IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v15y2023i3p2516-d1052238.html
   My bibliography  Save this article

Optimization of Paracetamol and Chloramphenicol Removal by Novel Activated Carbon Derived from Sawdust Using Response Surface Methodology

Author

Listed:
  • Mohamed Romdhani

    (Research Unit “Advanced Technologies for Environment and Smart Cities”, Faculty of Science of Sfax, University of Sfax, Sfax 3038, Tunisia
    LAGEP, UMR 5007, CNRS, Université Claude Bernard Lyon 1, 43 Boulevard du 11 Novembre 1918, F-69100 Villeurbanne, France)

  • Afef Attia

    (Research Unit “Advanced Technologies for Environment and Smart Cities”, Faculty of Science of Sfax, University of Sfax, Sfax 3038, Tunisia)

  • Catherine Charcosset

    (LAGEP, UMR 5007, CNRS, Université Claude Bernard Lyon 1, 43 Boulevard du 11 Novembre 1918, F-69100 Villeurbanne, France)

  • Samia Mahouche-Chergui

    (Institut de Chimie et des Matériaux Paris-Est (ICMPE), UMR 7182 CNRS, Université Paris-Est, 2 Rue Henri Dunant, F-94320 Thiais, France)

  • Ayten Ates

    (Department of Chemical Engineering, Engineering Faculty, Cumhuriyet University, 58140 Sivas, Türkiye)

  • Joelle Duplay

    (EOST-LHYGES, UMR 7517, CNRS, Université de Strasbourg, F-67084 Strasbourg, France)

  • Raja Ben Amar

    (Research Unit “Advanced Technologies for Environment and Smart Cities”, Faculty of Science of Sfax, University of Sfax, Sfax 3038, Tunisia)

Abstract

Paracetamol (PCT) and chloramphenicol (CPL) can have unfavorable impacts on human health, as well as on natural ecosystems. These substances contribute to the aquatic environment’s contamination and disturb the performance of municipal wastewater treatment systems, causing ecosystem disruption and microbial resistance. In this study, activated carbon produced from sawdust (ACs) was synthesized utilizing the chemical activation process for the removal of both PCT and CPL compounds from an aqueous solution. ACs has a primarily microporous structure with a significant specific surface area of 303–1298 m 2 /g, total pore volume of 0.462 cm 3 /g and bimodal distribution of pores of 0.73–1.7 nm. The removal efficiencies for PCT and CPL with the low-cost activated carbon, determined at the optimum dose (750 mg/L for PCT and 450 mg/L for CPL), were significantly high at 85% and 98%, respectively. The adsorption kinetics for both pharmaceuticals exhibited a quick initial decline. For PCT and CPL adsorption, the equilibrium was attained after just 20 and 90 min, respectively. The Langmuir isotherm model and the pseudo-second-order kinetics model offered the best fits for the adsorption of both compounds. Additionally, the central composite design (CCD) and Box–Behnken design (BBD) were used to optimize the experimental adsorption conditions using a response surface methodology (RSM). On the basis of the findings, it is evident that activated carbon made from sawdust may be used as a new, effective alternative adsorbent for removing PCT and CPL in aqueous environments.

