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Volatile species release during torrefaction of biomass and its macromolecular constituents: Part 2 – Modeling study

Author

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  • Nocquet, Timothée
  • Dupont, Capucine
  • Commandre, Jean-Michel
  • Grateau, Maguelone
  • Thiery, Sébastien
  • Salvador, Sylvain

Abstract

Based on the torrefaction experiments carried out on beechwood and on its macromolecular constituents – cellulose, lignin and xylan – in part 1 of this paper, a simple torrefaction model was developed to predict both solid and the eight main volatile species yields versus temperature, residence time and biomass macromolecular composition. This model consisted in the superposition of kinetic “sub-models” describing the torrefaction of each constituent. The interactions observed in part 1 between constituents were then taken into account by means of an empirical factor related to cellulose decomposition rate. The model reproduced quite well the experiments and enabled to show the influence of each constituent on torrefaction yields.

Suggested Citation

  • Nocquet, Timothée & Dupont, Capucine & Commandre, Jean-Michel & Grateau, Maguelone & Thiery, Sébastien & Salvador, Sylvain, 2014. "Volatile species release during torrefaction of biomass and its macromolecular constituents: Part 2 – Modeling study," Energy, Elsevier, vol. 72(C), pages 188-194.
    • Handle: RePEc:eee:energy:v:72:y:2014:i:c:p:188-194
    DOI: 10.1016/j.energy.2014.05.023
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    1. Granados, D.A. & Ruiz, R.A. & Vega, L.Y. & Chejne, F., 2017. "Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process," Energy, Elsevier, vol. 139(C), pages 818-827.
    2. Guizani, Chamseddine & Haddad, Khouloud & Jeguirim, Mejdi & Colin, Baptiste & Limousy, Lionel, 2016. "Combustion characteristics and kinetics of torrefied olive pomace," Energy, Elsevier, vol. 107(C), pages 453-463.
    3. González Martínez, María & Dupont, Capucine & da Silva Perez, Denilson & Mortha, Gérard & Thiéry, Sébastien & Meyer, Xuân-mi & Gourdon, Christophe, 2020. "Understanding the torrefaction of woody and agricultural biomasses through their extracted macromolecular components. Part 1: Experimental thermogravimetric solid mass loss," Energy, Elsevier, vol. 205(C).
    4. Yang, Yantao & Qu, Xia & Huang, Guorun & Ren, Suxia & Dong, Lili & Sun, Tanglei & Liu, Peng & Li, Yanling & Lei, Tingzhou & Cai, Junmeng, 2023. "Insight into lignocellulosic biomass torrefaction kinetics with case study of pinewood sawdust torrefaction," Renewable Energy, Elsevier, vol. 215(C).
    5. Suchandra Hazra & Prithvi Morampudi & John C. Prindle & Dhan Lord B. Fortela & Rafael Hernandez & Mark E. Zappi & Prashanth Buchireddy, 2023. "Torrefaction of Pine Using a Pilot-Scale Rotary Reactor: Experimentation, Kinetics, and Process Simulation Using Aspen Plus™," Clean Technol., MDPI, vol. 5(2), pages 1-21, May.
    6. Peduzzi, Emanuela & Boissonnet, Guillaume & Haarlemmer, Geert & Dupont, Capucine & Maréchal, François, 2014. "Torrefaction modelling for lignocellulosic biomass conversion processes," Energy, Elsevier, vol. 70(C), pages 58-67.
    7. Bouraoui, Zeineb & Jeguirim, Mejdi & Guizani, Chamseddine & Limousy, Lionel & Dupont, Capucine & Gadiou, Roger, 2015. "Thermogravimetric study on the influence of structural, textural and chemical properties of biomass chars on CO2 gasification reactivity," Energy, Elsevier, vol. 88(C), pages 703-710.
    8. Chai, Meiyun & Xie, Li & Yu, Xi & Zhang, Xingguang & Yang, Yang & Rahman, Md. Maksudur & Blanco, Paula H. & Liu, Ronghou & Bridgwater, Anthony V. & Cai, Junmeng, 2021. "Poplar wood torrefaction: Kinetics, thermochemistry and implications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    9. González Martínez, María & Dupont, Capucine & Anca-Couce, Andrés & da Silva Perez, Denilson & Boissonnet, Guillaume & Thiéry, Sébastien & Meyer, Xuân-mi & Gourdon, Christophe, 2020. "Understanding the torrefaction of woody and agricultural biomasses through their extracted macromolecular components. Part 2: Torrefaction model," Energy, Elsevier, vol. 210(C).
    10. Doddapaneni, Tharaka Rama Krishna C. & Praveenkumar, Ramasamy & Tolvanen, Henrik & Rintala, Jukka & Konttinen, Jukka, 2018. "Techno-economic evaluation of integrating torrefaction with anaerobic digestion," Applied Energy, Elsevier, vol. 213(C), pages 272-284.
    11. Krochmalny, Krystian & Niedzwiecki, Lukasz & Pelińska-Olko, Ewa & Wnukowski, Mateusz & Czajka, Krzysztof & Tkaczuk-Serafin, Monika & Pawlak-Kruczek, Halina, 2020. "Determination of the marker for automation of torrefaction and slow pyrolysis processes – A case study of spherical wood particles," Renewable Energy, Elsevier, vol. 161(C), pages 350-360.
    12. Arteaga-Pérez, Luis E. & Segura, Cristina & Bustamante-García, Verónica & Gómez Cápiro, Oscar & Jiménez, Romel, 2015. "Torrefaction of wood and bark from Eucalyptus globulus and Eucalyptus nitens: Focus on volatile evolution vs feasible temperatures," Energy, Elsevier, vol. 93(P2), pages 1731-1741.
    13. Tsai, Wen-Tien & Lin, Yu-Quan & Tsai, Chi-Hung & Chung, Mei-Hua & Chu, Ming-Hung & Huang, Hung-Ju & Jao, Ya-Hsuan & Yeh, Showin-Ing, 2020. "Conversion of water caltrop husk into torrefied biomass by torrefaction," Energy, Elsevier, vol. 195(C).
    14. Rodriguez Alonso, Elvira & Dupont, Capucine & Heux, Laurent & Da Silva Perez, Denilson & Commandre, Jean-Michel & Gourdon, Christophe, 2016. "Study of solid chemical evolution in torrefaction of different biomasses through solid-state 13C cross-polarization/magic angle spinning NMR (nuclear magnetic resonance) and TGA (thermogravimetric ana," Energy, Elsevier, vol. 97(C), pages 381-390.
    15. Leontiev, Alexandr & Kichatov, Boris & Korshunov, Alexey & Kiverin, Alexey & Medvetskaya, Natalia & Melnikova, Ksenia, 2018. "Oxidative torrefaction of briquetted birch shavings in the bentonite," Energy, Elsevier, vol. 165(PA), pages 303-313.
    16. Moya, Roger & Rodríguez-Zúñiga, Ana & Puente-Urbina, Allen & Gaitán-Álvarez, Johanna, 2018. "Study of light, middle and severe torrefaction and effects of extractives and chemical compositions on torrefaction process by thermogravimetric analysis in five fast-growing plantations of Costa Rica," Energy, Elsevier, vol. 149(C), pages 1-10.
    17. Dossow, Marcel & Dieterich, Vincent & Hanel, Andreas & Spliethoff, Hartmut & Fendt, Sebastian, 2021. "Improving carbon efficiency for an advanced Biomass-to-Liquid process using hydrogen and oxygen from electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).

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