IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v12y2019i6p1005-d214037.html
   My bibliography  Save this article

Effect of LaNi 3 Amorphous Alloy Nanopowders on the Performance and Hydrogen Storage Properties of MgH 2

Author

Listed:
  • M. Sherif El-Eskandarany

    (Nanotechnology and Advanced Materials Program, Energy and Building Research, Center, Kuwait Institute for Scientific Research, Safat 13109, Kuwait)

  • Maryam Saeed

    (Nanotechnology and Advanced Materials Program, Energy and Building Research, Center, Kuwait Institute for Scientific Research, Safat 13109, Kuwait)

  • Eissa Al-Nasrallah

    (Nanotechnology and Advanced Materials Program, Energy and Building Research, Center, Kuwait Institute for Scientific Research, Safat 13109, Kuwait)

  • Fahad Al-Ajmi

    (Nanotechnology and Advanced Materials Program, Energy and Building Research, Center, Kuwait Institute for Scientific Research, Safat 13109, Kuwait)

  • Mohammad Banyan

    (Nanotechnology and Advanced Materials Program, Energy and Building Research, Center, Kuwait Institute for Scientific Research, Safat 13109, Kuwait)

Abstract

Due to its affordable price, abundance, high storage capacity, low recycling coast, and easy processing, Mg metal is considered as a promising hydrogen storage material. However, the poor de/rehydrogenation kinetics and strong stability of MgH 2 must be improved before proposing this material for applications. Doping MgH 2 powders with one or more catalytic agents is one common approach leading to obvious improving on the behavior of MgH 2 . The present study was undertaken to investigate the effect of doping MgH 2 with 7 wt% of amorphous(a)-LaNi 3 nanopowders on hydrogenation/dehydrogenation behavior of the metal hydride powders. The results have shown that rod milling MgH 2 with a-LaNi 3 abrasive nanopowders led to disintegrate microscale-MgH 2 powders to nanolevel. The final nanocomposite product obtained after 50 h–100 h of rod milling revealed superior hydrogenation kinetics, indexed by short time (8 min) required to absorb 6 wt% of H 2 at 200 °C/10 bar. At 225 °C/200 mbar, nanocomposite powders revealed outstanding dehydrogenation kinetics, characterized by very short time (2 min) needed to release 6 wt% of H 2 . This new tailored solid-hydrogen storage system experienced long cycle-life-time (2000 h) at 225 °C without obeying to sever degradation on its kinetics and/or storage capacity.

