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Hot air recirculation enlarges efficient operating window of reversible solid oxide cell systems: A thermodynamic study of energy storage using ammonia

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  • Amladi, Amogh
  • Venkataraman, Vikrant
  • Woudstra, Theo
  • Aravind, P.V.

Abstract

Energy storage is vital for the energy transition, enabling reliable power grids based on intermittent renewables. Reversible solid oxide cell (rSOC) technology is promising for seasonal energy storage. The novel finding from this work is that optimised air recirculation for rSOC in endothermic electrolyser mode leads to efficiency being nearly independent of current density. Thereby the operating region of highest efficiency is expanded from the thermoneutral point to the entire endothermic region, leading to highly efficient part-load operation. Air recirculation increases fuel cell mode efficiency too, particularly at higher loads. This widens the efficient operating window in both modes. These findings emerge from a thermodynamic study of an rSOC-based energy storage system with ammonia as fuel. A process design is developed and optimised for efficiency, supported with detailed exergy analysis. First, ammonia synthesis subsystem integrated with the rSOC system in electrolyser mode is optimised. Second, rSOC outlet air recirculation is optimised for high system efficiency. Finally, rSOC operating points are optimised for highest round-trip efficiency. We find the least exergy destruction for the ammonia synthesis subsystem at 170bar synthesis pressure and 30°C condensation temperature (without needing refrigeration). The overall system achieves round-trip efficiencies up to 60.3%.

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  • Amladi, Amogh & Venkataraman, Vikrant & Woudstra, Theo & Aravind, P.V., 2024. "Hot air recirculation enlarges efficient operating window of reversible solid oxide cell systems: A thermodynamic study of energy storage using ammonia," Applied Energy, Elsevier, vol. 355(C).
    • Handle: RePEc:eee:appene:v:355:y:2024:i:c:s0306261923016409
    DOI: 10.1016/j.apenergy.2023.122276
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    1. Hartmann, Niklas & Vöhringer, O. & Kruck, C. & Eltrop, L., 2012. "Simulation and analysis of different adiabatic Compressed Air Energy Storage plant configurations," Applied Energy, Elsevier, vol. 93(C), pages 541-548.
    2. Wang, Ligang & Zhang, Yumeng & Pérez-Fortes, Mar & Aubin, Philippe & Lin, Tzu-En & Yang, Yongping & Maréchal, François & Van herle, Jan, 2020. "Reversible solid-oxide cell stack based power-to-x-to-power systems: Comparison of thermodynamic performance," Applied Energy, Elsevier, vol. 275(C).
    3. Botta, G. & Mor, R. & Patel, H. & Aravind, P.V., 2018. "Thermodynamic evaluation of bi-directional solid oxide cell systems including year-round cumulative exergy analysis," Applied Energy, Elsevier, vol. 226(C), pages 1100-1118.
    4. Morris, David R. & Szargut, Jan, 1986. "Standard chemical exergy of some elements and compounds on the planet earth," Energy, Elsevier, vol. 11(8), pages 733-755.
    5. Kirova-Yordanova, Zornitza, 2004. "Exergy analysis of industrial ammonia synthesis," Energy, Elsevier, vol. 29(12), pages 2373-2384.
    6. Liso, Vincenzo & Olesen, Anders Christian & Nielsen, Mads Pagh & Kær, Søren Knudsen, 2011. "Performance comparison between partial oxidation and methane steam reforming processes for solid oxide fuel cell (SOFC) micro combined heat and power (CHP) system," Energy, Elsevier, vol. 36(7), pages 4216-4226.
    7. Paolo Di Giorgio & Umberto Desideri, 2016. "Potential of Reversible Solid Oxide Cells as Electricity Storage System," Energies, MDPI, vol. 9(8), pages 1-14, August.
    8. Butera, Giacomo & Jensen, Søren Højgaard & Clausen, Lasse Røngaard, 2019. "A novel system for large-scale storage of electricity as synthetic natural gas using reversible pressurized solid oxide cells," Energy, Elsevier, vol. 166(C), pages 738-754.
    9. Gandiglio, M. & Lanzini, A. & Leone, P. & Santarelli, M. & Borchiellini, R., 2013. "Thermoeconomic analysis of large solid oxide fuel cell plants: Atmospheric vs. pressurized performance," Energy, Elsevier, vol. 55(C), pages 142-155.
    10. Gunther Glenk & Stefan Reichelstein, 2022. "Reversible Power-to-Gas systems for energy conversion and storage," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
    12. Giannoulidis, Sotiris & Venkataraman, Vikrant & Woudstra, Theo & Aravind, P.V., 2020. "Methanol based Solid Oxide Reversible energy storage system – Does it make sense thermodynamically?," Applied Energy, Elsevier, vol. 278(C).
    13. Jeanmonod, Guillaume & Wang, Ligang & Diethelm, Stefan & Maréchal, François & Van herle, Jan, 2019. "Trade-off designs of power-to-methane systems via solid-oxide electrolyzer and the application to biogas upgrading," Applied Energy, Elsevier, vol. 247(C), pages 572-581.
    14. Santhanam, S. & Heddrich, M.P. & Riedel, M. & Friedrich, K.A., 2017. "Theoretical and experimental study of Reversible Solid Oxide Cell (r-SOC) systems for energy storage," Energy, Elsevier, vol. 141(C), pages 202-214.
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