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Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage

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  • Yan, J.
  • Zhao, C.Y.

Abstract

The CaO/Ca(OH)2 thermochemical heat storage system is a very promising method to realize solar thermal energy utilization and industrial waste heat recycling. In this study, a CaO/Ca(OH)2 test-bed is setup to investigate the heat storage and release processes. In the heat storage process of pure Ca(OH)2, a higher dehydration temperature results in a faster heat storage speed. In addition, the heat storage process of Li-doped Ca(OH)2 can obtain a faster heat storage speed and produce more thermal energy than that of pure Ca(OH)2. The results of the experiment show that the air can seriously affect the heat release process in a fixed-bed test. Therefore, the method of pumping out the air is used in this study to improve the heat release process. According to the results of the heat release experiment, a lower initial sample temperature can lead to a higher extent of the dehydration reaction. Furthermore, a higher vapor pressure obviously improves the heat release capacity.

Suggested Citation

  • Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    • Handle: RePEc:eee:appene:v:175:y:2016:i:c:p:277-284
    DOI: 10.1016/j.apenergy.2016.05.038
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    1. Shao, H. & Nagel, T. & Roßkopf, C. & Linder, M. & Wörner, A. & Kolditz, O., 2013. "Non-equilibrium thermo-chemical heat storage in porous media: Part 2 – A 1D computational model for a calcium hydroxide reaction system," Energy, Elsevier, vol. 60(C), pages 271-282.
    2. Gu, Zhenhua & Li, Kongzhai & Wang, Hua & Qing, Shan & Zhu, Xing & Wei, Yonggang & Cheng, Xianming & Yu, He & Cao, Yan, 2016. "Bulk monolithic Ce–Zr–Fe–O/Al2O3 oxygen carriers for a fixed bed scheme of the chemical looping combustion: Reactivity of oxygen carrier," Applied Energy, Elsevier, vol. 163(C), pages 19-31.
    3. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    4. Fernández, J.R. & Abanades, J.C., 2014. "Conceptual design of a Ni-based chemical looping combustion process using fixed-beds," Applied Energy, Elsevier, vol. 135(C), pages 309-319.
    5. Yan, T. & Wang, R.Z. & Li, T.X. & Wang, L.W. & Fred, Ishugah T., 2015. "A review of promising candidate reactions for chemical heat storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 13-31.
    6. Abedin, Ali Haji & Rosen, Marc A., 2012. "Assessment of a closed thermochemical energy storage using energy and exergy methods," Applied Energy, Elsevier, vol. 93(C), pages 18-23.
    7. Pan, Zhihao & Zhao, C.Y., 2015. "Dehydration/hydration of MgO/H2O chemical thermal storage system," Energy, Elsevier, vol. 82(C), pages 611-618.
    8. Zhang, Hui & Wang, Hong & Zhu, Xun & Qiu, Yong-Jun & Li, Kai & Chen, Rong & Liao, Qiang, 2013. "A review of waste heat recovery technologies towards molten slag in steel industry," Applied Energy, Elsevier, vol. 112(C), pages 956-966.
    9. Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2015. "CO2 capture at ambient temperature in a fixed bed with CaO-based sorbents," Applied Energy, Elsevier, vol. 140(C), pages 297-303.
    10. Koepf, E. & Villasmil, W. & Meier, A., 2016. "Pilot-scale solar reactor operation and characterization for fuel production via the Zn/ZnO thermochemical cycle," Applied Energy, Elsevier, vol. 165(C), pages 1004-1023.
    11. Nagel, T. & Shao, H. & Roßkopf, C. & Linder, M. & Wörner, A. & Kolditz, O., 2014. "The influence of gas–solid reaction kinetics in models of thermochemical heat storage under monotonic and cyclic loading," Applied Energy, Elsevier, vol. 136(C), pages 289-302.
    12. Stitou, Driss & Mazet, Nathalie & Mauran, Sylvain, 2012. "Experimental investigation of a solid/gas thermochemical storage process for solar air-conditioning," Energy, Elsevier, vol. 41(1), pages 261-270.
    13. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
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