IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v112y2016icp133-145.html
   My bibliography  Save this article

Biomass char gasification by H2O, CO2 and their mixture: Evolution of chemical, textural and structural properties of the chars

Author

Listed:
  • Guizani, Chamseddine
  • Jeguirim, Mejdi
  • Gadiou, Roger
  • Escudero Sanz, Fransisco Javier
  • Salvador, Sylvain

Abstract

The present study aims to understand the phenomenology of char gasification by monitoring the chemical, structural and textural char characteristics through the gasification reaction. Chars from beech wood were gasified under 20%H2O, 20%CO2 and 20%H2O + 20%CO2 in N2 at 900° C. The gasification reactions were stopped at 20%, 50% and 70% of char conversion. The char properties were analysed by different analytical techniques such as temperature programmed desorption coupled to mass spectrometry, Raman spectroscopy, Scanning Electron Microscopy, N2 manometry and X-ray Fluorescence. These analyses provide valuable information on the unfolding of the gasification reactions with H2O, CO2 and their mixtures. In particular, it is noted that H2O and CO2 gasification reactions follow different pathways. Moreover, during mixed atmosphere, despite that the char reactivity can be fairly expressed by summing the two individual reactivities, this apparent additivity appears to be the result of several competitions and synergies between H2O and CO2 reactions.

