vol. 194(C), pages 199-211.
    16. Trubetskaya, Anna & Grams, Jacek & Leahy, James J. & Johnson, Robert & Gallagher, Paul & Monaghan, Rory F.D. & Kwapinska, Marzena, 2020. "The effect of particle size, temperature and residence time on the yields and reactivity of olive stones from torrefaction," Renewable Energy, Elsevier, vol. 160(C), pages 998-1011.
    17. Masnadi, Mohammad S. & Grace, John R. & Bi, Xiaotao T. & Ellis, Naoko & Lim, C. Jim & Butler, James W., 2015. "Biomass/coal steam co-gasification integrated with in-situ CO2 capture," Energy, Elsevier, vol. 83(C), pages 326-336.
    18. Surup, Gerrit Ralf & Leahy, James J. & Timko, Michael T. & Trubetskaya, Anna, 2020. "Hydrothermal carbonization of olive wastes to produce renewable, binder-free pellets for use as metallurgical reducing agents," Renewable Energy, Elsevier, vol. 155(C), pages 347-357.
    19. Guizani, Chamseddine & Jeguirim, Mejdi & Gadiou, Roger & Escudero Sanz, Fransisco Javier & Salvador, Sylvain, 2016. "Biomass char gasification by H2O, CO2 and their mixture: Evolution of chemical, textural and structural properties of the chars," Energy, Elsevier, vol. 112(C), pages 133-145.
    20. Marcin Bajcar & Grzegorz Zaguła & Bogdan Saletnik & Maria Tarapatskyy & Czesław Puchalski, 2018. "Relationship between Torrefaction Parameters and Physicochemical Properties of Torrefied Products Obtained from Selected Plant Biomass," Energies, MDPI, vol. 11(11), pages 1-13, October.
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    Cited by:

    1. Maximilian Robert Heinrich & André Herrmann & Andy Gradel & Marco Klemm & Tobias Plessing, 2023. "Extensive Experimental Characterization with Kinetic Data for the Gasification Simulation of Solid Biofuels," Energies, MDPI, vol. 16(6), pages 1-31, March.
    2. N., Mohammed Asheruddin & Shivapuji, Anand M. & Dasappa, Srinivasaiah, 2023. "Thermochemical conversion of millimeter-sized single char particle in steam dominated environments under varying temperature, reactant composition and flux—Experimental and numerical analysis," Energy, Elsevier, vol. 269(C).
    3. Gerrit Ralf Surup & Hamideh Kaffash & Yan Ma & Anna Trubetskaya & Johan Berg Pettersen & Merete Tangstad, 2022. "Life Cycle Based Climate Emissions of Charcoal Conditioning Routes for the Use in the Ferro-Alloy Production," Energies, MDPI, vol. 15(11), pages 1-28, May.
    4. Juraj Kukuruzović & Ana Matin & Mislav Kontek & Tajana Krička & Božidar Matin & Ivan Brandić & Alan Antonović, 2023. "The Effects of Demineralization on Reducing Ash Content in Corn and Soy Biomass with the Goal of Increasing Biofuel Quality," Energies, MDPI, vol. 16(2), pages 1-12, January.

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