IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v138y2019icp1104-1113.html
   My bibliography  Save this article

Synthesis and properties of novel cross-linked composite sulfonated poly (aryl ether ketone sulfone) containing multiple sulfonic side chains for high-performance proton exchange membranes

Author

Listed:
  • Xu, Jingmei
  • Zhang, Zhenguo
  • Yang, Kai
  • Zhang, Huixuan
  • Wang, Zhe

Abstract

The synthesis and properties of novel cross-linked composite sulfonated poly (aryl ether ketone sulfone) containing multiple sulfonic side chains as proton exchange membranes were investigated. The multiple side-chain membranes were prepared by direct polycondensation and simple free radical reaction. The cross-linked composite membranes were prepared by solvent coating method. The prepared membranes showed lower water absorption and swelling ratio than that of Nafion 117. The S-Am-2.0/C exhibited the highest proton conductivity of 0.135 S cm−1 at 80 °C, while its swelling ratio was only 3.59% at the same temperature. Much lower methanol permeability coefficients in the range of 3.11 × 10−8 cm2 s−1–7.25 × 10−7 cm2 s−1 compared to Nafion 117 (2.29 × 10−6 cm2 s−1) were also observed for the prepared membranes. Moreover, the S-Am-2.0/C exhibited higher peak power density (121.09 mW cm−2) than that of main-chain type C-SPAEKS membrane (66.65 mW cm−2). The results indicate that the cross-linked composite membranes are good candidate for fuel cells.

Suggested Citation

  • Xu, Jingmei & Zhang, Zhenguo & Yang, Kai & Zhang, Huixuan & Wang, Zhe, 2019. "Synthesis and properties of novel cross-linked composite sulfonated poly (aryl ether ketone sulfone) containing multiple sulfonic side chains for high-performance proton exchange membranes," Renewable Energy, Elsevier, vol. 138(C), pages 1104-1113.
    • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:1104-1113
    DOI: 10.1016/j.renene.2019.02.042
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119301934
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.02.042?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ahmadian-Alam, Leila & Mahdavi, Hossein, 2018. "A novel polysulfone-based ternary nanocomposite membrane consisting of metal-organic framework and silica nanoparticles: As proton exchange membrane for polymer electrolyte fuel cells," Renewable Energy, Elsevier, vol. 126(C), pages 630-639.
    2. Li, Jing & Xu, Guoxiao & Luo, Xingying & Xiong, Jie & Liu, Zhao & Cai, Weiwei, 2018. "Effect of nano-size of functionalized silica on overall performance of swelling-filling modified Nafion membrane for direct methanol fuel cell application," Applied Energy, Elsevier, vol. 213(C), pages 408-414.
    3. Ozden, Adnan & Shahgaldi, Samaneh & Li, Xianguo & Hamdullahpur, Feridun, 2018. "A graphene-based microporous layer for proton exchange membrane fuel cells: Characterization and performance comparison," Renewable Energy, Elsevier, vol. 126(C), pages 485-494.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Xiaoqing & Yang, Jiapei & Ma, Xiao & Zhuge, Weilin & Shuai, Shijin, 2022. "Modelling and analysis on effects of penetration of microporous layer into gas diffusion layer in PEM fuel cells: Focusing on mass transport," Energy, Elsevier, vol. 254(PA).
    2. Xu, Guoxiao & Wu, Zhiguang & Wei, Zenglv & Zhang, Wenjie & Wu, Junli & Li, Ying & Li, Jing & Qu, Konggang & Cai, Weiwei, 2020. "Non-destructive fabrication of Nafion/silica composite membrane via swelling-filling modification strategy for high temperature and low humidity PEM fuel cell," Renewable Energy, Elsevier, vol. 153(C), pages 935-939.
    3. Aldakheel, F. & Ismail, M.S. & Hughes, K.J. & Ingham, D.B. & Ma, L. & Pourkashanian, M. & Cumming, D. & Smith, R., 2020. "Gas permeability, wettability and morphology of gas diffusion layers before and after performing a realistic ex-situ compression test," Renewable Energy, Elsevier, vol. 151(C), pages 1082-1091.
    4. Riccardo Balzarotti & Saverio Latorrata & Marco Mariani & Paola Gallo Stampino & Giovanni Dotelli, 2020. "Optimization of Perfluoropolyether-Based Gas Diffusion Media Preparation for PEM Fuel Cells," Energies, MDPI, vol. 13(7), pages 1-14, April.
    5. Ke, Yuzhi & Yuan, Wei & Zhou, Feikun & Guo, Wenwen & Li, Jinguang & Zhuang, Ziyi & Su, Xiaoqing & Lu, Biaowu & Zhao, Yonghao & Tang, Yong & Chen, Yu & Song, Jianli, 2021. "A critical review on surface-pattern engineering of nafion membrane for fuel cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    6. Jiang, Jinghui & Li, Yinshi & Liang, Jiarong & Yang, Weiwei & Li, Xianglin, 2019. "Modeling of high-efficient direct methanol fuel cells with order-structured catalyst layer," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    7. Guoxiao Xu & Xinwei Dong & Bin Xue & Jianyou Huang & Junli Wu & Weiwei Cai, 2023. "Recent Approaches to Achieve High Temperature Operation of Nafion Membranes," Energies, MDPI, vol. 16(4), pages 1-21, February.
    8. Shahgaldi, Samaneh & Ozden, Adnan & Li, Xianguo & Hamdullahpur, Feridun, 2020. "A scaled-up proton exchange membrane fuel cell with enhanced performance and durability," Applied Energy, Elsevier, vol. 268(C).
    9. Bhosale, Amit C. & Rengaswamy, Raghunathan, 2019. "Interfacial contact resistance in polymer electrolyte membrane fuel cells: Recent developments and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    10. Zhou, Jing & Cao, Jiamu & Zhang, Yufeng & Liu, Junfeng & Chen, Junyu & Li, Mingxue & Wang, Weiqi & Liu, Xiaowei, 2021. "Overcoming undesired fuel crossover: Goals of methanol-resistant modification of polymer electrolyte membranes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    11. Xia, Qi & Zhao, Jianguo & Chen, Chen & Jin, Weiya, 2023. "Modeling of CO2/H2O Co-electrolysis using solar-driven SOEC coupled with ammonia-based chemical heat pump," Renewable Energy, Elsevier, vol. 212(C), pages 128-137.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:138:y:2019:i:c:p:1104-1113. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.