Suggested Citation

  • Guizani, Chamseddine & Jeguirim, Mejdi & Gadiou, Roger & Escudero Sanz, Fransisco Javier & Salvador, Sylvain, 2016. "Biomass char gasification by H2O, CO2 and their mixture: Evolution of chemical, textural and structural properties of the chars," Energy, Elsevier, vol. 112(C), pages 133-145.
    • Handle: RePEc:eee:energy:v:112:y:2016:i:c:p:133-145
    DOI: 10.1016/j.energy.2016.06.065
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216308398
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2016.06.065?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Bai, Yonghui & Wang, Yulong & Zhu, Shenghua & Li, Fan & Xie, Kechang, 2014. "Structural features and gasification reactivity of coal chars formed in Ar and CO2 atmospheres at elevated pressures," Energy, Elsevier, vol. 74(C), pages 464-470.
    2. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Gasification of lignocellulosic biomass char obtained from pyrolysis: Kinetic and evolved gas analyses," Energy, Elsevier, vol. 71(C), pages 456-467.
    3. Nzihou, Ange & Stanmore, Brian & Sharrock, Patrick, 2013. "A review of catalysts for the gasification of biomass char, with some reference to coal," Energy, Elsevier, vol. 58(C), pages 305-317.
    4. Bentsen, Niclas Scott & Jack, Michael W. & Felby, Claus & Thorsen, Bo Jellesmark, 2014. "Allocation of biomass resources for minimising energy system greenhouse gas emissions," Energy, Elsevier, vol. 69(C), pages 506-515.
    5. Lopez, Gartzen & Alvarez, Jon & Amutio, Maider & Arregi, Aitor & Bilbao, Javier & Olazar, Martin, 2016. "Assessment of steam gasification kinetics of the char from lignocellulosic biomass in a conical spouted bed reactor," Energy, Elsevier, vol. 107(C), pages 493-501.
    6. Bouraoui, Zeineb & Jeguirim, Mejdi & Guizani, Chamseddine & Limousy, Lionel & Dupont, Capucine & Gadiou, Roger, 2015. "Thermogravimetric study on the influence of structural, textural and chemical properties of biomass chars on CO2 gasification reactivity," Energy, Elsevier, vol. 88(C), pages 703-710.
    7. Im-orb, Karittha & Simasatitkul, Lida & Arpornwichanop, Amornchai, 2016. "Techno-economic analysis of the biomass gasification and Fischer–Tropsch integrated process with off-gas recirculation," Energy, Elsevier, vol. 94(C), pages 483-496.
    8. Dupont, Capucine & Jacob, Sylvain & Marrakchy, Khalil Ould & Hognon, Céline & Grateau, Maguelone & Labalette, Françoise & Da Silva Perez, Denilson, 2016. "How inorganic elements of biomass influence char steam gasification kinetics," Energy, Elsevier, vol. 109(C), pages 430-435.
    9. Gil, María V. & Riaza, Juan & Álvarez, Lucía & Pevida, Covadonga & Rubiera, Fernando, 2015. "Biomass devolatilization at high temperature under N2 and CO2: Char morphology and reactivity," Energy, Elsevier, vol. 91(C), pages 655-662.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. N., Mohammed Asheruddin & Shivapuji, Anand M. & Dasappa, Srinivasaiah, 2023. "Thermochemical conversion of millimeter-sized single char particle in steam dominated environments under varying temperature, reactant composition and flux—Experimental and numerical analysis," Energy, Elsevier, vol. 269(C).
    2. Gao, Xiaoyan & Zhang, Yaning & Xu, Fei & Yin, Zhaoqin & Wang, Yingying & Bao, Fubing & Li, Bingxi, 2019. "Experimental and kinetic studies on the intrinsic reactivities of rice husk char," Renewable Energy, Elsevier, vol. 135(C), pages 608-616.
    3. Hu, Mian & Ye, Zhiheng & Zhang, Qi & Xue, Qiping & Li, Zhibin & Wang, Junliang & Pan, Zhiyan, 2022. "Towards understanding the chemical reactions between KOH and oxygen-containing groups during KOH-catalyzed pyrolysis of biomass," Energy, Elsevier, vol. 245(C).
    4. Kou, Mingyin & Zuo, Haibin & Ning, Xiaojun & Wang, Guangwei & Hong, Zhibin & Xu, Haifa & Wu, Shengli, 2019. "Thermogravimetric study on gasification kinetics of hydropyrolysis char derived from low rank coal," Energy, Elsevier, vol. 188(C).
    5. Imen Ghouma & Mejdi Jeguirim & Uta Sager & Lionel Limousy & Simona Bennici & Eckhard Däuber & Christof Asbach & Roman Ligotski & Frank Schmidt & Abdelmottaleb Ouederni, 2017. "The Potential of Activated Carbon Made of Agro-Industrial Residues in NO x Immissions Abatement," Energies, MDPI, vol. 10(10), pages 1-15, September.
    6. Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    7. Zhang, Zihang & Yi, Baojun & Sun, Zhengshuai & Zhang, Qi & Feng, He & Hu, Hongyun & Huang, Xiangguo & Zhao, Chunqing, 2021. "Reaction process and characteristics for coal char gasification under changed CO2/H2O atmosphere in various reaction stages," Energy, Elsevier, vol. 229(C).
    8. Xia, Sunwen & Yang, Haiping & Lu, Wang & Cai, Ning & Xiao, Haoyu & Chen, Xu & Chen, Yingquan & Wang, Xianhua & Wang, Shurong & Wu, Peng & Chen, Hanping, 2022. "Fe–Co based synergistic catalytic graphitization of biomass: Influence of the catalyst type and the pyrolytic temperature," Energy, Elsevier, vol. 239(PC).
    9. Saiman Ding & Efthymios Kantarelis & Klas Engvall, 2020. "Effects of Porous Structure Development and Ash on the Steam Gasification Reactivity of Biochar Residues from a Commercial Gasifier at Different Temperatures," Energies, MDPI, vol. 13(19), pages 1-19, September.
    10. Parrillo, F. & Ruoppolo, G. & Arena, U., 2020. "The role of activated carbon size in the catalytic cracking of naphthalene," Energy, Elsevier, vol. 190(C).
    11. Huang, Hongyi & Liu, Jingyong & Liu, Hui & Evrendilek, Fatih & Zhang, Gang & He, Yao, 2022. "Turning the co-combustion synergy of textile dyeing sludge and waste biochar into emission-to-bottom slag pollution controls toward a circular economy," Renewable Energy, Elsevier, vol. 194(C), pages 760-777.
    12. Lajili, M. & Guizani, C. & Escudero Sanz, F.J. & Jeguirim, M., 2018. "Fast pyrolysis and steam gasification of pellets prepared from olive oil mill residues," Energy, Elsevier, vol. 150(C), pages 61-68.
