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A scaled-up proton exchange membrane fuel cell with enhanced performance and durability

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  • Shahgaldi, Samaneh
  • Ozden, Adnan
  • Li, Xianguo
  • Hamdullahpur, Feridun

Abstract

A proton exchange membrane fuel cell with enhanced performance and durability has been developed by using graphene for the microporous layer on the cathode side, and short-side-chain ionomer in the catalyst layers and electrolyte membrane layer. The cell components are analyzed for their detailed morphological, microstructural, physical, and electrochemical characteristics, and the performance and durability are investigated following the established protocol of accelerated stress tests for a scaled-up cell with an active area of 45 cm2 at 75 °C and 35 kPag, and a range of reactant flow rate and relative humidity conditions. The results indicate that the graphene flakes are arranged in the in-plane direction of the cell, and coupled with the improved proton conductivity and water retention of the short-side chain ionomer and membrane, the cell exhibits excellent performance and durability, and is highly tolerant to the variations in the operating conditions. Before and after 30,000 cycles of the accelerated stress tests, the maximum power densities are around 1.13 W/cm2 and 0.75 W/cm2 for the high-flow fully humidified reactants, and about 0.77 W/cm2 and 0.50 W/cm2 for the low-flow and low-humidity conditions, respectively. The excellent performance and durability at low relative humidity operation are significantly important for practical applications.

Suggested Citation

  • Shahgaldi, Samaneh & Ozden, Adnan & Li, Xianguo & Hamdullahpur, Feridun, 2020. "A scaled-up proton exchange membrane fuel cell with enhanced performance and durability," Applied Energy, Elsevier, vol. 268(C).
    • Handle: RePEc:eee:appene:v:268:y:2020:i:c:s0306261920304682
    DOI: 10.1016/j.apenergy.2020.114956
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    References listed on IDEAS

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    1. Wu, Horng-Wen, 2016. "A review of recent development: Transport and performance modeling of PEM fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 81-106.
    2. Saverio Latorrata & Paola Gallo Stampino & Cinzia Cristiani & Giovanni Dotelli, 2017. "Performance Evaluation and Durability Enhancement of FEP-Based Gas Diffusion Media for PEM Fuel Cells," Energies, MDPI, vol. 10(12), pages 1-17, December.
    3. Zhao, Jian & Ozden, Adnan & Shahgaldi, Samaneh & Alaefour, Ibrahim E. & Li, Xianguo & Hamdullahpur, Feridun, 2018. "Effect of Pt loading and catalyst type on the pore structure of porous electrodes in polymer electrolyte membrane (PEM) fuel cells," Energy, Elsevier, vol. 150(C), pages 69-76.
    4. Ozden, Adnan & Shahgaldi, Samaneh & Li, Xianguo & Hamdullahpur, Feridun, 2019. "The impact of ionomer type on the morphological and microstructural degradations of proton exchange membrane fuel cell electrodes under freeze-thaw cycles," Applied Energy, Elsevier, vol. 238(C), pages 1048-1059.
    5. Xing, Lei & Shi, Weidong & Su, Huaneng & Xu, Qian & Das, Prodip K. & Mao, Baodong & Scott, Keith, 2019. "Membrane electrode assemblies for PEM fuel cells: A review of functional graded design and optimization," Energy, Elsevier, vol. 177(C), pages 445-464.
    6. Zhao, Jian & Shahgaldi, Samaneh & Alaefour, Ibrahim & Xu, Qian & Li, Xianguo, 2018. "Gas permeability of catalyzed electrodes in polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 209(C), pages 203-210.
    7. Ozen, Dilek Nur & Timurkutluk, Bora & Altinisik, Kemal, 2016. "Effects of operation temperature and reactant gas humidity levels on performance of PEM fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1298-1306.
    8. Majlan, E.H. & Rohendi, D. & Daud, W.R.W. & Husaini, T. & Haque, M.A., 2018. "Electrode for proton exchange membrane fuel cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 117-134.
    9. Wang, Junye, 2017. "System integration, durability and reliability of fuel cells: Challenges and solutions," Applied Energy, Elsevier, vol. 189(C), pages 460-479.
    10. Shahgaldi, Samaneh & Alaefour, Ibrahim & Li, Xianguo, 2018. "The impact of short side chain ionomer on polymer electrolyte membrane fuel cell performance and durability," Applied Energy, Elsevier, vol. 217(C), pages 295-302.
    11. Wu, Horng-Wen & Shih, Gin-Jang & Chen, Yi-Bin, 2018. "Effect of operational parameters on transport and performance of a PEM fuel cell with the best protrusive gas diffusion layer arrangement," Applied Energy, Elsevier, vol. 220(C), pages 47-58.
    12. Ozden, Adnan & Shahgaldi, Samaneh & Li, Xianguo & Hamdullahpur, Feridun, 2018. "A graphene-based microporous layer for proton exchange membrane fuel cells: Characterization and performance comparison," Renewable Energy, Elsevier, vol. 126(C), pages 485-494.
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    Cited by:

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    2. Yang, Yange & Zhou, Xiangyang & Li, Bing & Zhang, Cunman, 2021. "Failure of cathode gas diffusion layer in 1 kW fuel cell stack under new European driving cycle," Applied Energy, Elsevier, vol. 303(C).

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