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Assessment of steam gasification kinetics of the char from lignocellulosic biomass in a conical spouted bed reactor

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  • Lopez, Gartzen
  • Alvarez, Jon
  • Amutio, Maider
  • Arregi, Aitor
  • Bilbao, Javier
  • Olazar, Martin

Abstract

The steam gasification of pinewood sawdust derived char has been studied in a conical spouted bed reactor. The effect temperature (in the 800–900 °C range), steam partial pressure (from 0.2 to 1) and sawdust particle size (0.3–1, 1–2 and 2–4 mm ranges) have on the char gasification kinetics has been determined. The pyrolysis step was performed in situ prior to the gasification step, at the same temperature as that in gasification. Four models have been proposed for the fitting of experimental results, i.e., homogeneous, shrinking core, nth order and random pore models, with the latter providing the best results. The activation energy obtained from the fitting is 190 kJ mol−1 and the reaction order with respect to steam partial pressure (α) is 0.344.

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  • Lopez, Gartzen & Alvarez, Jon & Amutio, Maider & Arregi, Aitor & Bilbao, Javier & Olazar, Martin, 2016. "Assessment of steam gasification kinetics of the char from lignocellulosic biomass in a conical spouted bed reactor," Energy, Elsevier, vol. 107(C), pages 493-501.
    • Handle: RePEc:eee:energy:v:107:y:2016:i:c:p:493-501
    DOI: 10.1016/j.energy.2016.04.040
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    2. Gao, Xiaoyan & Zhang, Yaning & Xu, Fei & Yin, Zhaoqin & Wang, Yingying & Bao, Fubing & Li, Bingxi, 2019. "Experimental and kinetic studies on the intrinsic reactivities of rice husk char," Renewable Energy, Elsevier, vol. 135(C), pages 608-616.
    3. Gai, Chao & Chen, Mengjun & Liu, Tingting & Peng, Nana & Liu, Zhengang, 2016. "Gasification characteristics of hydrochar and pyrochar derived from sewage sludge," Energy, Elsevier, vol. 113(C), pages 957-965.
    4. Guizani, Chamseddine & Jeguirim, Mejdi & Gadiou, Roger & Escudero Sanz, Fransisco Javier & Salvador, Sylvain, 2016. "Biomass char gasification by H2O, CO2 and their mixture: Evolution of chemical, textural and structural properties of the chars," Energy, Elsevier, vol. 112(C), pages 133-145.
    5. Hu, Qiang & Yang, Haiping & Wu, Zhiqiang & Lim, C. Jim & Bi, Xiaotao T. & Chen, Hanping, 2019. "Experimental and modeling study of potassium catalyzed gasification of woody char pellet with CO2," Energy, Elsevier, vol. 171(C), pages 678-688.
    6. Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Mumbach, Guilherme Davi & Domenico, Michele Di & da Silva Filho, Valdemar Francisco & de Sena, Rennio Felix & Machado, Ricardo Antonio F, 2020. "Insights into the bioenergy potential of jackfruit wastes considering their physicochemical properties, bioenergy indicators, combustion behaviors, and emission characteristics," Renewable Energy, Elsevier, vol. 155(C), pages 1328-1338.
    7. Shengguo Zhao & Liang Ding & Yun Ruan & Bin Bai & Zegang Qiu & Zhiqin Li, 2021. "Experimental and Kinetic Studies on Steam Gasification of a Biomass Char," Energies, MDPI, vol. 14(21), pages 1-23, November.
    8. Cristina Moliner & Filippo Marchelli & Barbara Bosio & Elisabetta Arato, 2017. "Modelling of Spouted and Spout-Fluid Beds: Key for Their Successful Scale Up," Energies, MDPI, vol. 10(11), pages 1-39, October.
    9. Filippo Marchelli & Giorgio Rovero & Massimo Curti & Elisabetta Arato & Barbara Bosio & Cristina Moliner, 2021. "An Integrated Approach to Convert Lignocellulosic and Wool Residues into Balanced Fertilisers," Energies, MDPI, vol. 14(2), pages 1-15, January.
    10. Cortazar, M. & Lopez, G. & Alvarez, J. & Amutio, M. & Bilbao, J. & Olazar, M., 2018. "Advantages of confining the fountain in a conical spouted bed reactor for biomass steam gasification," Energy, Elsevier, vol. 153(C), pages 455-463.
    11. González-Vázquez, M.P. & García, R. & Gil, M.V. & Pevida, C. & Rubiera, F., 2018. "Unconventional biomass fuels for steam gasification: Kinetic analysis and effect of ash composition on reactivity," Energy, Elsevier, vol. 155(C), pages 426-437.

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