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Synergistic effects during co-pyrolysis and co-gasification of polypropylene and polystyrene

Author

Listed:
  • Li, Jinhu
  • Ye, Xinhao
  • Burra, Kiran G.
  • Lu, Wei
  • Wang, Zhiwei
  • Liu, Xuan
  • Gupta, Ashwani K.

Abstract

The thermal conversion of waste plastic products can provide a promising solution to the issues of environmental pollution, waste management, and energy needs. However, our present understanding on the thermal reforming of different kinds of plastic wastes mixtures during their co-pyrolysis and co-gasification for syngas production and energy recovery is insufficient. Non-selective urban polypropylene (PP) and polystyrene (PS) waste plastics were chosen for the investigations reported here. Thermal degradation properties of PP and PS as well as their blends in different mass ratios were investigated via thermogravimetric (TG) analysis. Co-pyrolysis and CO2-assisted co-gasification of PP-PS blends were then conducted using a fixed-bed reactor at a temperature of 1173 K. Experimental results from the blends were then compared with the weighted value calculated from their component feedstocks to quantify the degree of synergistic effect. TG results showed that the co-treatment of PP and PS enhanced the respective devolatilization process. The co-pyrolysis of PP and PS enhanced their thermal cracking, leading to synergistic increases in the yields of H2, light hydrocarbons (HC) and total syngas. In co-gasification, the reforming reaction involving CO2 was synergistically enhanced, resulting in the increased yields of H2 and HC. The gasification reactivity of carbon black improved during the co-processing of PP and PS due to the synergistic effect between the two different kinds of plastics. Higher synergistic effects were observed from the plastic mixtures having higher PS content that resulted in increased yield of syngas. Co-gasification of PP-PS blends having 40% PP content (2P3S) exhibited the maximum synergistic effect on H2, CO, and total syngas showing increased yields by 88.8%, 77.7%, and 74.2% respectively. The lowest synergistic effect was observed for HC that showed increased yield of only 25.1%. The optimal CO2 consumption was also observed from the co-gasification of 2P3S. Each gram of 2P3S feedstock consumed approximately 1.80 g of CO2 to result in highest recovered energy of 27.49 kJ/g and the maximum overall energy efficiency of 43.2%. The results revealed that enhanced thermal cracking and CO2 reforming reaction, along with the improved reactivity of carbon black were mainly responsible for increased yields of H2, HC, CO and total syngas during co-gasification. This study contributes to the fundamental understanding of co-processing of non-separated waste plastics for enhanced syngas production and energy recovery, elucidating the synergistic effect between the various kinds of plastics during their co-pyrolysis and co-gasification.

