IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v63y2014icp370-375.html
   My bibliography  Save this article

Kinetic evaluation of the viologen-catalyzed carbohydrate oxidation reaction for fuel cell application

Author

Listed:
  • Watt, Gerald D.

Abstract

The use of abundant carbohydrates as resources for the production of electrical energy is an important area of research and development. Until recently only limited success has been reported in developing efficient catalysts for use in carbohydrate fuel cells. Viologens are active catalysts in transferring the abundant, low-potential (∼1.0 V) electrons stored in carbohydrates (24 electrons/glucose) to O2 or fuel cell electrodes in alkaline solution. To maximize electrical production from an alkaline carbohydrate fuel cell, it is essential to understand the variables determining the rate of electron transfer from the carbohydrate fuel to the viologen catalysts and then to the current collecting electrodes. Electron transfer from viologens to electrodes is a rapid process, so here we report a kinetic investigation evaluating the kinetics of oxidation of various carbohydrates with viologens under a variety of conditions, including viologen type. At a fixed temperature and pH, a first order reaction in both viologen and carbohydrate was observed. In general, carbohydrates with fewer than 5 carbon atoms react rapidly at room temperature and below but those with 5 carbons or more react more slowly and require temperatures of 40–55 °C. The results demonstrate that viologen oxidation of carbohydrates is sufficiently rapid that viable electrical power can be derived from alkaline carbohydrate fuel cells.

