IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v161y2018icp955-962.html
   My bibliography  Save this article

Experimental identification and thermodynamic analysis of ammonia sorption equilibrium characteristics on halide salts

Author

Listed:
  • Wu, S.
  • Li, T.X.
  • Wang, R.Z.

Abstract

Solid–gas chemisorption based on metal ammine complexes is a kind of promising energy-saving and environment-friendly technology for various thermal engineering applications such as chemical heat pump, thermochemical energy storage, chemisorption refrigeration, etc. The accurate thermodynamic parameters of ammonia sorption on halide salts can allow a significant theoretical and experimental study on a solid–gas chemisorption system using halide salt–ammonia sorption working pairs. In this study, the thermodynamic properties of chemisorption between strontium chloride (SrCl2) and ammonia is firstly investigated by developing a facile methodology for sorption equilibrium measurement. The facile methodology involves the fabrication of incompact composite sorbent of expanded graphite/SrCl2 with high porosity and an optimized temperature-controlling method so as to weaken the adverse effect of heat and mass transfer on chemisorption and realize the chemical equilibrium and thermal quasi-equilibrium during the isobaric measurement process. Through the experimental measurement, the stoichiometric equations of chemisorption between SrCl2 and NH3 are updated, and thermodynamic parameters including reaction enthalpy, reaction entropy and hysteresis are identified. Similarly, the thermodynamic characteristics of chemisorption between ammonia and halide salts BaCl2, SrBr2, and MnCl2 are also investigated. The facile methodology is proved available for measuring the ammonia sorption equilibrium characteristics on halide salts. At last, the working performance of a cascade thermochemical energy storage system using four halides salts is analyzed based on the obtained thermodynamic parameters.

