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Solid–Gas Thermochemical Energy Storage Materials and Reactors for Low to High-Temperature Applications: A Concise Review

Author

Listed:
  • Anti Kur

    (Buildings, Energy and Environment Research Group, Faculty of Engineering, University of Nottingham, Nottingham NG7 2RD, UK)

  • Jo Darkwa

    (Buildings, Energy and Environment Research Group, Faculty of Engineering, University of Nottingham, Nottingham NG7 2RD, UK)

  • John Calautit

    (Buildings, Energy and Environment Research Group, Faculty of Engineering, University of Nottingham, Nottingham NG7 2RD, UK)

  • Rabah Boukhanouf

    (Buildings, Energy and Environment Research Group, Faculty of Engineering, University of Nottingham, Nottingham NG7 2RD, UK)

  • Mark Worall

    (Buildings, Energy and Environment Research Group, Faculty of Engineering, University of Nottingham, Nottingham NG7 2RD, UK)

Abstract

Thermochemical energy storage materials and reactors have been reviewed for a range of temperature applications. For low-temperature applications, magnesium chloride is found to be a suitable candidate at temperatures up to 100 °C, whereas calcium hydroxide is identified to be appropriate for medium-temperature storage applications, ranging from 400 °C up to 650 °C. For the high-temperature range (750–1050 °C), oxides of cobalt, manganese, and copper are found to have the redox behaviour required for thermochemical heat storage. However, some of these materials suffer from low thermal conductivities, agglomeration, and low cyclability and, therefore, require further improvements. The concept of enhancing thermal conductivities through additives such as nanomaterials has been encouraging. From an operational point of view, fluidized-bed reactors perform better than fixed- and moving-bed reactors due to better particle interactions. There is, however, a need for the reaction bed to be further developed toward achieving optimum heat and mass transfers. Agitated fluidized-bed reactors have shown encouraging results and are suggested for further exploration. A combination of appropriate computational tools can facilitate an in-depth understanding of bed dynamics.

Suggested Citation

  • Anti Kur & Jo Darkwa & John Calautit & Rabah Boukhanouf & Mark Worall, 2023. "Solid–Gas Thermochemical Energy Storage Materials and Reactors for Low to High-Temperature Applications: A Concise Review," Energies, MDPI, vol. 16(2), pages 1-35, January.
  • Handle: RePEc:gam:jeners:v:16:y:2023:i:2:p:756-:d:1029697
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    References listed on IDEAS

