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Lithium Hydroxide Reaction for Low Temperature Chemical Heat Storage: Hydration and Dehydration Reaction

Author

Listed:
  • Jun Li

    (Department of Chemical Engineering, Nagoya University, Nagoya, Aichi 464-8603, Japan)

  • Tao Zeng

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Noriyuki Kobayashi

    (Department of Chemical Engineering, Nagoya University, Nagoya, Aichi 464-8603, Japan)

  • Haotai Xu

    (Department of Chemical Engineering, Nagoya University, Nagoya, Aichi 464-8603, Japan)

  • Yu Bai

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Lisheng Deng

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Zhaohong He

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Hongyu Huang

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China)

Abstract

As a key parameter of a chemical heat storage material, the hydration and dehydration reaction characteristics of lithium hydroxide (LiOH) at pure vapor condition is unclear. In this study, we focused on the hydration reaction and dehydration process of LiOH at the pure vapor condition. The pressure–temperature diagram of LiOH equilibrium was measured. The hydration and dehydration of LiOH at various conditions have been experimentally investigated. The results show that the steam diffusion can be greatly enhanced at vacuum condition. A thin layer of LiOH is uniformly dispersed in the reactor, which can greatly increase the heat transfer between the LiOH material and reactor, leading to a higher hydration reaction rate of LiOH. Furthermore, the steam pressure, reaction temperature, and the particle size of LiOH can greatly influence the hydration reaction. A maximum hydration reaction rate of 80% is obtained under the conditions of 47 °C, steam pressure of 9 kPa, and particle size of 32–40 μm. LiOH exhibits a different reaction property at the condition of pure steam without air and below atmospheric pressure. A store and reaction condition of LiOH with isolation of air is recommended when apply LiOH as a heat storage material at low temperature.

Suggested Citation

  • Jun Li & Tao Zeng & Noriyuki Kobayashi & Haotai Xu & Yu Bai & Lisheng Deng & Zhaohong He & Hongyu Huang, 2019. "Lithium Hydroxide Reaction for Low Temperature Chemical Heat Storage: Hydration and Dehydration Reaction," Energies, MDPI, vol. 12(19), pages 1-13, September.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:19:p:3741-:d:272306
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    References listed on IDEAS

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