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A new future for carbohydrate fuel cells

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  • Watt, G.D.

Abstract

The development of renewable energy sources to reduce our dependence on limiting fossil fuel reserves continues to be a critical research initiative. Utilizing the abundant high energy content of carbohydrates contained in biomass (cellulose and hemicellulose) must be considered to be an important contribution to our overall energy budget. Carbohydrate-derived furan-based liquid fuels and especially ethanol are becoming important added components forming gasoline blends to lower overall fossil fuel use. Alternate renewable energy processes that more efficiently use the carbohydrate energy content are desirable and would lower the overall carbohydrate input requirement for energy production. Recently, new catalysts have shown the feasibility of efficiently transporting the 24 electrons in glucose to fuel cell electrodes making possible the direct conversion of the stored energy in carbohydrates into electricity with the benign formation of carbonate and water as products. The conversion of glycerol, a byproduct of biodiesel production, into three-carbon carbohydrates provides another opportunity to produce electricity from an abundant carbohydrate source. New developments in catalyst systems promise to make carbohydrate fuel cells an important part of future energy strategies.

Suggested Citation

  • Watt, G.D., 2014. "A new future for carbohydrate fuel cells," Renewable Energy, Elsevier, vol. 72(C), pages 99-104.
  • Handle: RePEc:eee:renene:v:72:y:2014:i:c:p:99-104
    DOI: 10.1016/j.renene.2014.06.025
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    References listed on IDEAS

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    1. Watt, Gerald D., 2014. "Kinetic evaluation of the viologen-catalyzed carbohydrate oxidation reaction for fuel cell application," Renewable Energy, Elsevier, vol. 63(C), pages 370-375.
    2. Watt, Gerald D. & Hansen, Dane & Dodson, Daniel & Andrus, Merritt & Wheeler, Dean, 2011. "Electrical energy from carbohydrate oxidation during viologen-catalyzed O2-oxidation: Mechanistic insights," Renewable Energy, Elsevier, vol. 36(5), pages 1523-1528.
    3. Xuan, Jin & Leung, Michael K.H. & Leung, Dennis Y.C. & Ni, Meng, 2009. "A review of biomass-derived fuel processors for fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1301-1313, August.
    4. Yuriy Román-Leshkov & Christopher J. Barrett & Zhen Y. Liu & James A. Dumesic, 2007. "Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates," Nature, Nature, vol. 447(7147), pages 982-985, June.
    5. Janaun, Jidon & Ellis, Naoko, 2010. "Perspectives on biodiesel as a sustainable fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(4), pages 1312-1320, May.
    6. Read, Adam & Hansen, Dane & Aloi, Sekoti & Pitt, William G. & Wheeler, Dean R. & Watt, Gerald D., 2012. "Monoalkyl viologens are effective carbohydrate O2-oxidation catalysts for electrical energy generation by fuel cells," Renewable Energy, Elsevier, vol. 46(C), pages 218-223.
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    1. Yang, Chun & Cao, Wei-Qin & Ji, Xiao-Feng & Wang, Jian & Zhong, Tao-Lin & Wang, Yu & Zhang, Qing, 2020. "In situ fuel phosphorylation facilitates the complete oxidation of glycerol in direct biomass cells," Renewable Energy, Elsevier, vol. 146(C), pages 699-704.
    2. Bahari, Meisam & Malmberg, Michael A. & Brown, Daniel M. & Hadi Nazari, S. & Lewis, Randy S. & Watt, Gerald D. & Harb, John N., 2020. "Oxidation efficiency of glucose using viologen mediators for glucose fuel cell applications with non-precious anodes," Applied Energy, Elsevier, vol. 261(C).
    3. Irfan, Muhammad & Liu, Xianhua & Li, Shengling & Khan, Izhar Ullah & Li, Yang & Wang, Jiao & Wang, Xin & Du, Xiwen & Wang, Guangyi & Zhang, Pingping, 2020. "High-performance glucose fuel cell with bimetallic Ni–Co composite anchored on reduced graphene oxide as anode catalyst," Renewable Energy, Elsevier, vol. 155(C), pages 1118-1126.
    4. Cardoso, João & Silva, Valter & Eusébio, Daniela & Brito, Paulo & Boloy, Ronney Mancebo & Tarelho, Luís & Silveira, José Luz, 2019. "Comparative 2D and 3D analysis on the hydrodynamics behaviour during biomass gasification in a pilot-scale fluidized bed reactor," Renewable Energy, Elsevier, vol. 131(C), pages 713-729.
    5. Herranz, D. & Escudero-Cid, R. & Montiel, M. & Palacio, C. & Fatás, E. & Ocón, P., 2018. "Poly (vinyl alcohol) and poly (benzimidazole) blend membranes for high performance alkaline direct ethanol fuel cells," Renewable Energy, Elsevier, vol. 127(C), pages 883-895.

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