Suggested Citation

  • Wu, S. & Li, T.X. & Wang, R.Z., 2018. "Experimental identification and thermodynamic analysis of ammonia sorption equilibrium characteristics on halide salts," Energy, Elsevier, vol. 161(C), pages 955-962.
    • Handle: RePEc:eee:energy:v:161:y:2018:i:c:p:955-962
    DOI: 10.1016/j.energy.2018.07.129
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218314269
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.07.129?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. K. NagaMalleswara Rao & M. Ram Gopal & Souvik Bhattacharyya, 2015. "Analysis of a SrCl2–NH3 solid sorption refrigeration system," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 10(4), pages 365-373.
    2. Yan, T. & Wang, R.Z. & Li, T.X., 2018. "Experimental investigation on thermochemical heat storage using manganese chloride/ammonia," Energy, Elsevier, vol. 143(C), pages 562-574.
    3. Michel, Benoit & Neveu, Pierre & Mazet, Nathalie, 2014. "Comparison of closed and open thermochemical processes, for long-term thermal energy storage applications," Energy, Elsevier, vol. 72(C), pages 702-716.
    4. Li, Tingxian & Wang, Ruzhu & Kiplagat, Jeremiah K. & Kang, YongTae, 2013. "Performance analysis of an integrated energy storage and energy upgrade thermochemical solid–gas sorption system for seasonal storage of solar thermal energy," Energy, Elsevier, vol. 50(C), pages 454-467.
    5. Lu, Zisheng & Wang, Ruzhu & Gordeeva, Larisa, 2017. "Novel multi-step sorption-reaction energy storage cycles for air conditioning and temperature upgrading," Energy, Elsevier, vol. 118(C), pages 464-472.
    6. Sharma, Rakesh & Anil Kumar, E., 2017. "Study of ammoniated salts based thermochemical energy storage system with heat up-gradation: A thermodynamic approach," Energy, Elsevier, vol. 141(C), pages 1705-1716.
    7. Wang, R.Z. & Xia, Z.Z. & Wang, L.W. & Lu, Z.S. & Li, S.L. & Li, T.X. & Wu, J.Y. & He, S., 2011. "Heat transfer design in adsorption refrigeration systems for efficient use of low-grade thermal energy," Energy, Elsevier, vol. 36(9), pages 5425-5439.
    8. Li, T.X. & Wu, S. & Yan, T. & Xu, J.X. & Wang, R.Z., 2016. "A novel solid–gas thermochemical multilevel sorption thermal battery for cascaded solar thermal energy storage," Applied Energy, Elsevier, vol. 161(C), pages 1-10.
    9. N’Tsoukpoe, Kokouvi Edem & Osterland, Thomas & Opel, Oliver & Ruck, Wolfgang K.L., 2016. "Cascade thermochemical storage with internal condensation heat recovery for better energy and exergy efficiencies," Applied Energy, Elsevier, vol. 181(C), pages 562-574.
    10. Li, T.X. & Wu, S. & Yan, T. & Wang, R.Z. & Zhu, J., 2017. "Experimental investigation on a dual-mode thermochemical sorption energy storage system," Energy, Elsevier, vol. 140(P1), pages 383-394.
    11. Bao, Huashan & Ma, Zhiwei & Roskilly, Anthony Paul, 2017. "An optimised chemisorption cycle for power generation using low grade heat," Applied Energy, Elsevier, vol. 186(P3), pages 251-261.
    12. Yan, T. & Wang, R.Z. & Li, T.X. & Wang, L.W. & Fred, Ishugah T., 2015. "A review of promising candidate reactions for chemical heat storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 13-31.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Manente, Giovanni & Ding, Yulong & Sciacovelli, Adriano, 2021. "Organic Rankine cycles combined with thermochemical sorption heat transformers to enhance the power output from waste heat," Applied Energy, Elsevier, vol. 304(C).
    2. Yan, Ting & Zhang, Hong & Yu, Nan & Li, Dong & Pan, Q.W., 2022. "Performance of thermochemical adsorption heat storage system based on MnCl2-NH3 working pair," Energy, Elsevier, vol. 239(PD).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yan, Ting & Zhang, Hong & Yu, Nan & Li, Dong & Pan, Q.W., 2022. "Performance of thermochemical adsorption heat storage system based on MnCl2-NH3 working pair," Energy, Elsevier, vol. 239(PD).
    2. Mukherjee, Ankit & Pujari, Ankush Shankar & Shinde, Shraddha Nitin & Kashyap, Uddip & Kumar, Lalit & Subramaniam, Chandramouli & Saha, Sandip K., 2022. "Performance assessment of open thermochemical energy storage system for seasonal space heating in highly humid environment," Renewable Energy, Elsevier, vol. 201(P1), pages 204-223.
    3. Mehrabadi, Abbas & Farid, Mohammed, 2018. "New salt hydrate composite for low-grade thermal energy storage," Energy, Elsevier, vol. 164(C), pages 194-203.
    4. Li, T.X. & Xu, J.X. & Yan, T. & Wang, R.Z., 2016. "Development of sorption thermal battery for low-grade waste heat recovery and combined cold and heat energy storage," Energy, Elsevier, vol. 107(C), pages 347-359.
    5. An, G.L. & Wu, S.F. & Wang, L.W. & Zhang, C. & Zhang, B., 2022. "Comparative investigations of sorption/resorption/cascading cycles for long-term thermal energy storage," Applied Energy, Elsevier, vol. 306(PA).
    6. Jun Li & Tao Zeng & Noriyuki Kobayashi & Haotai Xu & Yu Bai & Lisheng Deng & Zhaohong He & Hongyu Huang, 2019. "Lithium Hydroxide Reaction for Low Temperature Chemical Heat Storage: Hydration and Dehydration Reaction," Energies, MDPI, vol. 12(19), pages 1-13, September.
    7. Clark, Ruby-Jean & Farid, Mohammed, 2022. "Experimental investigation into cascade thermochemical energy storage system using SrCl2-cement and zeolite-13X materials," Applied Energy, Elsevier, vol. 316(C).
    8. Alicia Crespo & Cèsar Fernández & Alvaro de Gracia & Andrea Frazzica, 2022. "Solar-Driven Sorption System for Seasonal Heat Storage under Optimal Control: Study for Different Climatic Zones," Energies, MDPI, vol. 15(15), pages 1-23, August.
    9. Zhu, F.Q. & Jiang, L. & Wang, L.W. & Wang, R.Z., 2016. "Experimental investigation on a MnCl2CaCl2NH3 resorption system for heat and refrigeration cogeneration," Applied Energy, Elsevier, vol. 181(C), pages 29-37.
    10. Cabeza, Luisa F. & Solé, Aran & Barreneche, Camila, 2017. "Review on sorption materials and technologies for heat pumps and thermal energy storage," Renewable Energy, Elsevier, vol. 110(C), pages 3-39.
    11. Ding, Zhixiong & Wu, Wei & Leung, Michael, 2021. "Advanced/hybrid thermal energy storage technology: material, cycle, system and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    12. Böhm, Hans & Lindorfer, Johannes, 2019. "Techno-economic assessment of seasonal heat storage in district heating with thermochemical materials," Energy, Elsevier, vol. 179(C), pages 1246-1264.
    13. Wu, S. & Li, T.X. & Yan, T. & Wang, R.Z., 2019. "Advanced thermochemical resorption heat transformer for high-efficiency energy storage and heat transformation," Energy, Elsevier, vol. 175(C), pages 1222-1233.
    14. Geilfuß, Kristina & Dawoud, Belal, 2020. "Analytical investigation of a zeolite-NaY-water adsorption heat and cold storage and its integration into a steam power process," Energy, Elsevier, vol. 195(C).
    15. Mehrabadi, Abbas & Crotet, Engie & Farid, Mohammed, 2018. "An innovative approach for storing low-grade thermal energy using liquid phase thermoreversible reaction," Applied Energy, Elsevier, vol. 222(C), pages 823-829.
    16. Dizaji, Hossein Beidaghy & Hosseini, Hannaneh, 2018. "A review of material screening in pure and mixed-metal oxide thermochemical energy storage (TCES) systems for concentrated solar power (CSP) applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 9-26.
    17. Jiang, L. & Liu, W. & Lin, Y.C. & Wang, R.Q. & Zhang, X.J. & Hu, M.K., 2022. "Hybrid thermochemical sorption seasonal storage for ultra-low temperature solar energy utilization," Energy, Elsevier, vol. 239(PB).
    18. Serge Nyallang Nyamsi & Mykhaylo Lototskyy & Ivan Tolj, 2020. "Optimal Design of Combined Two-Tank Latent and Metal Hydrides-Based Thermochemical Heat Storage Systems for High-Temperature Waste Heat Recovery," Energies, MDPI, vol. 13(16), pages 1-18, August.
    19. Jiang, Long & Gao, Jiao & Wang, Liwei & Wang, Ruzhu & Lu, Yiji & Roskilly, Anthony Paul, 2017. "Investigation on performance of multi-salt composite sorbents for multilevel sorption thermal energy storage," Applied Energy, Elsevier, vol. 190(C), pages 1029-1038.
    20. Yan, Ting & Kuai, Z.H. & Wu, S.F., 2020. "Experimental investigation on a MnCl2–SrCl2/NH3 thermochemical resorption heat storage system," Renewable Energy, Elsevier, vol. 147(P1), pages 874-883.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:161:y:2018:i:c:p:955-962. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.