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Numerical analysis of mass and heat transport in proton-conducting SOFCs with direct internal reforming

Author

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  • Menon, Vikram
  • Banerjee, Aayan
  • Dailly, Julian
  • Deutschmann, Olaf

Abstract

A computational model to investigate proton-conducting Solid-Oxide Fuel Cells (SOFCs) with direct internal reforming is developed. The numerical framework employs a 42-step elementary heterogeneous mechanism for Ni catalysts, using mean-field approximation. Mass transport through the porous media is described by the dusty gas model (DGM). Electrochemical parameters are deduced by reproducing two sets of experimental data, via the non-linear Butler–Volmer equation. A simple 1-D energy balance model is used to predict temperature profiles. The performance of the cell is analyzed by assuming the co-flow planar cell to be adiabatic. Simulations are carried out to understand the influence of various operating conditions on temperature distribution, species transport, and electrochemistry in the cell. The effect of dividing the anode into four zones, with different specific catalytic areas, on macroscopic performance parameters is investigated.

Suggested Citation

  • Menon, Vikram & Banerjee, Aayan & Dailly, Julian & Deutschmann, Olaf, 2015. "Numerical analysis of mass and heat transport in proton-conducting SOFCs with direct internal reforming," Applied Energy, Elsevier, vol. 149(C), pages 161-175.
    • Handle: RePEc:eee:appene:v:149:y:2015:i:c:p:161-175
    DOI: 10.1016/j.apenergy.2015.03.037
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    1. Hajimolana, S. Ahmad & Hussain, M. Azlan & Daud, W.M. Ashri Wan & Soroush, M. & Shamiri, A., 2011. "Mathematical modeling of solid oxide fuel cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(4), pages 1893-1917, May.
    2. Brian C. H. Steele, 1999. "Running on natural gas," Nature, Nature, vol. 400(6745), pages 619-621, August.
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    6. Emadi, Mohammad Ali & Chitgar, Nazanin & Oyewunmi, Oyeniyi A. & Markides, Christos N., 2020. "Working-fluid selection and thermoeconomic optimisation of a combined cycle cogeneration dual-loop organic Rankine cycle (ORC) system for solid oxide fuel cell (SOFC) waste-heat recovery," Applied Energy, Elsevier, vol. 261(C).
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    9. Lei, Libin & Keels, Jayson M. & Tao, Zetian & Zhang, Jihao & Chen, Fanglin, 2018. "Thermodynamic and experimental assessment of proton conducting solid oxide fuel cells with internal methane steam reforming," Applied Energy, Elsevier, vol. 224(C), pages 280-288.
    10. Putilov, L.P. & Demin, A.K. & Tsidilkovski, V.I. & Tsiakaras, P., 2019. "Theoretical modeling of the gas humidification effect on the characteristics of proton ceramic fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 1448-1459.
    11. Yang, Chao & Jing, Xiuhui & Miao, He & Wu, Yu & Shu, Chen & Wang, Jiatang & Zhang, Houcheng & Yu, Guojun & Yuan, Jinliang, 2020. "Analysis of effects of meso-scale reactions on multiphysics transport processes in rSOFC fueled with syngas," Energy, Elsevier, vol. 190(C).
    12. Kupecki, Jakub & Motylinski, Konrad & Milewski, Jaroslaw, 2018. "Dynamic analysis of direct internal reforming in a SOFC stack with electrolyte-supported cells using a quasi-1D model," Applied Energy, Elsevier, vol. 227(C), pages 198-205.
    13. Li, Ang & Song, Ce & Lin, Zijing, 2017. "A multiphysics fully coupled modeling tool for the design and operation analysis of planar solid oxide fuel cell stacks," Applied Energy, Elsevier, vol. 190(C), pages 1234-1244.
    14. Dai, Huidong & Besser, R.S., 2022. "Understanding hydrogen sulfide impact on a portable, commercial, propane-powered solid-oxide fuel cell," Applied Energy, Elsevier, vol. 307(C).
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