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The effect of overpotentials on the transient response of the 300W SOFC cell stack voltage

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  • Komatsu, Y.
  • Brus, G.
  • Kimijima, S.
  • Szmyd, J.S.

Abstract

This paper presents the results of an experimental investigation of transient characterizations of 300W planar type Solid Oxide Fuel Cell (SOFC) cell stack during load change. It indicates the transient characterization obtained during a ramped electric current with a Current-Based Fuel Control (CBFC) strategy. The fuel utilization factor is chosen for a reference of the CBFC strategy and is kept constant to the ramping electric current. The fuel utilization factor can be described as a ratio of consumed fuel (expressed as a function with an applied electric current) to supplied fuel. For the simplification of discussion, hydrogen was used as fuel by mixing it with nitrogen in order to satisfy the constant gas residential time in all cases and instances. The transient response of the cell voltage obtained under several thermal conditions was shown for discussion. The effect of overpotentials, associated with the cell’s operating temperature, on the transient response of the cell voltage is primarily discussed. The paper indicates that reducing the fuel flow rate, namely, setting a higher set-point for the fuel utilization factor, may decrease the OCV, increase concentration polarization and finally degrade cell performance. This paper also pointed out the importance of operating temperature management on both improving the steady-state cell performance and eliminating the negative effect of the overpotentials that appear on the transient response of the cell voltage.

Suggested Citation

  • Komatsu, Y. & Brus, G. & Kimijima, S. & Szmyd, J.S., 2014. "The effect of overpotentials on the transient response of the 300W SOFC cell stack voltage," Applied Energy, Elsevier, vol. 115(C), pages 352-359.
    • Handle: RePEc:eee:appene:v:115:y:2014:i:c:p:352-359
    DOI: 10.1016/j.apenergy.2013.11.017
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    2. Ferrari, Mario L., 2015. "Advanced control approach for hybrid systems based on solid oxide fuel cells," Applied Energy, Elsevier, vol. 145(C), pages 364-373.
    3. Li, Jiawen & Yu, Tao & Yang, Bo, 2021. "A data-driven output voltage control of solid oxide fuel cell using multi-agent deep reinforcement learning," Applied Energy, Elsevier, vol. 304(C).
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    6. Lee, Young Duk & Ahn, Kook Young & Morosuk, Tatiana & Tsatsaronis, George, 2018. "Exergetic and exergoeconomic evaluation of an SOFC-Engine hybrid power generation system," Energy, Elsevier, vol. 145(C), pages 810-822.
    7. Zhu, Pengfei & Wu, Zhen & Yang, Yuchen & Wang, Huan & Li, Ruiqing & Yang, Fusheng & Zhang, Zaoxiao, 2023. "The dynamic response of solid oxide fuel cell fueled by syngas during the operating condition variations," Applied Energy, Elsevier, vol. 349(C).
    8. Vinoth Kumar, R. & Khandale, A.P., 2022. "A review on recent progress and selection of cobalt-based cathode materials for low temperature-solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    9. Baudoin, Sylvain & Vechiu, Ionel & Camblong, Haritza & Vinassa, Jean-Michel & Barelli, Linda, 2016. "Sizing and control of a Solid Oxide Fuel Cell/Gas microTurbine hybrid power system using a unique inverter for rural microgrid integration," Applied Energy, Elsevier, vol. 176(C), pages 272-281.

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