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Thermal modelling of ethanol-fuelled Solid Oxide Fuel Cells

Author

Listed:
  • Chen, Bin
  • Xu, Haoran
  • Tan, Peng
  • Zhang, Yuan
  • Xu, Xiaoming
  • Cai, Weizi
  • Chen, Meina
  • Ni, Meng

Abstract

A 2D thermal model is developed to investigate an ethanol-fuelled Solid Oxide Fuel Cells (E-SOFC) with a Ni-ZrO2/CeO2 functional layer for internal reforming of ethanol. The catalytic kinetics of the functional layer used in this model is validated in terms of ethanol conversion and product selectivity in the experimental data of a fixed-bed testing reactor. The simulated E-SOFC demonstrates a typical performance of 4385.6 A m−2 at 0.6 V, corresponding to a power density of 2631.4 W m−2, with a high conversion ratio of ethanol (0.903) at 700 °C. Parametric studies of voltage, water to ethanol ratio and inlet fuel gas temperature are conducted and comprehensively analysed, concluding that the positive effects of lowering the voltage and increasing the inlet temperature on the ethanol conversion. We find that adding the reforming layer is a facile and effective way to replace the conventional H2 by abundant-in-nature ethanol for SOFC from the numerical analysis. Attention is also drawn to the carbon deposition risk by thermodynamic analysis of the gas composition, suggesting to keep the water to ethanol ratio higher than 3. The as-developed model can serve as an effective tool for the optimization of the operating conditions and geometry design to avoid carbon deposition and improve the performance of ethanol-fuelled Solid Oxide Fuel Cells.

Suggested Citation

  • Chen, Bin & Xu, Haoran & Tan, Peng & Zhang, Yuan & Xu, Xiaoming & Cai, Weizi & Chen, Meina & Ni, Meng, 2019. "Thermal modelling of ethanol-fuelled Solid Oxide Fuel Cells," Applied Energy, Elsevier, vol. 237(C), pages 476-486.
    • Handle: RePEc:eee:appene:v:237:y:2019:i:c:p:476-486
    DOI: 10.1016/j.apenergy.2019.01.025
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    References listed on IDEAS

