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Analysis of effects of meso-scale reactions on multiphysics transport processes in rSOFC fueled with syngas

Author

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  • Yang, Chao
  • Jing, Xiuhui
  • Miao, He
  • Wu, Yu
  • Shu, Chen
  • Wang, Jiatang
  • Zhang, Houcheng
  • Yu, Guojun
  • Yuan, Jinliang

Abstract

A two-dimensional mathematical model is developed for a single-cell based on the planar configuration and validated by relevant experimental data, with an aim to describe the coupling phenomena of the multiphysics transport processes and the meso-scale elementary reactions. It is revealed that desorption and adsorption reactions in the electrode mostly take place near the electrolyte and the channel, respectively; the distribution of the surface species depends on the gas diffusion in the porous electrode affected by the thickness and microstructure of the electrode. The electrochemical reactions are centralized in about 100 μm thick electrode from the electrolyte. Nis and COs are the major surface species in both fuel cell (FC) and electrolysis cell (EC) modes. Os is higher in the FC mode, particularly near the electrolyte due to the desorption and charge transfer reactions; The microscopic structure properties, including average porosity, tortuosity and particle size, are also influential on the elementary reactions due to the gas diffusion through the tortuous pathways and the active sites on the catalyst surfaces. It is also found that the performance predicted in the global models is often overestimated, because the limitations of the local elementary reactions are not considered in the global model.

Suggested Citation

  • Yang, Chao & Jing, Xiuhui & Miao, He & Wu, Yu & Shu, Chen & Wang, Jiatang & Zhang, Houcheng & Yu, Guojun & Yuan, Jinliang, 2020. "Analysis of effects of meso-scale reactions on multiphysics transport processes in rSOFC fueled with syngas," Energy, Elsevier, vol. 190(C).
    • Handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219320742
    DOI: 10.1016/j.energy.2019.116379
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    as
    1. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    2. Santhanam, S. & Heddrich, M.P. & Riedel, M. & Friedrich, K.A., 2017. "Theoretical and experimental study of Reversible Solid Oxide Cell (r-SOC) systems for energy storage," Energy, Elsevier, vol. 141(C), pages 202-214.
    3. Er-rbib, Hanaâ & Bouallou, Chakib, 2014. "Modeling and simulation of CO methanation process for renewable electricity storage," Energy, Elsevier, vol. 75(C), pages 81-88.
    4. Mohammadi, Amin & Mehrpooya, Mehdi, 2018. "A comprehensive review on coupling different types of electrolyzer to renewable energy sources," Energy, Elsevier, vol. 158(C), pages 632-655.
    5. Menon, Vikram & Banerjee, Aayan & Dailly, Julian & Deutschmann, Olaf, 2015. "Numerical analysis of mass and heat transport in proton-conducting SOFCs with direct internal reforming," Applied Energy, Elsevier, vol. 149(C), pages 161-175.
    6. Zhang, Houcheng & Xu, Haoran & Chen, Bin & Dong, Feifei & Ni, Meng, 2017. "Two-stage thermoelectric generators for waste heat recovery from solid oxide fuel cells," Energy, Elsevier, vol. 132(C), pages 280-288.
    7. Barelli, L. & Bidini, G. & Ottaviano, A., 2016. "Solid oxide fuel cell modelling: Electrochemical performance and thermal management during load-following operation," Energy, Elsevier, vol. 115(P1), pages 107-119.
    8. Wang, Yifei & Leung, Dennis Y.C. & Xuan, Jin & Wang, Huizhi, 2017. "A review on unitized regenerative fuel cell technologies, part B: Unitized regenerative alkaline fuel cell, solid oxide fuel cell, and microfluidic fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 775-795.
    9. Becker, W.L. & Braun, R.J. & Penev, M. & Melaina, M., 2012. "Production of Fischer–Tropsch liquid fuels from high temperature solid oxide co-electrolysis units," Energy, Elsevier, vol. 47(1), pages 99-115.
    10. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2014. "Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide," Energy, Elsevier, vol. 70(C), pages 420-434.
    11. Khazaee, I. & Rava, A., 2017. "Numerical simulation of the performance of solid oxide fuel cell with different flow channel geometries," Energy, Elsevier, vol. 119(C), pages 235-244.
    12. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2015. "Dynamic electro-thermal modeling of co-electrolysis of steam and carbon dioxide in a tubular solid oxide electrolysis cell," Energy, Elsevier, vol. 89(C), pages 637-647.
    13. Hofmann, P. & Panopoulos, K.D. & Fryda, L.E. & Kakaras, E., 2009. "Comparison between two methane reforming models applied to a quasi-two-dimensional planar solid oxide fuel cell model," Energy, Elsevier, vol. 34(12), pages 2151-2157.
    14. Butera, Giacomo & Jensen, Søren Højgaard & Clausen, Lasse Røngaard, 2019. "A novel system for large-scale storage of electricity as synthetic natural gas using reversible pressurized solid oxide cells," Energy, Elsevier, vol. 166(C), pages 738-754.
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    1. Yang, Chao & Jing, Xiuhui & Miao, He & Xu, Jingxiang & Lin, Peijian & Li, Ping & Liang, Chaoyu & Wu, Yu & Yuan, Jinliang, 2021. "The physical properties and effects of sintering conditions on rSOFC fuel electrodes evaluated by molecular dynamics simulation," Energy, Elsevier, vol. 216(C).
    2. Zhu, Pengfei & Wu, Zhen & Yang, Yuchen & Wang, Huan & Li, Ruiqing & Yang, Fusheng & Zhang, Zaoxiao, 2023. "The dynamic response of solid oxide fuel cell fueled by syngas during the operating condition variations," Applied Energy, Elsevier, vol. 349(C).

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