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A critical review on surface-pattern engineering of nafion membrane for fuel cell applications

Author

Listed:
  • Ke, Yuzhi
  • Yuan, Wei
  • Zhou, Feikun
  • Guo, Wenwen
  • Li, Jinguang
  • Zhuang, Ziyi
  • Su, Xiaoqing
  • Lu, Biaowu
  • Zhao, Yonghao
  • Tang, Yong
  • Chen, Yu
  • Song, Jianli

Abstract

Surface-pattern engineering, as a key strategy to fabricate high-performance Nafion membranes for fuel cells, plays an important role in surface functionalization of the membrane, optimization of the three-phase boundary, water management, proton transport, etc. Considerable efforts have been dedicated to developing advanced-patterned Nafion membranes with single-scale (nanoscale or microscale) and multiscale-patterned structures which are believed to improve the performance of membrane electrode assemblies (MEAs) for fuel cells. In this review, the recent progress in surface-patterned Nafion membranes (SPNMs) equipped with single-scale-patterned structures (including nanostructured and microstructured Nafion membranes) is firstly highlighted. The structural features and construction methods of SPNMs are discussed in detail. The effects of single-scale SPNMs on the construction and performance of fuel cells are also analyzed. Followed is an overview of the recent advances in fabricating multiscale SPNMs based on different strategies with a specific introduction on the membrane related effects on fuel cells. Finally, the future development direction and certain perspectives on the current issues of SPNMs are presented.

Suggested Citation

  • Ke, Yuzhi & Yuan, Wei & Zhou, Feikun & Guo, Wenwen & Li, Jinguang & Zhuang, Ziyi & Su, Xiaoqing & Lu, Biaowu & Zhao, Yonghao & Tang, Yong & Chen, Yu & Song, Jianli, 2021. "A critical review on surface-pattern engineering of nafion membrane for fuel cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
  • Handle: RePEc:eee:rensus:v:145:y:2021:i:c:s1364032121001544
    DOI: 10.1016/j.rser.2021.110860
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    Cited by:

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    2. Teixeira, Fátima C. & Teixeira, António P.S. & Rangel, C.M., 2022. "New proton conductive membranes of indazole- and condensed pyrazolebisphosphonic acid-Nafion membranes for PEMFC," Renewable Energy, Elsevier, vol. 196(C), pages 1187-1196.
    3. Ke, Yuzhi & Zhang, Baotong & Bai, Yafeng & Yuan, Wei & Li, Jinguang & Liu, Ziang & Su, Xiaoqing & Zhang, Shiwei & Ding, Xinrui & Wan, Zhenping & Tang, Yong & Zhou, Feikun, 2023. "Bubble-derived contour regeneration of flow channel by in situ tracking for direct methanol fuel cells," Energy, Elsevier, vol. 264(C).

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