Suggested Citation

  • Li, Jinhu & Ye, Xinhao & Burra, Kiran G. & Lu, Wei & Wang, Zhiwei & Liu, Xuan & Gupta, Ashwani K., 2023. "Synergistic effects during co-pyrolysis and co-gasification of polypropylene and polystyrene," Applied Energy, Elsevier, vol. 336(C).
    • Handle: RePEc:eee:appene:v:336:y:2023:i:c:s0306261923001149
    DOI: 10.1016/j.apenergy.2023.120750
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    as
    1. Chen, Zhaohui & Li, Yunjia & Lai, Dengguo & Geng, Sulong & Zhou, Qi & Gao, Shiqiu & Xu, Guangwen, 2018. "Coupling coal pyrolysis with char gasification in a multi-stage fluidized bed to co-produce high-quality tar and syngas," Applied Energy, Elsevier, vol. 215(C), pages 348-355.
    2. Wong, S.L. & Ngadi, N. & Abdullah, T.A.T. & Inuwa, I.M., 2015. "Current state and future prospects of plastic waste as source of fuel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1167-1180.
    3. Singh, P. & Déparrois, N. & Burra, K.G. & Bhattacharya, S. & Gupta, A.K., 2019. "Energy recovery from cross-linked polyethylene wastes using pyrolysis and CO2 assisted gasification," Applied Energy, Elsevier, vol. 254(C).
    4. Lahijani, Pooya & Zainal, Zainal Alimuddin & Mohammadi, Maedeh & Mohamed, Abdul Rahman, 2015. "Conversion of the greenhouse gas CO2 to the fuel gas CO via the Boudouard reaction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 615-632.
    5. Déparrois, N. & Singh, P. & Burra, K.G. & Gupta, A.K., 2019. "Syngas production from co-pyrolysis and co-gasification of polystyrene and paper with CO2," Applied Energy, Elsevier, vol. 246(C), pages 1-10.
    6. Burra, K.G. & Gupta, A.K., 2018. "Synergistic effects in steam gasification of combined biomass and plastic waste mixtures," Applied Energy, Elsevier, vol. 211(C), pages 230-236.
    7. Ahmed, I.I. & Gupta, A.K., 2013. "Experiments and stochastic simulations of lignite coal during pyrolysis and gasification," Applied Energy, Elsevier, vol. 102(C), pages 355-363.
    8. Liu, Xuan & Burra, Kiran G. & Wang, Zhiwei & Li, Jinhu & Che, Defu & Gupta, Ashwani K., 2020. "On deconvolution for understanding synergistic effects in co-pyrolysis of pinewood and polypropylene," Applied Energy, Elsevier, vol. 279(C).
    9. Li, Jinhu & Burra, Kiran Raj G. & Wang, Zhiwei & Liu, Xuan & Gupta, Ashwani K., 2021. "Co-gasification of high-density polyethylene and pretreated pine wood," Applied Energy, Elsevier, vol. 285(C).
    10. Parthasarathy, Prakash & Narayanan, K. Sheeba, 2014. "Hydrogen production from steam gasification of biomass: Influence of process parameters on hydrogen yield – A review," Renewable Energy, Elsevier, vol. 66(C), pages 570-579.
    11. Policella, Matteo & Wang, Zhiwei & Burra, Kiran. G. & Gupta, Ashwani K., 2019. "Characteristics of syngas from pyrolysis and CO2-assisted gasification of waste tires," Applied Energy, Elsevier, vol. 254(C).
    12. Wang, Zhiwei & Burra, Kiran G. & Zhang, Mengju & Li, Xueqin & He, Xiaofeng & Lei, Tingzhou & Gupta, Ashwani K., 2020. "Syngas evolution and energy efficiency in CO2-assisted gasification of pine bark," Applied Energy, Elsevier, vol. 269(C).
    13. Ahmed, I. & Gupta, A.K., 2009. "Evolution of syngas from cardboard gasification," Applied Energy, Elsevier, vol. 86(9), pages 1732-1740, September.
    14. Park, Ki-Bum & Jeong, Yong-Seong & Kim, Joo-Sik, 2019. "Activator-assisted pyrolysis of polypropylene," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    15. Liu, Xuan & Burra, Kiran Raj G. & Wang, Zhiwei & Li, Jinhu & Che, Defu & Gupta, Ashwani K., 2021. "Towards enhanced understanding of synergistic effects in co-pyrolysis of pinewood and polycarbonate," Applied Energy, Elsevier, vol. 289(C).
    16. Ahmed, I. & Gupta, A.K., 2009. "Characteristics of cardboard and paper gasification with CO2," Applied Energy, Elsevier, vol. 86(12), pages 2626-2634, December.
    17. Bellomare, Filippo & Rokni, Masoud, 2013. "Integration of a municipal solid waste gasification plant with solid oxide fuel cell and gas turbine," Renewable Energy, Elsevier, vol. 55(C), pages 490-500.
    18. Zhang, Yayun & Duan, Dengle & Lei, Hanwu & Villota, Elmar & Ruan, Roger, 2019. "Jet fuel production from waste plastics via catalytic pyrolysis with activated carbons," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
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