    as
    1. Nicole Carina Preisner & Inga Bürger & Michael Wokon & Marc Linder, 2020. "Numerical Investigations of a Counter-Current Moving Bed Reactor for Thermochemical Energy Storage at High Temperatures," Energies, MDPI, vol. 13(3), pages 1-22, February.
    2. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    3. Donkers, P.A.J. & Sögütoglu, L.C. & Huinink, H.P. & Fischer, H.R. & Adan, O.C.G., 2017. "A review of salt hydrates for seasonal heat storage in domestic applications," Applied Energy, Elsevier, vol. 199(C), pages 45-68.
    4. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    5. Pragya Jain & Viney Dixit & Ankur Jain & Onkar N. Srivastava & Jacques Huot, 2015. "Effect of Magnesium Fluoride on Hydrogenation Properties of Magnesium Hydride," Energies, MDPI, vol. 8(11), pages 1-11, November.
    6. N’Tsoukpoe, Kokouvi Edem & Schmidt, Thomas & Rammelberg, Holger Urs & Watts, Beatriz Amanda & Ruck, Wolfgang K.L., 2014. "A systematic multi-step screening of numerous salt hydrates for low temperature thermochemical energy storage," Applied Energy, Elsevier, vol. 124(C), pages 1-16.
    7. N’Tsoukpoe, Kokouvi Edem & Kuznik, Frédéric, 2021. "A reality check on long-term thermochemical heat storage for household applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    8. Michel, Benoit & Neveu, Pierre & Mazet, Nathalie, 2014. "Comparison of closed and open thermochemical processes, for long-term thermal energy storage applications," Energy, Elsevier, vol. 72(C), pages 702-716.
    9. Kant, K. & Pitchumani, R., 2022. "Advances and opportunities in thermochemical heat storage systems for buildings applications," Applied Energy, Elsevier, vol. 321(C).
    10. Paskevicius, M. & Sheppard, D.A. & Williamson, K. & Buckley, C.E., 2015. "Metal hydride thermal heat storage prototype for concentrating solar thermal power," Energy, Elsevier, vol. 88(C), pages 469-477.
    11. Watson, S.D. & Lomas, K.J. & Buswell, R.A., 2019. "Decarbonising domestic heating: What is the peak GB demand?," Energy Policy, Elsevier, vol. 126(C), pages 533-544.
    12. Solé, Aran & Martorell, Ingrid & Cabeza, Luisa F., 2015. "State of the art on gas–solid thermochemical energy storage systems and reactors for building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 386-398.
    13. Flegkas, S. & Birkelbach, F. & Winter, F. & Freiberger, N. & Werner, A., 2018. "Fluidized bed reactors for solid-gas thermochemical energy storage concepts - Modelling and process limitations," Energy, Elsevier, vol. 143(C), pages 615-623.
    14. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    15. Peng, Xinyue & Yao, Min & Root, Thatcher W. & Maravelias, Christos T., 2020. "Design and analysis of concentrating solar power plants with fixed-bed reactors for thermochemical energy storage," Applied Energy, Elsevier, vol. 262(C).
    16. Meroueh, Laureen & Yenduru, Karthik & Dasgupta, Arindam & Jiang, Duo & AuYeung, Nick, 2019. "Energy storage based on SrCO3 and Sorbents—A probabilistic analysis towards realizing solar thermochemical power plants," Renewable Energy, Elsevier, vol. 133(C), pages 770-786.
    17. Sun, Hao & Li, Yingjie & Yan, Xianyao & Zhao, Jianli & Wang, Zeyan, 2020. "Thermochemical energy storage performance of Al2O3/CeO2 co-doped CaO-based material under high carbonation pressure," Applied Energy, Elsevier, vol. 263(C).
    18. Saman Setoodeh Jahromy & Felix Birkelbach & Christian Jordan & Clemens Huber & Michael Harasek & Andreas Werner & Franz Winter, 2019. "Impact of Partial Pressure, Conversion, and Temperature on the Oxidation Reaction Kinetics of Cu 2 O to CuO in Thermochemical Energy Storage," Energies, MDPI, vol. 12(3), pages 1-15, February.
    19. Funayama, Shigehiko & Takasu, Hiroki & Kim, Seon Tae & Kato, Yukitaka, 2020. "Thermochemical storage performance of a packed bed of calcium hydroxide composite with a silicon-based ceramic honeycomb support," Energy, Elsevier, vol. 201(C).
    20. Nicole Carina Preisner & Marc Linder, 2020. "A Moving Bed Reactor for Thermochemical Energy Storage Based on Metal Oxides," Energies, MDPI, vol. 13(5), pages 1-20, March.
    21. Schmidt, Matthias & Gutierrez, Andrea & Linder, Marc, 2017. "Thermochemical energy storage with CaO/Ca(OH)2 – Experimental investigation of the thermal capability at low vapor pressures in a lab scale reactor," Applied Energy, Elsevier, vol. 188(C), pages 672-681.
    22. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    23. Meier, Anton & Bonaldi, Enrico & Cella, Gian Mario & Lipinski, Wojciech & Wuillemin, Daniel & Palumbo, Robert, 2004. "Design and experimental investigation of a horizontal rotary reactor for the solar thermal production of lime," Energy, Elsevier, vol. 29(5), pages 811-821.
    24. Zhao, Y.J. & Wang, R.Z. & Zhang, Y.N. & Yu, N., 2016. "Development of SrBr2 composite sorbents for a sorption thermal energy storage system to store low-temperature heat," Energy, Elsevier, vol. 115(P1), pages 129-139.
    25. Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    26. Zondag, Herbert & Kikkert, Benjamin & Smeding, Simon & Boer, Robert de & Bakker, Marco, 2013. "Prototype thermochemical heat storage with open reactor system," Applied Energy, Elsevier, vol. 109(C), pages 360-365.
    27. Chen, Xiaoyi & Jin, Xiaogang & Liu, Zhimin & Ling, Xiang & Wang, Yan, 2018. "Experimental investigation on the CaO/CaCO3 thermochemical energy storage with SiO2 doping," Energy, Elsevier, vol. 155(C), pages 128-138.
    28. Stylianos Flegkas & Felix Birkelbach & Franz Winter & Hans Groenewold & Andreas Werner, 2019. "Profitability Analysis and Capital Cost Estimation of a Thermochemical Energy Storage System Utilizing Fluidized Bed Reactors and the Reaction System MgO/Mg(OH) 2," Energies, MDPI, vol. 12(24), pages 1-16, December.
    29. Pan, Z.H. & Zhao, C.Y., 2017. "Gas–solid thermochemical heat storage reactors for high-temperature applications," Energy, Elsevier, vol. 130(C), pages 155-173.
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