IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v227y2018icp198-205.html
   My bibliography  Save this article

Dynamic analysis of direct internal reforming in a SOFC stack with electrolyte-supported cells using a quasi-1D model

Author

Listed:
  • Kupecki, Jakub
  • Motylinski, Konrad
  • Milewski, Jaroslaw

Abstract

Solid oxide fuel cells (SOFC) offer several advantages that are accelerating the research and development of the technology. Recent advances include the improvement of materials and new fabrication techniques, as well as new designs, flow configurations, and applications. The large scale implementation of fuel cells, especially in distributed energy generation, is limited by several factors––one of which is their limited fuel flexibility. Changing fuel typically requires modifying the fuel processing unit to make it possible to effectively convert raw fuel into hydrogen-rich gas. One potential solution allows for the use of alternative fuels without the need for customization of the fuel processor. This solution requires the adaptation of the stack to operate with direct internal reforming (DIR) of the fuel on the surface of the anodes. The present study explores the potential to internally reform methane in the SOFC stack with electrolyte supported cells. The numerical model that was developed for the simulation of the 1300W stack was validated using experimental data obtained from partial internal reforming. Later, the model was applied to simulate the operation of the stack with complete internal reforming of methane. It was observed that the strong effects of internal reforming on the temperature in the outlets are visible when the current exceeds 22A. However, it was proven that the DIR-SOFC mode of operation is possible in the considered stack without exceeding the advised temperature limits in the core, and in the outlets of the anodic and cathodic compartments. The model was found to be accurate and the observed relative prediction error was in the range of 1.51–2.38%.