Suggested Citation

  • Mohamed Romdhani & Afef Attia & Catherine Charcosset & Samia Mahouche-Chergui & Ayten Ates & Joelle Duplay & Raja Ben Amar, 2023. "Optimization of Paracetamol and Chloramphenicol Removal by Novel Activated Carbon Derived from Sawdust Using Response Surface Methodology," Sustainability, MDPI, vol. 15(3), pages 1-24, January.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:3:p:2516-:d:1052238
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/15/3/2516/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2071-1050/15/3/2516/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Xu, Feng & Yu, Jianming & Tesso, Tesfaye & Dowell, Floyd & Wang, Donghai, 2013. "Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: A mini-review," Applied Energy, Elsevier, vol. 104(C), pages 801-809.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Pitak, Lakkana & Sirisomboon, Panmanas & Saengprachatanarug, Khwantri & Wongpichet, Seree & Posom, Jetsada, 2021. "Rapid elemental composition measurement of commercial pellets using line-scan hyperspectral imaging analysis," Energy, Elsevier, vol. 220(C).
    2. Krishna, Bhavya B. & Biswas, Bijoy & Ohri, Priyanka & Kumar, Jitendra & Singh, Rawel & Bhaskar, Thallada, 2016. "Pyrolysis of Cedrus deodara saw mill shavings in hydrogen and nitrogen atmosphere for the production of bio-oil," Renewable Energy, Elsevier, vol. 98(C), pages 238-244.
    3. Kłosowski, Grzegorz & Mikulski, Dawid, 2023. "Changes in various lignocellulose biomasses structure after microwave-assisted hydrotropic pretreatment," Renewable Energy, Elsevier, vol. 219(P1).
    4. Fan, Yuyang & Tippayawong, Nakorn & Wei, Guoqiang & Huang, Zhen & Zhao, Kun & Jiang, Liqun & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2020. "Minimizing tar formation whilst enhancing syngas production by integrating biomass torrefaction pretreatment with chemical looping gasification," Applied Energy, Elsevier, vol. 260(C).
    5. Junying Chen & Lijun Wang & Bo Zhang & Rui Li & Abolghasem Shahbazi, 2018. "Hydrothermal Liquefaction Enhanced by Various Chemicals as a Means of Sustainable Dairy Manure Treatment," Sustainability, MDPI, vol. 10(1), pages 1-14, January.
    6. Song, Yintao & Chen, Zhuo & Li, Yanling & Sun, Tanglei & Huhetaoli, & Lei, Tingzhou & Liu, Peng, 2024. "Regulation of energy properties and thermal behavior of bio-coal from lignocellulosic biomass using torrefaction," Energy, Elsevier, vol. 289(C).
    7. Abdul Waheed & Salman Raza Naqvi & Imtiaz Ali, 2022. "Co-Torrefaction Progress of Biomass Residue/Waste Obtained for High-Value Bio-Solid Products," Energies, MDPI, vol. 15(21), pages 1-20, November.
    8. Tom Haeldermans & Jeamichel Puente Torres & Willem Vercruysse & Robert Carleer & Pieter Samyn & Dries Vandamme & Jan Yperman & Ann Cuypers & Kenny Vanreppelen & Sonja Schreurs, 2023. "An Experimentally Validated Selection Protocol for Biochar as a Sustainable Component in Green Roofs," Waste, MDPI, vol. 1(1), pages 1-19, January.
    9. John Steven Devia-Orjuela & Christian E Alvarez-Pugliese & Dayana Donneys-Victoria & Nilson Marriaga Cabrales & Luz Edith Barba Ho & Balazs Brém & Anca Sauciuc & Emese Gál & Douglas Espin & Martin Sch, 2019. "Evaluation of Press Mud, Vinasse Powder and Extraction Sludge with Ethanol in a Pyrolysis Process," Energies, MDPI, vol. 12(21), pages 1-21, October.
    10. Pizzi, A. & Toscano, G. & Foppa Pedretti, E. & Duca, D. & Rossini, G. & Mengarelli, C. & Ilari, A. & Renzi, A. & Mancini, M., 2018. "Energy characteristics assessment of olive pomace by means of FT-NIR spectroscopy," Energy, Elsevier, vol. 147(C), pages 51-58.
    11. Andrea Kruse & Thomas A. Zevaco, 2018. "Properties of Hydrochar as Function of Feedstock, Reaction Conditions and Post-Treatment," Energies, MDPI, vol. 11(3), pages 1-12, March.
    12. Chen, Dongyu & Gao, Dongxiao & Capareda, Sergio C. & E, Shuang & Jia, Fengrui & Wang, Ying, 2020. "Influences of hydrochloric acid washing on the thermal decomposition behavior and thermodynamic parameters of sweet sorghum stalk," Renewable Energy, Elsevier, vol. 148(C), pages 1244-1255.
    13. Zhang, Ke & Zhou, Ling & Brady, Michael & Xu, Feng & Yu, Jianming & Wang, Donghai, 2017. "Fast analysis of high heating value and elemental compositions of sorghum biomass using near-infrared spectroscopy," Energy, Elsevier, vol. 118(C), pages 1353-1360.
    14. Nanduri, Arvind & Kulkarni, Shreesh S. & Mills, Patrick L., 2021. "Experimental techniques to gain mechanistic insight into fast pyrolysis of lignocellulosic biomass: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    15. Gupta, Ankita & Mahajani, Sanjay, 2020. "Kinetic studies in pyrolysis of garden waste in the context of downdraft gasification: Experiments and modeling," Energy, Elsevier, vol. 208(C).
    16. Gillespie, Gary D. & Everard, Colm D. & McDonnell, Kevin P., 2015. "Prediction of biomass pellet quality indices using near infrared spectroscopy," Energy, Elsevier, vol. 80(C), pages 582-588.
    17. Long, Jinxing & Shu, Riyang & Yuan, Zhengqiu & Wang, Tiejun & Xu, Ying & Zhang, Xinghua & Zhang, Qi & Ma, Longlong, 2015. "Efficient valorization of lignin depolymerization products in the present of NixMg1−xO," Applied Energy, Elsevier, vol. 157(C), pages 540-545.
    18. Li, Haowei & Ma, Hongwei & Zhao, Weijie & Li, Xuehui & Long, Jinxing, 2019. "Upgrading lignin bio-oil for oxygen-containing fuel production using Ni/MgO: Effect of the catalyst calcination temperature," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    19. José Luis Fernández & Felicia Sáez & Eulogio Castro & Paloma Manzanares & Mercedes Ballesteros & María José Negro, 2019. "Determination of the Lignocellulosic Components of Olive Tree Pruning Biomass by Near Infrared Spectroscopy," Energies, MDPI, vol. 12(13), pages 1-10, June.
    20. Zhao, Weijie & Li, Yingwen & Song, Changhua & Liu, Sijie & Li, Xuehui & Long, Jinxing, 2017. "Intensified levulinic acid/ester production from cassava by one-pot cascade prehydrolysis and delignification," Applied Energy, Elsevier, vol. 204(C), pages 1094-1100.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:15:y:2023:i:3:p:2516-:d:1052238. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.