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Application of a non-noble Fe-N-C catalyst for oxygen reduction reaction in an alkaline direct ethanol fuel cell

Author

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  • Osmieri, Luigi
  • Escudero-Cid, Ricardo
  • Monteverde Videla, Alessandro H.A.
  • Ocón, Pilar
  • Specchia, Stefania

Abstract

A Fe-N-C non-noble metal (NNM) catalyst for oxygen reduction reaction (ORR) was prepared via hard templating method using Fe(II)-phthalocyanine. Its electrochemical behavior towards the ORR was tested in alkaline conditions using cyclic voltammetry (CV) and rotating disk electrode (RDE) techniques. The kinetics of the reduction of the adsorbed oxygen, the selectivity, and the activity towards hydrogen peroxide reduction reaction (HPRR) were investigated. The ethanol tolerance and the stability in alkaline conditions were also assessed with the purpose to verify the good potentiality of this catalyst to be used in an alkaline direct ethanol fuel cell (DEFC). The results evidence that the ORR occurs mainly following the direct 4 e– reduction to OH−, and that the Fe-N-C catalyst is highly ethanol tolerant and shows a promising stability. The alkaline DEFC tests, performed after the optimization of the ionomer amount used for the preparation of the catalyst ink, show good results at low-intermediate currents, with a maximum power density of 62 mW cm−2. The initial DEFC performance can be partially recovered after a purge-drying procedure.

Suggested Citation

  • Osmieri, Luigi & Escudero-Cid, Ricardo & Monteverde Videla, Alessandro H.A. & Ocón, Pilar & Specchia, Stefania, 2018. "Application of a non-noble Fe-N-C catalyst for oxygen reduction reaction in an alkaline direct ethanol fuel cell," Renewable Energy, Elsevier, vol. 115(C), pages 226-237.
    • Handle: RePEc:eee:renene:v:115:y:2018:i:c:p:226-237
    DOI: 10.1016/j.renene.2017.08.062
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    References listed on IDEAS

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    1. An, L. & Zhao, T.S. & Li, Y.S., 2015. "Carbon-neutral sustainable energy technology: Direct ethanol fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1462-1468.
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    3. Benipal, Neeva & Qi, Ji & Gentile, Jacob C. & Li, Wenzhen, 2017. "Direct glycerol fuel cell with polytetrafluoroethylene (PTFE) thin film separator," Renewable Energy, Elsevier, vol. 105(C), pages 647-655.
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    2. Chen, Bin & Xu, Haoran & Tan, Peng & Zhang, Yuan & Xu, Xiaoming & Cai, Weizi & Chen, Meina & Ni, Meng, 2019. "Thermal modelling of ethanol-fuelled Solid Oxide Fuel Cells," Applied Energy, Elsevier, vol. 237(C), pages 476-486.
    3. Fathabadi, Hassan, 2019. "Combining a proton exchange membrane fuel cell (PEMFC) stack with a Li-ion battery to supply the power needs of a hybrid electric vehicle," Renewable Energy, Elsevier, vol. 130(C), pages 714-724.
    4. Luque-Centeno, J.M. & Martínez-Huerta, M.V. & Sebastián, D. & Lemes, G. & Pastor, E. & Lázaro, M.J., 2018. "Bifunctional N-doped graphene Ti and Co nanocomposites for the oxygen reduction and evolution reactions," Renewable Energy, Elsevier, vol. 125(C), pages 182-192.
    5. Ingabire, Providence Buregeya & Pan, Xueting & Haragirimana, Alphonse & Li, Na & Hu, Zhaoxia & Chen, Shouwen, 2020. "Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells," Renewable Energy, Elsevier, vol. 152(C), pages 590-600.

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