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Hydrogen generation and utilization in a two-phase flow membraneless microfluidic electrolyzer-fuel cell tandem operation for micropower application

Author

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  • Samir De, Biswajit
  • Cunningham, Joshua
  • Khare, Neeraj
  • Luo, Jing-Li
  • Elias, Anastasia
  • Basu, Suddhasatwa

Abstract

Advances in device miniaturization, ranging from sensors to transmitters, are driving the need for micro-scaled personalized on-demand power sources. Herein, the tandem operation of a membraneless, two-phase flow microfluidic electrolysis cell and fuel cell (µEC-µFC) is demonstrated, which is a step towards developing an independent micropower source. This device consists of a membraneless double Y-shaped microchannel that encompasses microelectrodes for the microfluidic electrolysis cell (µEC) and microfluidic fuel cell (µFC). A voltage applied to the µEC induces two-phase flow in the µEC-µFC, resulting in the evolution of H2 and O2 gases that are transported to the µFC by convection, and consumed to generate power. The catholyte-anolyte interface of the µEC-µFC behaves as a virtual membrane. The gas product mixing and crossover are averted by controlling the flow rate of electrolyte. Dimensionless numbers are used to characterize the flow in the microchannel. Tandem performance evaluation of µEC-µFC operation in acidic and alkaline electrolytes based on the flow rate (1.4 – 1.6 mL min−1) and µEC operating voltages (2.3 – 2.5 V) is done by polarization and power density curves. The µEC-µFC exhibited 4 h of stable tandem operation. The µEC exhibits 99.98% energy conversion efficiency, with the µFC attaining up to 50% fuel utilization in tandem mode.

Suggested Citation

  • Samir De, Biswajit & Cunningham, Joshua & Khare, Neeraj & Luo, Jing-Li & Elias, Anastasia & Basu, Suddhasatwa, 2022. "Hydrogen generation and utilization in a two-phase flow membraneless microfluidic electrolyzer-fuel cell tandem operation for micropower application," Applied Energy, Elsevier, vol. 305(C).
    • Handle: RePEc:eee:appene:v:305:y:2022:i:c:s0306261921012551
    DOI: 10.1016/j.apenergy.2021.117945
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    References listed on IDEAS

    as
    1. Chen, Binbin & Leung, Dennis Y.C. & Xuan, Jin & Wang, Huizhi, 2017. "A mixed-pH dual-electrolyte microfluidic aluminum–air cell with high performance," Applied Energy, Elsevier, vol. 185(P2), pages 1303-1308.
    2. Ismail, M.S. & Hughes, K.J. & Ingham, D.B. & Ma, L. & Pourkashanian, M., 2012. "Effects of anisotropic permeability and electrical conductivity of gas diffusion layers on the performance of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 95(C), pages 50-63.
    3. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    4. Lu, Xu & Wang, Yifei & Leung, Dennis Y.C. & Xuan, Jin & Wang, Huizhi, 2018. "A counter-flow-based dual-electrolyte protocol for multiple electrochemical applications," Applied Energy, Elsevier, vol. 217(C), pages 241-248.
    5. Fu, Ya-Lu & Zhang, Biao & Zhu, Xun & Ye, Ding-Ding & Sui, Pang-Chieh & Djilali, Ned, 2020. "Pore-scale modeling of oxygen transport in the catalyst layer of air-breathing cathode in membraneless microfluidic fuel cells," Applied Energy, Elsevier, vol. 277(C).
    6. Wang, Yifei & Leung, Dennis Y.C., 2016. "A circular stacking strategy for microfluidic fuel cells with volatile methanol fuel," Applied Energy, Elsevier, vol. 184(C), pages 659-669.
    7. Xuan, Jin & Leung, D.Y.C. & Wang, Huizhi & Leung, Michael K.H. & Wang, Bin & Ni, Meng, 2013. "Air-breathing membraneless laminar flow-based fuel cells: Do they breathe enough oxygen?," Applied Energy, Elsevier, vol. 104(C), pages 400-407.
    8. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
    9. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
    10. Cho, Junhyun & Park, Jaeman & Oh, Hwanyeong & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2013. "Analysis of the transient response and durability characteristics of a proton exchange membrane fuel cell with different micro-porous layer penetration thicknesses," Applied Energy, Elsevier, vol. 111(C), pages 300-309.
    11. Wang, Yifei & Leung, Dennis Y.C. & Xuan, Jin & Wang, Huizhi, 2015. "A vapor feed methanol microfluidic fuel cell with high fuel and energy efficiency," Applied Energy, Elsevier, vol. 147(C), pages 456-465.
    12. Park, Jaeman & Oh, Hwanyeong & Lee, Yoo Il & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2016. "Effect of the pore size variation in the substrate of the gas diffusion layer on water management and fuel cell performance," Applied Energy, Elsevier, vol. 171(C), pages 200-212.
    13. Xuan, Jin & Leung, Michael K.H. & Leung, Dennis Y.C. & Wang, Huizhi, 2012. "Laminar flow-based fuel cell working under critical conditions: The effect of parasitic current," Applied Energy, Elsevier, vol. 90(1), pages 87-93.
    14. Kwok, Y.H. & Wang, Y.F. & Tsang, Alpha C.H. & Leung, Dennis Y.C., 2018. "Graphene-carbon nanotube composite aerogel with Ru@Pt nanoparticle as a porous electrode for direct methanol microfluidic fuel cell," Applied Energy, Elsevier, vol. 217(C), pages 258-265.
    15. Chino, Isabel & Vega, Lorenzo & Keramati, Abtin & Hendrix, Kimberly & Haan, John L., 2020. "A direct liquid fuel cell powered by 1,3- or 1,2-propanediol," Applied Energy, Elsevier, vol. 262(C).
    16. Xu, Hong & Zhang, Hao & Wang, Huizhi & Leung, Dennis Y.C. & Zhang, Li & Cao, Jun & Jiao, Kui & Xuan, Jin, 2015. "Counter-flow formic acid microfluidic fuel cell with high fuel utilization exceeding 90%," Applied Energy, Elsevier, vol. 160(C), pages 930-936.
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    Cited by:

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    2. Li, Li & Wang, Hongkang & Bei, Shaoyi & Li, Yuanjiang & Sun, Yanyun & Zheng, Keqing & Xu, Qiang, 2023. "Unsymmetrical design and operation in counter-flow microfluidic fuel cell: A prospective study," Energy, Elsevier, vol. 262(PB).
    3. Ouyang, Tiancheng & Lu, Jie & Hu, Xiaoyi & Liu, Wenjun & Chen, Jingxian, 2022. "Multi-dimensional performance analysis and efficiency evaluation of paper-based microfluidic fuel cell," Renewable Energy, Elsevier, vol. 187(C), pages 94-108.

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