IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v127y2018icp883-895.html
   My bibliography  Save this article

Poly (vinyl alcohol) and poly (benzimidazole) blend membranes for high performance alkaline direct ethanol fuel cells

Author

Listed:
  • Herranz, D.
  • Escudero-Cid, R.
  • Montiel, M.
  • Palacio, C.
  • Fatás, E.
  • Ocón, P.

Abstract

A series of poly(vinyl alcohol)-blend-poly(benzimidazole) (PVA:PBI) membranes are synthesized with different ratios of PVA and PBI (2:1, 4:1, 6:1 and 8:1) using the casting method. These materials are doped in KOH 6 M solution in order to study their suitability for fuel cell applications. The Infra-red (IR) and Raman spectra confirm the successful doping of the membranes and the dimensional changes due to water and KOH uptakes during the doping are similar to other PBI-based membranes. XPS measurements are performed to evaluate the characteristics of these materials after the doping process. The thermal stability of the membranes is excellent in the range of desired temperatures (below 100 °C) and the conductivity values found are between 10−2 and 10−1 S cm−1. These results are optimal to consider these membranes as candidates for anion exchange membranes (AEMs) and they are tested in a single cell with ethanol as fuel. The PVA:PBI 4:1 membrane have the best behaviour in fuel cell, reaching a power density of 76 mW cm−2, approximately 50% better than the doped PBI in the same conditions. These important results can be considered highly promising for the future application of these membranes in alkaline polymer electrolyte membrane fuel cells (APEMFC).

