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Membranes for direct ethanol fuel cells: An overview

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  • Zakaria, Z.
  • Kamarudin, S.K.
  • Timmiati, S.N.

Abstract

Direct ethanol fuel cells (DEFCs) are attractive as a power source options because ethanol is a nontoxic, leading to ease of handling and a high energy density fuel, leading to high system energy density. However, to provide practical DEFCs power source there are several issues that still must be addressed including low power density, effect of ethanol crossover on efficiency of fuel utilization, electrical, mechanical and thermal stability and water uptake of the DEFCs electrolyte membrane. This paper describes the proton exchange membrane and alkaline exchange membrane for DEFCs, focusing on current problems and advancements in DEFC membranes. It also presents the specifications and performances of the membranes used in DEFC.

Suggested Citation

  • Zakaria, Z. & Kamarudin, S.K. & Timmiati, S.N., 2016. "Membranes for direct ethanol fuel cells: An overview," Applied Energy, Elsevier, vol. 163(C), pages 334-342.
    • Handle: RePEc:eee:appene:v:163:y:2016:i:c:p:334-342
    DOI: 10.1016/j.apenergy.2015.10.124
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    1. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
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    Cited by:

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    2. Zakaria, Z. & Kamarudin, S.K., 2016. "Direct conversion technologies of methane to methanol: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 250-261.
    3. Sánchez-Monreal, Juan & García-Salaberri, Pablo A. & Vera, Marcos, 2019. "A mathematical model for direct ethanol fuel cells based on detailed ethanol electro-oxidation kinetics," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    4. Gomes, R.S. & De Bortoli, A.L., 2016. "A three-dimensional mathematical model for the anode of a direct ethanol fuel cell," Applied Energy, Elsevier, vol. 183(C), pages 1292-1301.
    5. Santiago, Óscar & Navarro, Emilio & Raso, Miguel A. & Leo, Teresa J., 2016. "Review of implantable and external abiotically catalysed glucose fuel cells and the differences between their membranes and catalysts," Applied Energy, Elsevier, vol. 179(C), pages 497-522.
    6. Li, Yang & Zhang, Xuelin & Yuan, Weijian & Zhang, Yufeng & Liu, Xiaowei, 2018. "A novel CO2 gas removal design for a micro passive direct methanol fuel cell," Energy, Elsevier, vol. 157(C), pages 599-607.
    7. Li, Jing & Xu, Guoxiao & Luo, Xingying & Xiong, Jie & Liu, Zhao & Cai, Weiwei, 2018. "Effect of nano-size of functionalized silica on overall performance of swelling-filling modified Nafion membrane for direct methanol fuel cell application," Applied Energy, Elsevier, vol. 213(C), pages 408-414.
    8. Wang, Junye, 2017. "System integration, durability and reliability of fuel cells: Challenges and solutions," Applied Energy, Elsevier, vol. 189(C), pages 460-479.
    9. Zhu, Shengdong & Luo, Fang & Huang, Wenjing & Huang, Wangxiang & Wu, Yuanxin, 2017. "Comparison of three fermentation strategies for alleviating the negative effect of the ionic liquid 1-ethyl-3-methylimidazolium acetate on lignocellulosic ethanol production," Applied Energy, Elsevier, vol. 197(C), pages 124-131.
    10. A. C. Gómez-Monsiváis & I. Velázquez-Hernández & L. Álvarez-Contreras & M. Guerra-Balcázar & L. G. Arriaga & N. Arjona & J. Ledesma-García, 2017. "In Situ Surface-Enhanced Raman Spectroscopy Study of the Electrocatalytic Effect of PtFe/C Nanocatalyst on Ethanol Electro-Oxidation in Alkaline Medium," Energies, MDPI, vol. 10(3), pages 1-19, March.
    11. Deng, Hao & Wang, Dawei & Wang, Renfang & Xie, Xu & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Effect of electrode design and operating condition on performance of hydrogen alkaline membrane fuel cell," Applied Energy, Elsevier, vol. 183(C), pages 1272-1278.
    12. Zakaria, Zulfirdaus & Kamarudin, Siti Kartom & Abd Wahid, Khairul Anuar & Abu Hassan, Saiful Hasmady, 2021. "The progress of fuel cell for malaysian residential consumption: Energy status and prospects to introduction as a renewable power generation system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).

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