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Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process

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  • Granados, D.A.
  • Ruiz, R.A.
  • Vega, L.Y.
  • Chejne, F.

Abstract

A complete study of torrefaction process to sugarcane bagasse under different thermal conditions was developed. After torrefaction process, chars were burned in an oxidizing atmosphere and its reactivities were studied. The torrefied biomass was characterized through chemical and physical analysis such as proximate and elemental analyses, lignocellulosic composition, High Heating Value (HHV), Fourier Transform Infrared Spectroscopy (FTIR) and observations in Scanning Electron Microscopy (SEM). The torrefied biomass was also evaluated in oxidizing conditions in order to analyze the impact of torrefaction process over biomass combustion process. Remarkable changes of the main functional groups were observed as the severity of the torrefaction process increased. The main structural carbohydrates affected in the process were hemicellulose and cellulose, which break down largely as a result of decarboxylation reactions, and breakage of links with methyl and acetyl groups. This was evidenced qualitatively when the material was observed in SEM, an increase in the decomposition of the cell wall structures as the process temperature increased was noted. These changes in the material were also verified with FTIR tests, and lignified matrix with higher content of aromatic groups and greater thermal stability is yielded with temperature increases.

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  • Granados, D.A. & Ruiz, R.A. & Vega, L.Y. & Chejne, F., 2017. "Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process," Energy, Elsevier, vol. 139(C), pages 818-827.
    • Handle: RePEc:eee:energy:v:139:y:2017:i:c:p:818-827
    DOI: 10.1016/j.energy.2017.08.013
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    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Xu, Feng & Yu, Jianming & Tesso, Tesfaye & Dowell, Floyd & Wang, Donghai, 2013. "Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: A mini-review," Applied Energy, Elsevier, vol. 104(C), pages 801-809.
    3. Liu, Zhijia & Hu, Wanhe & Jiang, Zehui & Mi, Bingbing & Fei, Benhua, 2016. "Investigating combustion behaviors of bamboo, torrefied bamboo, coal and their respective blends by thermogravimetric analysis," Renewable Energy, Elsevier, vol. 87(P1), pages 346-352.
    4. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba, Izabela, 2015. "Characterisation of renewable fuels' torrefaction process with different instrumental techniques," Energy, Elsevier, vol. 87(C), pages 259-269.
    5. Antonio Bizzo, Waldir & Lenço, Paulo César & Carvalho, Danilo José & Veiga, João Paulo Soto, 2014. "The generation of residual biomass during the production of bio-ethanol from sugarcane, its characterization and its use in energy production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 589-603.
    6. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    7. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    8. Chew, J.J. & Doshi, V., 2011. "Recent advances in biomass pretreatment – Torrefaction fundamentals and technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4212-4222.
    9. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Isothermal torrefaction kinetics of hemicellulose, cellulose, lignin and xylan using thermogravimetric analysis," Energy, Elsevier, vol. 36(11), pages 6451-6460.
    10. Nocquet, Timothée & Dupont, Capucine & Commandre, Jean-Michel & Grateau, Maguelone & Thiery, Sébastien & Salvador, Sylvain, 2014. "Volatile species release during torrefaction of wood and its macromolecular constituents: Part 1 – Experimental study," Energy, Elsevier, vol. 72(C), pages 180-187.
    11. Nocquet, Timothée & Dupont, Capucine & Commandre, Jean-Michel & Grateau, Maguelone & Thiery, Sébastien & Salvador, Sylvain, 2014. "Volatile species release during torrefaction of biomass and its macromolecular constituents: Part 2 – Modeling study," Energy, Elsevier, vol. 72(C), pages 188-194.
    12. Pereira, Sandra C. & Maehara, Larissa & Machado, Cristina M.M. & Farinas, Cristiane S., 2016. "Physical–chemical–morphological characterization of the whole sugarcane lignocellulosic biomass used for 2G ethanol production by spectroscopy and microscopy techniques," Renewable Energy, Elsevier, vol. 87(P1), pages 607-617.
    13. Chen, Wei-Hsin & Kuo, Po-Chih, 2010. "A study on torrefaction of various biomass materials and its impact on lignocellulosic structure simulated by a thermogravimetry," Energy, Elsevier, vol. 35(6), pages 2580-2586.
    14. Chen, Wei-Hsin & Chen, Chih-Jung & Hung, Chen-I & Shen, Cheng-Hsien & Hsu, Heng-Wen, 2013. "A comparison of gasification phenomena among raw biomass, torrefied biomass and coal in an entrained-flow reactor," Applied Energy, Elsevier, vol. 112(C), pages 421-430.
    15. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    16. Granados, D.A. & Velásquez, H.I. & Chejne, F., 2014. "Energetic and exergetic evaluation of residual biomass in a torrefaction process," Energy, Elsevier, vol. 74(C), pages 181-189.
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    5. Huang, Shengxiong & Lei, Can & Qin, Jie & Yi, Cheng & Chen, Tao & Yao, Lingling & Li, Bo & Wen, Yujiao & Zhou, Zhi & Xia, Mao, 2022. "Properties, kinetics and pyrolysis products distribution of oxidative torrefied camellia shell in different oxygen concentration," Energy, Elsevier, vol. 251(C).
    6. Sun Yong Park & Kwang Cheol Oh & Seok Jun Kim & La Hoon Cho & Young Kwang Jeon & DaeHyun Kim, 2023. "Development of a Biomass Component Prediction Model Based on Elemental and Proximate Analyses," Energies, MDPI, vol. 16(14), pages 1-17, July.
    7. Lin, Yi-Li & Zheng, Nai-Yun & Lin, Ching-Shi, 2021. "Repurposing Washingtonia filifera petiole and Sterculia foetida follicle waste biomass for renewable energy through torrefaction," Energy, Elsevier, vol. 223(C).
    8. Ahmad, Razi & Mohd Ishak, Mohd Azlan & Kasim, Nur Nasulhah & Ismail, Khudzir, 2019. "Properties and thermal analysis of upgraded palm kernel shell and Mukah Balingian coal," Energy, Elsevier, vol. 167(C), pages 538-547.
    9. Sher, Farooq & Yaqoob, Aqsa & Saeed, Farrukh & Zhang, Shengfu & Jahan, Zaib & Klemeš, Jiří Jaromír, 2020. "Torrefied biomass fuels as a renewable alternative to coal in co-firing for power generation," Energy, Elsevier, vol. 209(C).
    10. Germán Álvarez-López & Alejandra María Múnera & Juan G. Villegas, 2023. "Multicriteria Decision-Making Tools for the Selection of Biomasses as Supplementary Cementitious Materials," Sustainability, MDPI, vol. 15(13), pages 1-17, June.
    11. Niu, Qi & Ronsse, Frederik & Qi, Zhiyong & Zhang, Dongdong, 2022. "Fast torrefaction of large biomass particles by superheated steam: Enhanced solid products for multipurpose production," Renewable Energy, Elsevier, vol. 185(C), pages 552-563.

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