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How inorganic elements of biomass influence char steam gasification kinetics

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  • Dupont, Capucine
  • Jacob, Sylvain
  • Marrakchy, Khalil Ould
  • Hognon, Céline
  • Grateau, Maguelone
  • Labalette, Françoise
  • Da Silva Perez, Denilson

Abstract

A study was performed to elucidate the influence of biomass type on char steam gasification kinetics. Isothermal experiments were carried out in a thermobalance in chemical regime on nineteen biomass chars produced under the same conditions. The reactivity obtained varied of a factor of more than thirty. This large difference appeared to be correlated with the biomass inorganic elements. In particular, the catalytic effect of potassium (K) as well as the inhibiting effect of silicon (Si) and phosphorus (P) were highlighted. Three different types of rate evolution versus conversion could be observed depending on the ratio K/(Si + P) and were correlated with the ash surface composition after gasification. Conversion could be satisfactorily predicted versus time through simple models taking into account the influence of inorganic elements and thus further useable in simulation of industrial gasifiers fed by various biomass types.

Suggested Citation

  • Dupont, Capucine & Jacob, Sylvain & Marrakchy, Khalil Ould & Hognon, Céline & Grateau, Maguelone & Labalette, Françoise & Da Silva Perez, Denilson, 2016. "How inorganic elements of biomass influence char steam gasification kinetics," Energy, Elsevier, vol. 109(C), pages 430-435.
    • Handle: RePEc:eee:energy:v:109:y:2016:i:c:p:430-435
    DOI: 10.1016/j.energy.2016.04.094
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    1. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Gasification of lignocellulosic biomass char obtained from pyrolysis: Kinetic and evolved gas analyses," Energy, Elsevier, vol. 71(C), pages 456-467.
    2. Nzihou, Ange & Stanmore, Brian & Sharrock, Patrick, 2013. "A review of catalysts for the gasification of biomass char, with some reference to coal," Energy, Elsevier, vol. 58(C), pages 305-317.
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    13. Guizani, Chamseddine & Jeguirim, Mejdi & Gadiou, Roger & Escudero Sanz, Fransisco Javier & Salvador, Sylvain, 2016. "Biomass char gasification by H2O, CO2 and their mixture: Evolution of chemical, textural and structural properties of the chars," Energy, Elsevier, vol. 112(C), pages 133-145.
    14. Hu, Qiang & Yang, Haiping & Wu, Zhiqiang & Lim, C. Jim & Bi, Xiaotao T. & Chen, Hanping, 2019. "Experimental and modeling study of potassium catalyzed gasification of woody char pellet with CO2," Energy, Elsevier, vol. 171(C), pages 678-688.
    15. Shengguo Zhao & Liang Ding & Yun Ruan & Bin Bai & Zegang Qiu & Zhiqin Li, 2021. "Experimental and Kinetic Studies on Steam Gasification of a Biomass Char," Energies, MDPI, vol. 14(21), pages 1-23, November.
    16. Katarzyna Śpiewak & Grzegorz Czerski & Karol Bijak, 2021. "The Effect of Temperature-Pressure Conditions on the RDF Gasification in the Atmosphere of Steam and Carbon Dioxide," Energies, MDPI, vol. 14(22), pages 1-15, November.
    17. Dahou, T. & Defoort, F. & Khiari, B. & Labaki, M. & Dupont, C. & Jeguirim, M., 2021. "Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    18. Qian, Hongliang & Zhu, Weiwei & Fan, Sudong & Liu, Chang & Lu, Xiaohua & Wang, Zhixiang & Huang, Dechun & Chen, Wei, 2017. "Prediction models for chemical exergy of biomass on dry basis from ultimate analysis using available electron concepts," Energy, Elsevier, vol. 131(C), pages 251-258.
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    20. González-Vázquez, M.P. & García, R. & Gil, M.V. & Pevida, C. & Rubiera, F., 2018. "Unconventional biomass fuels for steam gasification: Kinetic analysis and effect of ash composition on reactivity," Energy, Elsevier, vol. 155(C), pages 426-437.

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