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Syngas production from co-pyrolysis and co-gasification of polystyrene and paper with CO2

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  • Déparrois, N.
  • Singh, P.
  • Burra, K.G.
  • Gupta, A.K.

Abstract

Co-pyrolysis and CO2 co-gasification of paper and polystyrene blends in different mixture ratios were studied at 1173 K using a laboratory scale tube reactor and thermogravimetric analysis. The chemical composition and yield of the syngas produced was analyzed by a micro gas chromatograph to understand the influence of mixture components. Co-pyrolysis positively impacted the syngas yield exhibiting a synergistic influence on cracking reactions leading to increased gaseous yield having almost double the amounts of hydrogen yield. Co-gasification using CO2 increased the total gas yield with enhanced synergistic conversion. This effect provided a non-linear impact on the combustible gases in the gaseous yields when compared to the separate gasification of these feedstocks. The synergistic enhancement of co-pyrolysis conversion in paper-polystyrene led to lower char present for CO2 to react during CO2 co-gasification that lead to lower CO during the gasification of this blended char residue. The mixtures of paper with polystyrene provided increased product gas yields and enhanced conversion with an increase in polystyrene content. The results showed the effectiveness of producing high energy density syngas from co-gasification which can alleviate material handling issues present in segregation of waste, such as plastics and biomass providing uniform valuable product from diverse waste feedstocks with minimal need for classification.

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  • Déparrois, N. & Singh, P. & Burra, K.G. & Gupta, A.K., 2019. "Syngas production from co-pyrolysis and co-gasification of polystyrene and paper with CO2," Applied Energy, Elsevier, vol. 246(C), pages 1-10.
    • Handle: RePEc:eee:appene:v:246:y:2019:i:c:p:1-10
    DOI: 10.1016/j.apenergy.2019.04.013
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    1. Luo, Siyi & Zhou, Yangmin & Yi, Chuijie, 2012. "Syngas production by catalytic steam gasification of municipal solid waste in fixed-bed reactor," Energy, Elsevier, vol. 44(1), pages 391-395.
    2. Ramos, Ana & Monteiro, Eliseu & Silva, Valter & Rouboa, Abel, 2018. "Co-gasification and recent developments on waste-to-energy conversion: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 380-398.
    3. Wong, S.L. & Ngadi, N. & Abdullah, T.A.T. & Inuwa, I.M., 2015. "Current state and future prospects of plastic waste as source of fuel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1167-1180.
    4. Ahmed, I.I. & Nipattummakul, N. & Gupta, A.K., 2011. "Characteristics of syngas from co-gasification of polyethylene and woodchips," Applied Energy, Elsevier, vol. 88(1), pages 165-174, January.
    5. Ahmed, I. & Gupta, A.K., 2009. "Syngas yield during pyrolysis and steam gasification of paper," Applied Energy, Elsevier, vol. 86(9), pages 1813-1821, September.
    6. Kunwar, Bidhya & Cheng, H.N. & Chandrashekaran, Sriram R & Sharma, Brajendra K, 2016. "Plastics to fuel: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 421-428.
    7. Burra, K.G. & Gupta, A.K., 2018. "Kinetics of synergistic effects in co-pyrolysis of biomass with plastic wastes," Applied Energy, Elsevier, vol. 220(C), pages 408-418.
    8. Burra, K.G. & Gupta, A.K., 2018. "Synergistic effects in steam gasification of combined biomass and plastic waste mixtures," Applied Energy, Elsevier, vol. 211(C), pages 230-236.
    9. Parthasarathy, Prakash & Narayanan, K. Sheeba, 2014. "Hydrogen production from steam gasification of biomass: Influence of process parameters on hydrogen yield – A review," Renewable Energy, Elsevier, vol. 66(C), pages 570-579.
    10. Ahmed, I. & Gupta, A.K., 2009. "Characteristics of cardboard and paper gasification with CO2," Applied Energy, Elsevier, vol. 86(12), pages 2626-2634, December.
    11. Nipattummakul, Nimit & Ahmed, Islam & Kerdsuwan, Somrat & Gupta, Ashwani K., 2010. "High temperature steam gasification of wastewater sludge," Applied Energy, Elsevier, vol. 87(12), pages 3729-3734, December.
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