Suggested Citation

  • M. Sherif El-Eskandarany & Maryam Saeed & Eissa Al-Nasrallah & Fahad Al-Ajmi & Mohammad Banyan, 2019. "Effect of LaNi 3 Amorphous Alloy Nanopowders on the Performance and Hydrogen Storage Properties of MgH 2," Energies, MDPI, vol. 12(6), pages 1-15, March.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:6:p:1005-:d:214037
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/12/6/1005/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/12/6/1005/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Lanzi, Elisa & Verdolini, Elena & Haščič, Ivan, 2011. "Efficiency-improving fossil fuel technologies for electricity generation: Data selection and trends," Energy Policy, Elsevier, vol. 39(11), pages 7000-7014.
    2. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    3. El-Eskandarany, M. Sherif & Al-Matrouk, H. & Shaban, Ehab & Al-Duweesh, Ahmed, 2015. "Superior catalytic effect of nanocrystalline big-cube Zr2Ni metastable phase for improving the hydrogen sorption/desorption kinetics and cyclability of MgH2 powders," Energy, Elsevier, vol. 91(C), pages 274-282.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. repec:spo:wpmain:info:hdl:2441/2qaasbmk6u8cj8maoa30ls1roi is not listed on IDEAS
    2. Chung, Kyong-Hwan, 2010. "High-pressure hydrogen storage on microporous zeolites with varying pore properties," Energy, Elsevier, vol. 35(5), pages 2235-2241.
    3. Rashed Kaiser & Ayesha Munira Chowdhury, 2025. "Hydrogen-Powered Marine Vessels: A Rewarding yet Challenging Route to Decarbonization," Clean Technol., MDPI, vol. 7(3), pages 1-29, August.
    4. Rasheed, Tahir & Ahmad, Rabia & Arishi, Ali, 2025. "Revolutionizing hydrogen production and storage: Harnessing the power of MXenes for a greener and sustainable future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 216(C).
    5. Nesta, Lionel & Verdolini, Elena & Vona, Francesco, "undated". "Threshold Policy Effects and Directed Technical Change in Energy Innovation," CSI: Climate and Sustainable Innovation 268731, Fondazione Eni Enrico Mattei (FEEM).
    6. Sukanta Mondal & Pratim Kumar Chattaraj, 2023. "Aromatic Clusters and Hydrogen Storage," Energies, MDPI, vol. 16(6), pages 1-18, March.
    7. Song, Yanwu & Zhang, Jinrui & Song, Yingkang & Fan, Xinran & Zhu, Yuqing & Zhang, Chen, 2020. "Can industry-university-research collaborative innovation efficiency reduce carbon emissions?," Technological Forecasting and Social Change, Elsevier, vol. 157(C).
    8. Im, Jingyeong & Kwon, Taeho & Lee, Seungho & Kim, Donghan & Cho, Hyungtae & Won, Wangyun & Gu, Boram, 2025. "Unveiling the impact of internal structure on boil-off gas generation in moving liquid hydrogen (LH2) transport trailer," Renewable and Sustainable Energy Reviews, Elsevier, vol. 216(C).
    9. Melaina, Marc W., 2007. "Turn of the century refueling: A review of innovations in early gasoline refueling methods and analogies for hydrogen," Energy Policy, Elsevier, vol. 35(10), pages 4919-4934, October.
    10. Joëlle Noailly & Roger Smeets, 2013. "Directing Technical Change from Fossil-Fuel to Renewable Energy Innovation: An Empirical Application Using Firm-Level Patent Data," CPB Discussion Paper 237, CPB Netherlands Bureau for Economic Policy Analysis.
    11. Toyoto Sato & Shin-ichi Orimo, 2021. "The Crystal Structures in Hydrogen Absorption Reactions of REMgNi 4 -Based Alloys (RE: Rare-Earth Metals)," Energies, MDPI, vol. 14(23), pages 1-10, December.
    12. Valentina Bosetti & Elena Verdolini, 2013. "Clean and Dirty International Technology Diffusion," Working Papers 2013.43, Fondazione Eni Enrico Mattei.
    13. Radu-George Ciocarlan & Judit Farrando-Perez & Daniel Arenas-Esteban & Maarten Houlleberghs & Luke L. Daemen & Yongqiang Cheng & Anibal J. Ramirez-Cuesta & Eric Breynaert & Johan Martens & Sara Bals &, 2024. "Tuneable mesoporous silica material for hydrogen storage application via nano-confined clathrate hydrate construction," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    14. Conti, C. & Mancusi, M.L. & Sanna-Randaccio, F. & Sestini, R. & Verdolini, E., 2018. "Transition towards a green economy in Europe: Innovation and knowledge integration in the renewable energy sector," Research Policy, Elsevier, vol. 47(10), pages 1996-2009.
    15. Sharma, Monikankana & N, Rakesh & Dasappa, S., 2016. "Solid oxide fuel cell operating with biomass derived producer gas: Status and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 450-463.
    16. Ádám Révész & Marcell Gajdics & Miratul Alifah & Viktória Kovács Kis & Erhard Schafler & Lajos Károly Varga & Stanislava Todorova & Tony Spassov & Marcello Baricco, 2022. "Thermal, Microstructural and Electrochemical Hydriding Performance of a Mg 65 Ni 20 Cu 5 Y 10 Metallic Glass Catalyzed by CNT and Processed by High-Pressure Torsion," Energies, MDPI, vol. 15(15), pages 1-15, August.
    17. Lijuan Yan & Yange Zhang & Jun Liu, 2019. "The Dissociation and Diffusion Features of H2 Molecule on Two Ti Atoms Doped Al(111) Surface," Biomedical Journal of Scientific & Technical Research, Biomedical Research Network+, LLC, vol. 16(3), pages 1-4, March.
    18. Joëlle Noailly & Roger Smeets, 2022. "Financing Energy Innovation: Internal Finance and the Direction of Technical Change," Environmental & Resource Economics, Springer;European Association of Environmental and Resource Economists, vol. 83(1), pages 145-169, September.
    19. Lazkano, Itziar & Nøstbakken, Linda & Pelli, Martino, 2017. "From fossil fuels to renewables: The role of electricity storage," European Economic Review, Elsevier, vol. 99(C), pages 113-129.
    20. Fan Li & Dong Liu & Ke Sun & Songheng Yang & Fangzheng Peng & Kexin Zhang & Guodong Guo & Yuan Si, 2024. "Towards a Future Hydrogen Supply Chain: A Review of Technologies and Challenges," Sustainability, MDPI, vol. 16(5), pages 1-36, February.
    21. Ádám Révész & Roman Paramonov & Tony Spassov & Marcell Gajdics, 2023. "Microstructure and Hydrogen Storage Performance of Ball-Milled MgH 2 Catalyzed by FeTi," Energies, MDPI, vol. 16(3), pages 1-14, January.

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:12:y:2019:i:6:p:1005-:d:214037. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.