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    1. Chen, Xiaoguang & Khanna, Madhu, 2018. "Effect of corn ethanol production on Conservation Reserve Program acres in the US," Applied Energy, Elsevier, vol. 225(C), pages 124-134.
    2. Xu, Youjie & Wang, Donghai, 2017. "Integrating starchy substrate into cellulosic ethanol production to boost ethanol titers and yields," Applied Energy, Elsevier, vol. 195(C), pages 196-203.
    3. Steil, M.C. & Nobrega, S.D. & Georges, S. & Gelin, P. & Uhlenbruck, S. & Fonseca, F.C., 2017. "Durable direct ethanol anode-supported solid oxide fuel cell," Applied Energy, Elsevier, vol. 199(C), pages 180-186.
    4. Chen, Bin & Xu, Haoran & Ni, Meng, 2017. "Modelling of SOEC-FT reactor: Pressure effects on methanation process," Applied Energy, Elsevier, vol. 185(P1), pages 814-824.
    5. Khanna, M., 2018. "Effect of Corn Ethanol Production on Conservation Reserve Program Acres in the US," 2018 Conference, July 28-August 2, 2018, Vancouver, British Columbia 277014, International Association of Agricultural Economists.
    6. Chen, Bin & Xu, Haoran & Zhang, Houcheng & Tan, Peng & Cai, Weizi & Ni, Meng, 2017. "A novel design of solid oxide electrolyser integrated with magnesium hydride bed for hydrogen generation and storage – A dynamic simulation study," Applied Energy, Elsevier, vol. 200(C), pages 260-272.
    7. Cinti, Giovanni & Desideri, Umberto, 2015. "SOFC fuelled with reformed urea," Applied Energy, Elsevier, vol. 154(C), pages 242-253.
    8. Perna, A. & Minutillo, M. & Jannelli, E. & Cigolotti, V. & Nam, S.W. & Han, J., 2018. "Design and performance assessment of a combined heat, hydrogen and power (CHHP) system based on ammonia-fueled SOFC," Applied Energy, Elsevier, vol. 231(C), pages 1216-1229.
    9. Osmieri, Luigi & Escudero-Cid, Ricardo & Monteverde Videla, Alessandro H.A. & Ocón, Pilar & Specchia, Stefania, 2018. "Application of a non-noble Fe-N-C catalyst for oxygen reduction reaction in an alkaline direct ethanol fuel cell," Renewable Energy, Elsevier, vol. 115(C), pages 226-237.
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    4. Wu, Zhen & Tan, Peng & Chen, Bin & Cai, Weizi & Chen, Meina & Xu, Xiaoming & Zhang, Zaoxiao & Ni, Meng, 2019. "Dynamic modeling and operation strategy of an NG-fueled SOFC-WGS-TSA-PEMFC hybrid energy conversion system for fuel cell vehicle by using MATLAB/SIMULINK," Energy, Elsevier, vol. 175(C), pages 567-579.
    5. Abdellah Essaghouri & Zezhi Zeng & Bingguo Zhao & Changkun Hao & Yuping Qian & Weilin Zhuge & Yangjun Zhang, 2022. "Effects of Radial and Circumferential Flows on Power Density Improvements of Tubular Solid Oxide Fuel Cells," Energies, MDPI, vol. 15(19), pages 1-21, September.
    6. Wang, Chaoyang & Chen, Ming & Liu, Ming & Yan, Junjie, 2020. "Dynamic modeling and parameter analysis study on reversible solid oxide cells during mode switching transient processes," Applied Energy, Elsevier, vol. 263(C).
    7. Xiao-Long Wu & Hong Zhang & Hongli Liu & Yuan-Wu Xu & Jingxuan Peng & Zhiping Xia & Yongan Wang, 2022. "Modeling Analysis of SOFC System Oriented to Working Condition Identification," Energies, MDPI, vol. 15(5), pages 1-19, February.
    8. Yang, Yang & Liu, Fangsheng & Han, Xu & Wang, Xinxin & Dong, Dehua & Chen, Yan & Feng, Peizhong & Khan, Majid & Wang, Shaorong & Ling, Yihan, 2022. "Highly efficient and stable fuel-catalyzed dendritic microchannels for dilute ethanol fueled solid oxide fuel cells," Applied Energy, Elsevier, vol. 307(C).
    9. Zhu, Pengfei & Wu, Zhen & Yang, Yuchen & Wang, Huan & Li, Ruiqing & Yang, Fusheng & Zhang, Zaoxiao, 2023. "The dynamic response of solid oxide fuel cell fueled by syngas during the operating condition variations," Applied Energy, Elsevier, vol. 349(C).
    10. Li, Bangxin & Irvine, John T.S. & Ni, Jiupai & Ni, Chengsheng, 2022. "High-performance and durable alcohol-fueled symmetrical solid oxide fuel cell based on ferrite perovskite electrode," Applied Energy, Elsevier, vol. 306(PB).
    11. Mendiburu, Andrés Z. & Lauermann, Carlos H. & Hayashi, Thamy C. & Mariños, Diego J. & Rodrigues da Costa, Roberto Berlini & Coronado, Christian J.R. & Roberts, Justo J. & de Carvalho, João A., 2022. "Ethanol as a renewable biofuel: Combustion characteristics and application in engines," Energy, Elsevier, vol. 257(C).
    12. Abdellah Essaghouri & Zezhi Zeng & Bingguo Zhao & Changkun Hao & Yuping Qian & Weilin Zhuge & Yangjun Zhang, 2022. "Influence of Radial Flows on Power Density and Gas Stream Pressure Drop of Tubular Solid Oxide Fuel Cells," Energies, MDPI, vol. 15(21), pages 1-21, October.
    13. Guo, Meiting & Ru, Xiao & Yang, Lin & Ni, Meng & Lin, Zijing, 2022. "Effects of methane steam reforming on the mechanical stability of solid oxide fuel cell stack," Applied Energy, Elsevier, vol. 322(C).

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