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Effect of nano-size of functionalized silica on overall performance of swelling-filling modified Nafion membrane for direct methanol fuel cell application

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  • Li, Jing
  • Xu, Guoxiao
  • Luo, Xingying
  • Xiong, Jie
  • Liu, Zhao
  • Cai, Weiwei

Abstract

A non-destructive swelling-filling (SF) strategy is applied for inorganic modification on Nafion by using functionalized silica (F-silica) nanoparticles as fillers. With the facilely prepared F-silica gel as SF treating agent, the mono-dispersed F-silica nanoparticles can in-situ insert into the Nafion membrane and tightly anchor on the Nafion chains through the hydrogen bonding interaction between the oxygen containing groups on F-silica fillers and –SO3H group on Nafion chains. The F-silica nanoparticles act as bi-functional fillers in the modified Nafion membrane to improve proton conductive and methanol-permeation resistive performances simultaneously. 100% enhanced proton/methanol selectivity therefore leads to a more than 30% improved direct methanol fuel cell (DMFC) performance in terms of power output. By considering the great mechanical, thermal and oxidative stabilities comprehensively, the F-silica-Nafion membranes exhibit promising application potential for high-energy DMFC application.

Suggested Citation

  • Li, Jing & Xu, Guoxiao & Luo, Xingying & Xiong, Jie & Liu, Zhao & Cai, Weiwei, 2018. "Effect of nano-size of functionalized silica on overall performance of swelling-filling modified Nafion membrane for direct methanol fuel cell application," Applied Energy, Elsevier, vol. 213(C), pages 408-414.
    • Handle: RePEc:eee:appene:v:213:y:2018:i:c:p:408-414
    DOI: 10.1016/j.apenergy.2018.01.052
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    1. Guoxiao Xu & Xinwei Dong & Bin Xue & Jianyou Huang & Junli Wu & Weiwei Cai, 2023. "Recent Approaches to Achieve High Temperature Operation of Nafion Membranes," Energies, MDPI, vol. 16(4), pages 1-21, February.
    2. Jiang, Jinghui & Li, Yinshi & Liang, Jiarong & Yang, Weiwei & Li, Xianglin, 2019. "Modeling of high-efficient direct methanol fuel cells with order-structured catalyst layer," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    3. Xu, Guoxiao & Wu, Zhiguang & Wei, Zenglv & Zhang, Wenjie & Wu, Junli & Li, Ying & Li, Jing & Qu, Konggang & Cai, Weiwei, 2020. "Non-destructive fabrication of Nafion/silica composite membrane via swelling-filling modification strategy for high temperature and low humidity PEM fuel cell," Renewable Energy, Elsevier, vol. 153(C), pages 935-939.
    4. Zhou, Jing & Cao, Jiamu & Zhang, Yufeng & Liu, Junfeng & Chen, Junyu & Li, Mingxue & Wang, Weiqi & Liu, Xiaowei, 2021. "Overcoming undesired fuel crossover: Goals of methanol-resistant modification of polymer electrolyte membranes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    5. Ke, Yuzhi & Yuan, Wei & Zhou, Feikun & Guo, Wenwen & Li, Jinguang & Zhuang, Ziyi & Su, Xiaoqing & Lu, Biaowu & Zhao, Yonghao & Tang, Yong & Chen, Yu & Song, Jianli, 2021. "A critical review on surface-pattern engineering of nafion membrane for fuel cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    6. Zhao, Chen & Wang, Fei & Wu, Xiaoyu, 2024. "Analysis and review on air-cooled open cathode proton exchange membrane fuel cells: Bibliometric, environmental adaptation and prospect," Renewable and Sustainable Energy Reviews, Elsevier, vol. 197(C).
    7. Xu, Jingmei & Zhang, Zhenguo & Yang, Kai & Zhang, Huixuan & Wang, Zhe, 2019. "Synthesis and properties of novel cross-linked composite sulfonated poly (aryl ether ketone sulfone) containing multiple sulfonic side chains for high-performance proton exchange membranes," Renewable Energy, Elsevier, vol. 138(C), pages 1104-1113.

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