    13. Özdenkçi, Karhan & Prestipino, Mauro & Björklund-Sänkiaho, Margareta & Galvagno, Antonio & De Blasio, Cataldo, 2020. "Alternative energy valorization routes of black liquor by stepwise supercritical water gasification: Effect of process parameters on hydrogen yield and energy efficiency," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    14. María Pilar González-Vázquez & Roberto García & Covadonga Pevida & Fernando Rubiera, 2017. "Optimization of a Bubbling Fluidized Bed Plant for Low-Temperature Gasification of Biomass," Energies, MDPI, vol. 10(3), pages 1-16, March.
    15. Wang, Meichen & Wei, Guangsheng & Yang, Shufeng & Zhu, Rong & Yang, Lingzhi, 2022. "Effect of alkali (K/Na) metal vapor on the metallurgical properties of coke in CO2–O2–N2 mixed atmosphere," Energy, Elsevier, vol. 257(C).
    16. Pedro L. Cruz & Diego Iribarren & Javier Dufour, 2019. "Life Cycle Costing and Eco-Efficiency Assessment of Fuel Production by Coprocessing Biomass in Crude Oil Refineries," Energies, MDPI, vol. 12(24), pages 1-17, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Elsaddik, Majd & Nzihou, Ange & Delmas, Michel & Delmas, Guo-Hua, 2023. "Steam gasification of cellulose pulp char: Insights on experimental and kinetic study with a focus on the role of Silicon," Energy, Elsevier, vol. 271(C).
    2. Hu, Qiang & Yang, Haiping & Wu, Zhiqiang & Lim, C. Jim & Bi, Xiaotao T. & Chen, Hanping, 2019. "Experimental and modeling study of potassium catalyzed gasification of woody char pellet with CO2," Energy, Elsevier, vol. 171(C), pages 678-688.
    3. Dahou, T. & Defoort, F. & Khiari, B. & Labaki, M. & Dupont, C. & Jeguirim, M., 2021. "Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    4. Lajili, M. & Guizani, C. & Escudero Sanz, F.J. & Jeguirim, M., 2018. "Fast pyrolysis and steam gasification of pellets prepared from olive oil mill residues," Energy, Elsevier, vol. 150(C), pages 61-68.
    5. González-Vázquez, M.P. & García, R. & Gil, M.V. & Pevida, C. & Rubiera, F., 2018. "Unconventional biomass fuels for steam gasification: Kinetic analysis and effect of ash composition on reactivity," Energy, Elsevier, vol. 155(C), pages 426-437.
    6. Saiman Ding & Efthymios Kantarelis & Klas Engvall, 2020. "Effects of Porous Structure Development and Ash on the Steam Gasification Reactivity of Biochar Residues from a Commercial Gasifier at Different Temperatures," Energies, MDPI, vol. 13(19), pages 1-19, September.
    7. Zhang, Zihang & Yi, Baojun & Sun, Zhengshuai & Zhang, Qi & Feng, He & Hu, Hongyun & Huang, Xiangguo & Zhao, Chunqing, 2021. "Reaction process and characteristics for coal char gasification under changed CO2/H2O atmosphere in various reaction stages," Energy, Elsevier, vol. 229(C).
    8. Dupont, Capucine & Jacob, Sylvain & Marrakchy, Khalil Ould & Hognon, Céline & Grateau, Maguelone & Labalette, Françoise & Da Silva Perez, Denilson, 2016. "How inorganic elements of biomass influence char steam gasification kinetics," Energy, Elsevier, vol. 109(C), pages 430-435.
    9. Bouraoui, Zeineb & Jeguirim, Mejdi & Guizani, Chamseddine & Limousy, Lionel & Dupont, Capucine & Gadiou, Roger, 2015. "Thermogravimetric study on the influence of structural, textural and chemical properties of biomass chars on CO2 gasification reactivity," Energy, Elsevier, vol. 88(C), pages 703-710.
    10. Chen, Yuan & Lin, Weigang & Wu, Hao & Jensen, Peter Arendt & Song, Wenli & Du, Lin & Li, Songgeng, 2021. "Steam gasification of char derived from penicillin mycelial dreg and lignocellulosic biomass: Influence of P, K and Ca on char reactivity," Energy, Elsevier, vol. 228(C).
    11. Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    12. Parascanu, M.M. & Sandoval-Salas, F. & Soreanu, G. & Valverde, J.L. & Sanchez-Silva, L., 2017. "Valorization of Mexican biomasses through pyrolysis, combustion and gasification processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 509-522.
    13. Hervy, Maxime & Weiss-Hortala, Elsa & Pham Minh, Doan & Dib, Hadi & Villot, Audrey & Gérente, Claire & Berhanu, Sarah & Chesnaud, Anthony & Thorel, Alain & Le Coq, Laurence & Nzihou, Ange, 2019. "Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tar," Applied Energy, Elsevier, vol. 237(C), pages 487-499.
    14. Gai, Chao & Chen, Mengjun & Liu, Tingting & Peng, Nana & Liu, Zhengang, 2016. "Gasification characteristics of hydrochar and pyrochar derived from sewage sludge," Energy, Elsevier, vol. 113(C), pages 957-965.
    15. Prestipino, M. & Galvagno, A. & Karlström, O. & Brink, A., 2018. "Energy conversion of agricultural biomass char: Steam gasification kinetics," Energy, Elsevier, vol. 161(C), pages 1055-1063.
    16. Shahbaz, Muhammad & Al-Ansari, Tareq & Inayat, Muddasser & Sulaiman, Shaharin A. & Parthasarathy, Prakash & McKay, Gordon, 2020. "A critical review on the influence of process parameters in catalytic co-gasification: Current performance and challenges for a future prospectus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    17. Haddad, Khouloud & Jeguirim, Mejdi & Jellali, Salah & Guizani, Chamseddine & Delmotte, Luc & Bennici, Simona & Limousy, Lionel, 2017. "Combined NMR structural characterization and thermogravimetric analyses for the assessment of the AAEM effect during lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 134(C), pages 10-23.
    18. Shengguo Zhao & Liang Ding & Yun Ruan & Bin Bai & Zegang Qiu & Zhiqin Li, 2021. "Experimental and Kinetic Studies on Steam Gasification of a Biomass Char," Energies, MDPI, vol. 14(21), pages 1-23, November.
    19. Wang, Guangwei & Zhang, Jianliang & Shao, Jiugang & Liu, Zhengjian & Wang, Haiyang & Li, Xinyu & Zhang, Pengcheng & Geng, Weiwei & Zhang, Guohua, 2016. "Experimental and modeling studies on CO2 gasification of biomass chars," Energy, Elsevier, vol. 114(C), pages 143-154.
    20. Lopez, Gartzen & Alvarez, Jon & Amutio, Maider & Arregi, Aitor & Bilbao, Javier & Olazar, Martin, 2016. "Assessment of steam gasification kinetics of the char from lignocellulosic biomass in a conical spouted bed reactor," Energy, Elsevier, vol. 107(C), pages 493-501.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:112:y:2016:i:c:p:133-145. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.