Suggested Citation

  • Herranz, D. & Escudero-Cid, R. & Montiel, M. & Palacio, C. & Fatás, E. & Ocón, P., 2018. "Poly (vinyl alcohol) and poly (benzimidazole) blend membranes for high performance alkaline direct ethanol fuel cells," Renewable Energy, Elsevier, vol. 127(C), pages 883-895.
    • Handle: RePEc:eee:renene:v:127:y:2018:i:c:p:883-895
    DOI: 10.1016/j.renene.2018.05.020
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148118305391
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2018.05.020?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Benipal, Neeva & Qi, Ji & Gentile, Jacob C. & Li, Wenzhen, 2017. "Direct glycerol fuel cell with polytetrafluoroethylene (PTFE) thin film separator," Renewable Energy, Elsevier, vol. 105(C), pages 647-655.
    2. Deng, Hao & Wang, Dawei & Xie, Xu & Zhou, Yibo & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Modeling of hydrogen alkaline membrane fuel cell with interfacial effect and water management optimization," Renewable Energy, Elsevier, vol. 91(C), pages 166-177.
    3. Watt, G.D., 2014. "A new future for carbohydrate fuel cells," Renewable Energy, Elsevier, vol. 72(C), pages 99-104.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Altaf, Faizah & Batool, Rida & Gill, Rohama & Rehman, Zohaib Ur & Majeed, Hammad & Ahmad, Adnan & Shafiq, Muhammad & Dastan, Davoud & Abbas, Ghazanfar & Jacob, Karl, 2021. "Synthesis and electrochemical investigations of ABPBI grafted montmorillonite based polymer electrolyte membranes for PEMFC applications," Renewable Energy, Elsevier, vol. 164(C), pages 709-728.
    2. Ingabire, Providence Buregeya & Pan, Xueting & Haragirimana, Alphonse & Li, Na & Hu, Zhaoxia & Chen, Shouwen, 2020. "Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells," Renewable Energy, Elsevier, vol. 152(C), pages 590-600.
    3. Zhengping Zhou & Oksana Zholobko & Xiang-Fa Wu & Ted Aulich & Jivan Thakare & John Hurley, 2020. "Polybenzimidazole-Based Polymer Electrolyte Membranes for High-Temperature Fuel Cells: Current Status and Prospects," Energies, MDPI, vol. 14(1), pages 1-27, December.
    4. Coppola, R.E. & Herranz, D. & Escudero-Cid, R. & Ming, N. & D’Accorso, N.B. & Ocón, P. & Abuin, G.C., 2020. "Polybenzimidazole-crosslinked-poly(vinyl benzyl chloride) as anion exchange membrane for alkaline electrolyzers," Renewable Energy, Elsevier, vol. 157(C), pages 71-82.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ingabire, Providence Buregeya & Pan, Xueting & Haragirimana, Alphonse & Li, Na & Hu, Zhaoxia & Chen, Shouwen, 2020. "Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells," Renewable Energy, Elsevier, vol. 152(C), pages 590-600.
    2. Chino, Isabel & Hendrix, Kimberly & Keramati, Abtin & Muneeb, Omar & Haan, John L., 2019. "A split pH direct liquid fuel cell powered by propanol or glycerol," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    3. Cheng, Chaochao & Yang, Zirong & Liu, Zhi & Tongsh, Chasen & Zhang, Guobin & Xie, Biao & He, Shaoqing & Jiao, Kui, 2021. "Numerical investigation on the feasibility of metal foam as flow field in alkaline anion exchange membrane fuel cell," Applied Energy, Elsevier, vol. 302(C).
    4. Cardoso, João & Silva, Valter & Eusébio, Daniela & Brito, Paulo & Boloy, Ronney Mancebo & Tarelho, Luís & Silveira, José Luz, 2019. "Comparative 2D and 3D analysis on the hydrodynamics behaviour during biomass gasification in a pilot-scale fluidized bed reactor," Renewable Energy, Elsevier, vol. 131(C), pages 713-729.
    5. Wang, Bowen & Deng, Hao & Jiao, Kui, 2018. "Purge strategy optimization of proton exchange membrane fuel cell with anode recirculation," Applied Energy, Elsevier, vol. 225(C), pages 1-13.
    6. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
    7. Irfan, Muhammad & Liu, Xianhua & Li, Shengling & Khan, Izhar Ullah & Li, Yang & Wang, Jiao & Wang, Xin & Du, Xiwen & Wang, Guangyi & Zhang, Pingping, 2020. "High-performance glucose fuel cell with bimetallic Ni–Co composite anchored on reduced graphene oxide as anode catalyst," Renewable Energy, Elsevier, vol. 155(C), pages 1118-1126.
    8. Chino, Isabel & Vega, Lorenzo & Keramati, Abtin & Hendrix, Kimberly & Haan, John L., 2020. "A direct liquid fuel cell powered by 1,3- or 1,2-propanediol," Applied Energy, Elsevier, vol. 262(C).
    9. Bahari, Meisam & Malmberg, Michael A. & Brown, Daniel M. & Hadi Nazari, S. & Lewis, Randy S. & Watt, Gerald D. & Harb, John N., 2020. "Oxidation efficiency of glucose using viologen mediators for glucose fuel cell applications with non-precious anodes," Applied Energy, Elsevier, vol. 261(C).
    10. Deng, Hao & Wang, Dawei & Wang, Renfang & Xie, Xu & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Effect of electrode design and operating condition on performance of hydrogen alkaline membrane fuel cell," Applied Energy, Elsevier, vol. 183(C), pages 1272-1278.
    11. Do-Hyeong Kim & Moon-Sung Kang, 2020. "Pore-Filled Anion-Exchange Membranes with Double Cross-Linking Structure for Fuel Cells and Redox Flow Batteries," Energies, MDPI, vol. 13(18), pages 1-16, September.
    12. Yang, Chun & Cao, Wei-Qin & Ji, Xiao-Feng & Wang, Jian & Zhong, Tao-Lin & Wang, Yu & Zhang, Qing, 2020. "In situ fuel phosphorylation facilitates the complete oxidation of glycerol in direct biomass cells," Renewable Energy, Elsevier, vol. 146(C), pages 699-704.
    13. Osmieri, Luigi & Escudero-Cid, Ricardo & Monteverde Videla, Alessandro H.A. & Ocón, Pilar & Specchia, Stefania, 2018. "Application of a non-noble Fe-N-C catalyst for oxygen reduction reaction in an alkaline direct ethanol fuel cell," Renewable Energy, Elsevier, vol. 115(C), pages 226-237.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:127:y:2018:i:c:p:883-895. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.