Suggested Citation

  • Kupecki, Jakub & Motylinski, Konrad & Milewski, Jaroslaw, 2018. "Dynamic analysis of direct internal reforming in a SOFC stack with electrolyte-supported cells using a quasi-1D model," Applied Energy, Elsevier, vol. 227(C), pages 198-205.
    • Handle: RePEc:eee:appene:v:227:y:2018:i:c:p:198-205
    DOI: 10.1016/j.apenergy.2017.07.122
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261917309960
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2017.07.122?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kang, Sanggyu & Ahn, Kook-Young, 2017. "Dynamic modeling of solid oxide fuel cell and engine hybrid system for distributed power generation," Applied Energy, Elsevier, vol. 195(C), pages 1086-1099.
    2. Eveloy, Valérie, 2012. "Numerical analysis of an internal methane reforming solid oxide fuel cell with fuel recycling," Applied Energy, Elsevier, vol. 93(C), pages 107-115.
    3. Menon, Vikram & Banerjee, Aayan & Dailly, Julian & Deutschmann, Olaf, 2015. "Numerical analysis of mass and heat transport in proton-conducting SOFCs with direct internal reforming," Applied Energy, Elsevier, vol. 149(C), pages 161-175.
    4. Wang, Baoxuan & Zhu, Jiang & Lin, Zijing, 2016. "A theoretical framework for multiphysics modeling of methane fueled solid oxide fuel cell and analysis of low steam methane reforming kinetics," Applied Energy, Elsevier, vol. 176(C), pages 1-11.
    5. Al-Masri, A. & Peksen, M. & Blum, L. & Stolten, D., 2014. "A 3D CFD model for predicting the temperature distribution in a full scale APU SOFC short stack under transient operating conditions," Applied Energy, Elsevier, vol. 135(C), pages 539-547.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Shi, Wangying & Zhu, Jianzhong & Han, Minfang & Sun, Zaihong & Guo, Yaming, 2019. "Operating limitation and degradation modeling of micro solid oxide fuel cell-combined heat and power system," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    2. Szczęśniak, Arkadiusz & Milewski, Jarosław & Szabłowski, Łukasz & Bujalski, Wojciech & Dybiński, Olaf, 2020. "Dynamic model of a molten carbonate fuel cell 1 kW stack," Energy, Elsevier, vol. 200(C).
    3. Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    4. Yongqing Wang & Xingchen Li & Zhenning Guo & Ke Wang & Yan Cao, 2021. "Effect of the Reactant Transportation on Performance of a Planar Solid Oxide Fuel Cell," Energies, MDPI, vol. 14(4), pages 1-14, February.
    5. Dai, Huidong & Besser, R.S., 2022. "Understanding hydrogen sulfide impact on a portable, commercial, propane-powered solid-oxide fuel cell," Applied Energy, Elsevier, vol. 307(C).
    6. Wu, Xiao-long & Xu, Yuan-Wu & Xue, Tao & Zhao, Dong-qi & Jiang, Jianhua & Deng, Zhonghua & Fu, Xiaowei & Li, Xi, 2019. "Health state prediction and analysis of SOFC system based on the data-driven entire stage experiment," Applied Energy, Elsevier, vol. 248(C), pages 126-140.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Ang & Song, Ce & Lin, Zijing, 2017. "A multiphysics fully coupled modeling tool for the design and operation analysis of planar solid oxide fuel cell stacks," Applied Energy, Elsevier, vol. 190(C), pages 1234-1244.
    2. Wang, Baoxuan & Zhu, Jiang & Lin, Zijing, 2016. "A theoretical framework for multiphysics modeling of methane fueled solid oxide fuel cell and analysis of low steam methane reforming kinetics," Applied Energy, Elsevier, vol. 176(C), pages 1-11.
    3. Zeng, Hongyu & Wang, Yuqing & Shi, Yixiang & Cai, Ningsheng & Yuan, Dazhong, 2018. "Highly thermal integrated heat pipe-solid oxide fuel cell," Applied Energy, Elsevier, vol. 216(C), pages 613-619.
    4. Recalde, Mayra & Woudstra, Theo & Aravind, P.V., 2018. "Renewed sanitation technology: A highly efficient faecal-sludge gasification–solid oxide fuel cell power plant," Applied Energy, Elsevier, vol. 222(C), pages 515-529.
    5. Zaccaria, V. & Tucker, D. & Traverso, A., 2017. "Operating strategies to minimize degradation in fuel cell gas turbine hybrids," Applied Energy, Elsevier, vol. 192(C), pages 437-445.
    6. Shao, Qian & Gao, Enlai & Mara, Thierry & Hu, Heng & Liu, Tong & Makradi, Ahmed, 2020. "Global sensitivity analysis of solid oxide fuel cells with Bayesian sparse polynomial chaos expansions," Applied Energy, Elsevier, vol. 260(C).
    7. Kishimoto, Masashi & Kishida, Shohei & Seo, Haewon & Iwai, Hiroshi & Yoshida, Hideo, 2021. "Prediction of electrochemical characteristics of practical-size solid oxide fuel cells based on database of unit cell performance," Applied Energy, Elsevier, vol. 283(C).
    8. Chen, Daifen & Zeng, Qice & Su, Shichuan & Bi, Wuxi & Ren, Zhiqiang, 2013. "Geometric optimization of a 10-cell modular planar solid oxide fuel cell stack manifold," Applied Energy, Elsevier, vol. 112(C), pages 1100-1107.
    9. Guk, Erdogan & Venkatesan, Vijay & Babar, Shumaila & Jackson, Lisa & Kim, Jung-Sik, 2019. "Parameters and their impacts on the temperature distribution and thermal gradient of solid oxide fuel cell," Applied Energy, Elsevier, vol. 241(C), pages 164-173.
    10. Kim, Taebeen & Kang, Sanggyu, 2023. "Numerical analysis of a highly efficient cascade solid oxide fuel cell system with a fuel regenerator," Applied Energy, Elsevier, vol. 341(C).
    11. Kim, Jaehyun & Kim, Yongtae & Choi, Wonjae & Ahn, Kook Young & Song, Han Ho, 2020. "Analysis on the operating performance of 5-kW class solid oxide fuel cell-internal combustion engine hybrid system using spark-assisted ignition," Applied Energy, Elsevier, vol. 260(C).
    12. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
    13. Xu, Haoran & Chen, Bin & Tan, Peng & Zhang, Houcheng & Yuan, Jinliang & Liu, Jiang & Ni, Meng, 2017. "Performance improvement of a direct carbon solid oxide fuel cell system by combining with a Stirling cycle," Energy, Elsevier, vol. 140(P1), pages 979-987.
    14. Komatsu, Y. & Brus, G. & Kimijima, S. & Szmyd, J.S., 2014. "The effect of overpotentials on the transient response of the 300W SOFC cell stack voltage," Applied Energy, Elsevier, vol. 115(C), pages 352-359.
    15. Silva-Mosqueda, Dulce María & Elizalde-Blancas, Francisco & Pumiglia, Davide & Santoni, Francesca & Boigues-Muñoz, Carlos & McPhail, Stephen J., 2019. "Intermediate temperature solid oxide fuel cell under internal reforming: Critical operating conditions, associated problems and their impact on the performance," Applied Energy, Elsevier, vol. 235(C), pages 625-640.
    16. Wang, Erlei & Xia, Jiangying & Li, Jia & Sun, Xianke & Li, Hao, 2022. "Parameters exploration of SOFC for dynamic simulation using adaptive chaotic grey wolf optimization algorithm," Energy, Elsevier, vol. 261(PA).
    17. Lei, Libin & Keels, Jayson M. & Tao, Zetian & Zhang, Jihao & Chen, Fanglin, 2018. "Thermodynamic and experimental assessment of proton conducting solid oxide fuel cells with internal methane steam reforming," Applied Energy, Elsevier, vol. 224(C), pages 280-288.
    18. Wang, Chaoyang & Chen, Ming & Liu, Ming & Yan, Junjie, 2020. "Dynamic modeling and parameter analysis study on reversible solid oxide cells during mode switching transient processes," Applied Energy, Elsevier, vol. 263(C).
    19. Shah, M.A.K. Yousaf & Lu, Yuzheng & Mushtaq, Naveed & Yousaf, Muhammad & Akbar, Nabeela & Xia, Chen & Yun, Sining & Zhu, Bin, 2023. "Semiconductor-membrane fuel cell (SMFC) for renewable energy technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).
    20. van Biert, L. & Godjevac, M. & Visser, K. & Aravind, P.V., 2019. "Dynamic modelling of a direct internal reforming solid oxide fuel cell stack based on single cell experiments," Applied Energy, Elsevier, vol. 250(C), pages 976-990.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:227:y:2018:i:c:p:198-205. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.