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A Ta-TaS2 monolith catalyst with robust and metallic interface for superior hydrogen evolution

Author

Listed:
  • Qiangmin Yu

    (Tsinghua University)

  • Zhiyuan Zhang

    (Tsinghua University)

  • Siyao Qiu

    (Dongguan University of Technology)

  • Yuting Luo

    (Tsinghua University)

  • Zhibo Liu

    (Institute of Metal Research, Chinese Academy of Sciences)

  • Fengning Yang

    (Tsinghua University)

  • Heming Liu

    (Tsinghua University)

  • Shiyu Ge

    (Tsinghua University)

  • Xiaolong Zou

    (Tsinghua University)

  • Baofu Ding

    (Tsinghua University)

  • Wencai Ren

    (Institute of Metal Research, Chinese Academy of Sciences)

  • Hui-Ming Cheng

    (Tsinghua University
    Institute of Metal Research, Chinese Academy of Sciences
    University of Surrey, Guildford)

  • Chenghua Sun

    (Dongguan University of Technology
    Swinburne University of Technology)

  • Bilu Liu

    (Tsinghua University)

Abstract

The use of highly-active and robust catalysts is crucial for producing green hydrogen by water electrolysis as we strive to achieve global carbon neutrality. Noble metals like platinum are currently used catalysts in industry for the hydrogen evolution, but suffer from scarcity, high price and unsatisfied performance and stability at large current density, restrict their large-scale implementations. Here we report the synthesis of a type of monolith catalyst consisting of a metal disulfide (e.g., tantalum sulfides) vertically bonded to a conductive substrate of the same metal tantalum by strong covalent bonds. These features give the monolith catalyst a mechanically-robust and electrically near-zero-resistance interface, leading to an excellent hydrogen evolution performance including rapid charge transfer and excellent durability, together with a low overpotential of 398 mV to achieve a current density of 2,000 mA cm−2 as required by industry. The monolith catalyst has a negligible performance decay after 200 h operation at large current densities. In light of its robust and metallic interface and the various choices of metals giving the same structure, such monolith materials would have broad uses besides catalysis.

Suggested Citation

  • Qiangmin Yu & Zhiyuan Zhang & Siyao Qiu & Yuting Luo & Zhibo Liu & Fengning Yang & Heming Liu & Shiyu Ge & Xiaolong Zou & Baofu Ding & Wencai Ren & Hui-Ming Cheng & Chenghua Sun & Bilu Liu, 2021. "A Ta-TaS2 monolith catalyst with robust and metallic interface for superior hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26315-7
    DOI: 10.1038/s41467-021-26315-7
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    References listed on IDEAS

    as
    1. Smriti Mallapaty, 2020. "How China could be carbon neutral by mid-century," Nature, Nature, vol. 586(7830), pages 482-483, October.
    2. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    3. Yuting Luo & Lei Tang & Usman Khan & Qiangmin Yu & Hui-Ming Cheng & Xiaolong Zou & Bilu Liu, 2019. "Morphology and surface chemistry engineering toward pH-universal catalysts for hydrogen evolution at high current density," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Yuanyue Liu & Jingjie Wu & Ken P. Hackenberg & Jing Zhang & Y. Morris Wang & Yingchao Yang & Kunttal Keyshar & Jing Gu & Tadashi Ogitsu & Robert Vajtai & Jun Lou & Pulickel M. Ajayan & Brandon C. Wood, 2017. "Self-optimizing, highly surface-active layered metal dichalcogenide catalysts for hydrogen evolution," Nature Energy, Nature, vol. 2(9), pages 1-7, September.
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    Citations

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    Cited by:

    1. Heming Liu & Ruikuan Xie & Yuting Luo & Zhicheng Cui & Qiangmin Yu & Zhiqiang Gao & Zhiyuan Zhang & Fengning Yang & Xin Kang & Shiyu Ge & Shaohai Li & Xuefeng Gao & Guoliang Chai & Le Liu & Bilu Liu, 2022. "Dual interfacial engineering of a Chevrel phase electrode material for stable hydrogen evolution at 2500 mA cm−2," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Yudi Zhang & Kathryn E. Arpino & Qun Yang & Naoki Kikugawa & Dmitry A. Sokolov & Clifford W. Hicks & Jian Liu & Claudia Felser & Guowei Li, 2022. "Observation of a robust and active catalyst for hydrogen evolution under high current densities," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Gonglei Shao & Changfei Jing & Zhinan Ma & Yuanyuan Li & Weiqi Dang & Dong Guo & Manman Wu & Song Liu & Xu Zhang & Kun He & Yifei Yuan & Jun Luo & Sheng Dai & Jie Xu & Zhen Zhou, 2024. "Dynamic coordination engineering of 2D PhenPtCl2 nanosheets for superior hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Yang Gao & Yurui Xue & Lu Qi & Chengyu Xing & Xuchen Zheng & Feng He & Yuliang Li, 2022. "Rhodium nanocrystals on porous graphdiyne for electrocatalytic hydrogen evolution from saline water," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    5. Xin Kang & Fengning Yang & Zhiyuan Zhang & Heming Liu & Shiyu Ge & Shuqi Hu & Shaohai Li & Yuting Luo & Qiangmin Yu & Zhibo Liu & Qiang Wang & Wencai Ren & Chenghua Sun & Hui-Ming Cheng & Bilu Liu, 2023. "A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Chenyu Li & Zhijie Wang & Mingda Liu & Enze Wang & Bolun Wang & Longlong Xu & Kaili Jiang & Shoushan Fan & Yinghui Sun & Jia Li & Kai Liu, 2022. "Ultrafast self-heating synthesis of robust heterogeneous nanocarbides for high current density hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

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