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Sugarcane bagasse gasification: Global reaction mechanism of syngas evolution

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  • Ahmed, I.I.
  • Gupta, A.K.

Abstract

Steam gasification of sugarcane bagasse has been investigated. A semi batch reactor with a fixed amount of sugarcane bagasse sample placed in steady flow of high temperature steam at atmospheric pressure has been used. The gasification of bagasse was examined at reactor and steam temperatures of 800, 900 and 1000°C. The evolution of syngas flow rate and chemical composition has been monitored. The evolution of chemical composition and total flow rate of the syngas has been used to formulate a global reaction mechanism. The mechanism combines pyrolysis reaction mechanisms from the literature and steam gasification/reforming reactions. Steam gasification steps include steam–hydrocarbons reforming, char gasification and water gas shift reactions. Evidence of fragmentation, secondary ring opening reactions and tertiary reactions resulting in formation of gaseous hydrocarbons is supported by higher flow rates of syngas and hydrogen at high heating rates and high reactor temperatures. Increase in carbon monoxide flow rate at the expense of carbon dioxide flow rate with the increase in reactor temperature has been observed. This increase in the ratio of CO/CO2 flow rate confirms the production of CO and CO2 from the competing reaction routes. At 1000°C gasification a total merging between the pyrolysis step and the char gasification step has been observed. This is attributed to acceleration of char gasification reactions and acceleration of steam–hydrocarbons reforming reactions. These hydrocarbons are the precursors to char formation by aromatization and repolymerization.

Suggested Citation

  • Ahmed, I.I. & Gupta, A.K., 2012. "Sugarcane bagasse gasification: Global reaction mechanism of syngas evolution," Applied Energy, Elsevier, vol. 91(1), pages 75-81.
    • Handle: RePEc:eee:appene:v:91:y:2012:i:1:p:75-81
    DOI: 10.1016/j.apenergy.2011.07.001
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    1. Pellegrini, Luiz Felipe & de Oliveira, Silvio, 2007. "Exergy analysis of sugarcane bagasse gasification," Energy, Elsevier, vol. 32(4), pages 314-327.
    2. Ahmed, I.I. & Nipattummakul, N. & Gupta, A.K., 2011. "Characteristics of syngas from co-gasification of polyethylene and woodchips," Applied Energy, Elsevier, vol. 88(1), pages 165-174, January.
    3. Ahmed, I. & Gupta, A.K., 2009. "Syngas yield during pyrolysis and steam gasification of paper," Applied Energy, Elsevier, vol. 86(9), pages 1813-1821, September.
    4. Ahmed, I. & Gupta, A.K., 2009. "Evolution of syngas from cardboard gasification," Applied Energy, Elsevier, vol. 86(9), pages 1732-1740, September.
    5. Ahmed, I. & Gupta, A.K., 2009. "Characteristics of cardboard and paper gasification with CO2," Applied Energy, Elsevier, vol. 86(12), pages 2626-2634, December.
    6. Ahmed, I.I. & Gupta, A.K., 2010. "Pyrolysis and gasification of food waste: Syngas characteristics and char gasification kinetics," Applied Energy, Elsevier, vol. 87(1), pages 101-108, January.
    7. Nipattummakul, Nimit & Ahmed, Islam & Kerdsuwan, Somrat & Gupta, Ashwani K., 2010. "High temperature steam gasification of wastewater sludge," Applied Energy, Elsevier, vol. 87(12), pages 3729-3734, December.
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