Suggested Citation

  • Watt, Gerald D., 2014. "Kinetic evaluation of the viologen-catalyzed carbohydrate oxidation reaction for fuel cell application," Renewable Energy, Elsevier, vol. 63(C), pages 370-375.
    • Handle: RePEc:eee:renene:v:63:y:2014:i:c:p:370-375
    DOI: 10.1016/j.renene.2013.09.025
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148113004928
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2013.09.025?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Read, Adam & Hansen, Dane & Aloi, Sekoti & Pitt, William G. & Wheeler, Dean R. & Watt, Gerald D., 2012. "Monoalkyl viologens are effective carbohydrate O2-oxidation catalysts for electrical energy generation by fuel cells," Renewable Energy, Elsevier, vol. 46(C), pages 218-223.
    2. Xuan, Jin & Leung, Michael K.H. & Leung, Dennis Y.C. & Ni, Meng, 2009. "A review of biomass-derived fuel processors for fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1301-1313, August.
    3. M. S. Dresselhaus & I. L. Thomas, 2001. "Alternative energy technologies," Nature, Nature, vol. 414(6861), pages 332-337, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Watt, G.D., 2014. "A new future for carbohydrate fuel cells," Renewable Energy, Elsevier, vol. 72(C), pages 99-104.
    2. Bahari, Meisam & Malmberg, Michael A. & Brown, Daniel M. & Hadi Nazari, S. & Lewis, Randy S. & Watt, Gerald D. & Harb, John N., 2020. "Oxidation efficiency of glucose using viologen mediators for glucose fuel cell applications with non-precious anodes," Applied Energy, Elsevier, vol. 261(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Watt, G.D., 2014. "A new future for carbohydrate fuel cells," Renewable Energy, Elsevier, vol. 72(C), pages 99-104.
    2. Xiaoqin Si & Rui Lu & Zhitong Zhao & Xiaofeng Yang & Feng Wang & Huifang Jiang & Xiaolin Luo & Aiqin Wang & Zhaochi Feng & Jie Xu & Fang Lu, 2022. "Catalytic production of low-carbon footprint sustainable natural gas," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Sung-Fu Hung & Aoni Xu & Xue Wang & Fengwang Li & Shao-Hui Hsu & Yuhang Li & Joshua Wicks & Eduardo González Cervantes & Armin Sedighian Rasouli & Yuguang C. Li & Mingchuan Luo & Dae-Hyun Nam & Ning W, 2022. "A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Cala, Anggie & Maturana-Córdoba, Aymer & Soto-Verjel, Joseph, 2023. "Exploring the pretreatments' influence on pressure reverse osmosis: PRISMA review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    5. Keramiotis, Ch. & Vourliotakis, G. & Skevis, G. & Founti, M.A. & Esarte, C. & Sánchez, N.E. & Millera, A. & Bilbao, R. & Alzueta, M.U., 2012. "Experimental and computational study of methane mixtures pyrolysis in a flow reactor under atmospheric pressure," Energy, Elsevier, vol. 43(1), pages 103-110.
    6. Ahmadi, Pouria & Dincer, Ibrahim & Rosen, Marc A., 2014. "Thermoeconomic multi-objective optimization of a novel biomass-based integrated energy system," Energy, Elsevier, vol. 68(C), pages 958-970.
    7. Ansis Mezulis & Christiaan Richter & Peteris Lesnicenoks & Ainars Knoks & Sarunas Varnagiris & Marius Urbonavicius & Darius Milcius & Janis Kleperis, 2023. "Studies on Water–Aluminum Scrap Reaction Kinetics in Two Steps and the Efficiency of Green Hydrogen Production," Energies, MDPI, vol. 16(14), pages 1-17, July.
    8. Woong Hee Lee & Young-Jin Ko & Jung Hwan Kim & Chang Hyuck Choi & Keun Hwa Chae & Hansung Kim & Yun Jeong Hwang & Byoung Koun Min & Peter Strasser & Hyung-Suk Oh, 2021. "High crystallinity design of Ir-based catalysts drives catalytic reversibility for water electrolysis and fuel cells," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    9. Jacqueline Noga & Gregor Wolbring, 2014. "The Oil and Gas Discourse from the Perspective of the Canadian and Albertan Governments, Non-Governmental Organizations and the Oil and Gas Industry," Energies, MDPI, vol. 7(1), pages 1-20, January.
    10. Kudzai Mugadza & Annegret Stark & Patrick G. Ndungu & Vincent O. Nyamori, 2021. "Effects of Ionic Liquid and Biomass Sources on Carbon Nanotube Physical and Electrochemical Properties," Sustainability, MDPI, vol. 13(5), pages 1-12, March.
    11. Roy, Debmalya & Shastri, Babita & Imamuddin, Md. & Mukhopadhyay, K. & Rao, K.U. Bhasker, 2011. "Nanostructured carbon and polymer materials – Synthesis and their application in energy conversion devices," Renewable Energy, Elsevier, vol. 36(3), pages 1014-1018.
    12. Tang, Jia & Yang, Mu & Yu, Fang & Chen, Xingyu & Tan, Li & Wang, Ge, 2017. "1-Octadecanol@hierarchical porous polymer composite as a novel shape-stability phase change material for latent heat thermal energy storage," Applied Energy, Elsevier, vol. 187(C), pages 514-522.
    13. Wang, Chaoqi & Lü, Zhe & Li, Jingwei & Cao, Zhiqun & Wei, Bo & Li, Huan & Shang, Minghao & Su, Chaoxiang, 2020. "Efficient use of waste carton for power generation, tar and fertilizer through direct carbon solid oxide fuel cell," Renewable Energy, Elsevier, vol. 158(C), pages 410-420.
    14. Jiaxi Zhang & Longhai Zhang & Jiamin Liu & Chengzhi Zhong & Yuanhua Tu & Peng Li & Li Du & Shengli Chen & Zhiming Cui, 2022. "OH spectator at IrMo intermetallic narrowing activity gap between alkaline and acidic hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    15. Sun, Li & Li, Guanru & You, Fengqi, 2020. "Combined internal resistance and state-of-charge estimation of lithium-ion battery based on extended state observer," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    16. Moharana, Manoj Kumar & Peela, Nageswara Rao & Khandekar, Sameer & Kunzru, Deepak, 2011. "Distributed hydrogen production from ethanol in a microfuel processor: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 524-533, January.
    17. Valero-Pedraza, María José & Martín-Cortés, Alexandra & Navarrete, Alexander & Bermejo, María Dolores & Martín, Ángel, 2015. "Kinetics of hydrogen release from dissolutions of ammonia borane in different ionic liquids," Energy, Elsevier, vol. 91(C), pages 742-750.
    18. Chen, Guanyi & Wenga, Terrence & Ma, Wenchao & Lin, Fawei, 2019. "Theoretical and experimental study of gas-phase corrosion attack of Fe under simulated municipal solid waste combustion: Influence of KCl, SO2, HCl, and H2O vapour," Applied Energy, Elsevier, vol. 247(C), pages 630-642.
    19. Paweł P. Włodarczyk & Barbara Włodarczyk, 2024. "Study of the Use of Gas Diffusion Anode with Various Cathodes (Cu-Ag, Ni-Co, and Cu-B Alloys) in a Microbial Fuel Cell," Energies, MDPI, vol. 17(7), pages 1-12, March.
    20. Kirankumar Kuruvinashetti & Shanmuga Sundaram Pakkiriswami & Dhilippan M. Panneerselvam & Muthukumaran Packirisamy, 2024. "Micro Photosynthetic Power Cell Array for Energy Harvesting: Bio-Inspired Modeling, Testing and Verification," Energies, MDPI, vol. 17(7), pages 1-18, April.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:63:y:2014:i:c:p:370-375. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.