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A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer

Author

Listed:
  • Xin Kang

    (Tsinghua University)

  • Fengning Yang

    (Tsinghua University
    University of Oxford, Clarendon Laboratory)

  • Zhiyuan Zhang

    (Tsinghua University)

  • Heming Liu

    (Tsinghua University)

  • Shiyu Ge

    (Tsinghua University)

  • Shuqi Hu

    (Tsinghua University)

  • Shaohai Li

    (Tsinghua University)

  • Yuting Luo

    (Tsinghua University
    University of Toronto)

  • Qiangmin Yu

    (Tsinghua University)

  • Zhibo Liu

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences)

  • Qiang Wang

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences)

  • Wencai Ren

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences)

  • Chenghua Sun

    (Swinburne University of Technology, Hawthorn)

  • Hui-Ming Cheng

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
    Chinese Academy of Sciences
    Advanced Technology Institute, University of Surrey)

  • Bilu Liu

    (Tsinghua University)

Abstract

Direct seawater electrolysis is promising for sustainable hydrogen gas (H2) production. However, the chloride ions in seawater lead to side reactions and corrosion, which result in a low efficiency and poor stability of the electrocatalyst and hinder the use of seawater electrolysis technology. Here we report a corrosion-resistant RuMoNi electrocatalyst, in which the in situ-formed molybdate ions on its surface repel chloride ions. The electrocatalyst works stably for over 3000 h at a high current density of 500 mA cm−2 in alkaline seawater electrolytes. Using the RuMoNi catalyst in an anion exchange membrane electrolyzer, we report an energy conversion efficiency of 77.9% and a current density of 1000 mA cm−2 at 1.72 V. The calculated price per gallon of gasoline equivalent (GGE) of the H2 produced is $ 0.85, which is lower than the 2026 technical target of $ 2.0/GGE set by the United Stated Department of Energy, thus, suggesting practicability of the technology.

Suggested Citation

  • Xin Kang & Fengning Yang & Zhiyuan Zhang & Heming Liu & Shiyu Ge & Shuqi Hu & Shaohai Li & Yuting Luo & Qiangmin Yu & Zhibo Liu & Qiang Wang & Wencai Ren & Chenghua Sun & Hui-Ming Cheng & Bilu Liu, 2023. "A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39386-5
    DOI: 10.1038/s41467-023-39386-5
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    as
    1. Jiaxin Guo & Yao Zheng & Zhenpeng Hu & Caiyan Zheng & Jing Mao & Kun Du & Mietek Jaroniec & Shi-Zhang Qiao & Tao Ling, 2023. "Direct seawater electrolysis by adjusting the local reaction environment of a catalyst," Nature Energy, Nature, vol. 8(3), pages 264-272, March.
    2. Hang T. Dinh & Jan Kuever & Marc Mußmann & Achim W. Hassel & Martin Stratmann & Friedrich Widdel, 2004. "Iron corrosion by novel anaerobic microorganisms," Nature, Nature, vol. 427(6977), pages 829-832, February.
    3. Hen Dotan & Avigail Landman & Stafford W. Sheehan & Kirtiman Deo Malviya & Gennady E. Shter & Daniel A. Grave & Ziv Arzi & Nachshon Yehudai & Manar Halabi & Netta Gal & Noam Hadari & Coral Cohen & Avn, 2019. "Decoupled hydrogen and oxygen evolution by a two-step electrochemical–chemical cycle for efficient overall water splitting," Nature Energy, Nature, vol. 4(9), pages 786-795, September.
    4. Heping Xie & Zhiyu Zhao & Tao Liu & Yifan Wu & Cheng Lan & Wenchuan Jiang & Liangyu Zhu & Yunpeng Wang & Dongsheng Yang & Zongping Shao, 2022. "A membrane-based seawater electrolyser for hydrogen generation," Nature, Nature, vol. 612(7941), pages 673-678, December.
    5. B. Zhang & J. Wang & B. Wu & X. W. Guo & Y. J. Wang & D. Chen & Y. C. Zhang & K. Du & E. E. Oguzie & X. L. Ma, 2018. "Unmasking chloride attack on the passive film of metals," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    6. Yuting Luo & Lei Tang & Usman Khan & Qiangmin Yu & Hui-Ming Cheng & Xiaolong Zou & Bilu Liu, 2019. "Morphology and surface chemistry engineering toward pH-universal catalysts for hydrogen evolution at high current density," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    7. Wenming Tong & Mark Forster & Fabio Dionigi & Sören Dresp & Roghayeh Sadeghi Erami & Peter Strasser & Alexander J. Cowan & Pau Farràs, 2020. "Electrolysis of low-grade and saline surface water," Nature Energy, Nature, vol. 5(5), pages 367-377, May.
    8. M. S. Dresselhaus & I. L. Thomas, 2001. "Alternative energy technologies," Nature, Nature, vol. 414(6861), pages 332-337, November.
    9. Qiangmin Yu & Zhiyuan Zhang & Siyao Qiu & Yuting Luo & Zhibo Liu & Fengning Yang & Heming Liu & Shiyu Ge & Xiaolong Zou & Baofu Ding & Wencai Ren & Hui-Ming Cheng & Chenghua Sun & Bilu Liu, 2021. "A Ta-TaS2 monolith catalyst with robust and metallic interface for superior hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    10. Haoyi Li & Shuangming Chen & Ying Zhang & Qinghua Zhang & Xiaofan Jia & Qi Zhang & Lin Gu & Xiaoming Sun & Li Song & Xun Wang, 2018. "Systematic design of superaerophobic nanotube-array electrode comprised of transition-metal sulfides for overall water splitting," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
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    2. Tao Liu & Zhiyu Zhao & Wenbin Tang & Yi Chen & Cheng Lan & Liangyu Zhu & Wenchuan Jiang & Yifan Wu & Yunpeng Wang & Zezhou Yang & Dongsheng Yang & Qijun Wang & Lunbo Luo & Taisheng Liu & Heping Xie, 2024. "In-situ direct seawater electrolysis using floating platform in ocean with uncontrollable wave motion," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Zhengwei Cai & Jie Liang & Zixiao Li & Tingyu Yan & Chaoxin Yang & Shengjun Sun & Meng Yue & Xuwei Liu & Ting Xie & Yan Wang & Tingshuai Li & Yongsong Luo & Dongdong Zheng & Qian Liu & Jingxiang Zhao , 2024. "Stabilizing NiFe sites by high-dispersity of nanosized and anionic Cr species toward durable seawater oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Wei Liu & Jiage Yu & Tianshui Li & Shihang Li & Boyu Ding & Xinlong Guo & Aiqing Cao & Qihao Sha & Daojin Zhou & Yun Kuang & Xiaoming Sun, 2024. "Self-protecting CoFeAl-layered double hydroxides enable stable and efficient brine oxidation at 2 A cm−2," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Yuzhen Chen & Qiuhong Li & Yuxing Lin & Jiao Liu & Jing Pan & Jingguo Hu & Xiaoyong Xu, 2024. "Boosting oxygen evolution reaction by FeNi hydroxide-organic framework electrocatalyst toward alkaline water electrolyzer," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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