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Thermal, Microstructural and Electrochemical Hydriding Performance of a Mg 65 Ni 20 Cu 5 Y 10 Metallic Glass Catalyzed by CNT and Processed by High-Pressure Torsion

Author

Listed:
  • Ádám Révész

    (Department of Materials Physics, Eötvös University, P.O. Box 32, H-1518 Budapest, Hungary)

  • Marcell Gajdics

    (Center of Energy Research, Hungarian Academy of Sciences, H-1121 Budapest, Hungary)

  • Miratul Alifah

    (Department of Materials Physics, Eötvös University, P.O. Box 32, H-1518 Budapest, Hungary)

  • Viktória Kovács Kis

    (Center of Energy Research, Hungarian Academy of Sciences, H-1121 Budapest, Hungary
    Department of Mineralogy, Eötvös University, Pázmány Péter Sétány 1/c, H-1119 Budapest, Hungary)

  • Erhard Schafler

    (Physics of Nanostructured Materials, Faculty of Physics, University of Vienna, A-1090 Vienna, Austria)

  • Lajos Károly Varga

    (Research Institute for Solid State Physics and Optics, Hungarian Academy of Sciences, P.O. Box 49, H-1525 Budapest, Hungary)

  • Stanislava Todorova

    (Department of Chemistry, University of Sofia “St. Kl. Ohridski”, 1164 Sofia, Bulgaria)

  • Tony Spassov

    (Department of Chemistry, University of Sofia “St. Kl. Ohridski”, 1164 Sofia, Bulgaria)

  • Marcello Baricco

    (Dipartimento di Chimica and NIS-INSTM, Università di Torino, Via P. Giuria 7, 10125 Torino, Italy)

Abstract

A Mg 65 Ni 20 Cu 5 Y 10 metallic glass was produced by melt spinning and was mixed with a 5 wt.% multiwall carbon nanotube additive in a high-energy ball mill. Subsequently, the composite mixture was exposed to high-pressure torsion deformation with different torsion numbers. Complimentary XRD and DSC experiments confirmed the exceptional structural and thermal stability of the amorphous phase against severe plastic deformation. Combined high-resolution transmission electron microscopy observations and fast Fourier transform analysis revealed deformation-induced Mg 2 Ni nanocrystals, together with the structural and morphological stability of the nanotubes. The electrochemical hydrogen discharge capacity of the severely deformed pure metallic glass was substantially lower than that of samples with the nanotube additive for several cycles. It was also established that the most deformed sample containing nanotubes exhibited a drastic breakdown in the electrochemical capacity after eight cycles.

Suggested Citation

  • Ádám Révész & Marcell Gajdics & Miratul Alifah & Viktória Kovács Kis & Erhard Schafler & Lajos Károly Varga & Stanislava Todorova & Tony Spassov & Marcello Baricco, 2022. "Thermal, Microstructural and Electrochemical Hydriding Performance of a Mg 65 Ni 20 Cu 5 Y 10 Metallic Glass Catalyzed by CNT and Processed by High-Pressure Torsion," Energies, MDPI, vol. 15(15), pages 1-15, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5710-:d:881594
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    References listed on IDEAS

    as
    1. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    2. Ádám Révész & Marcell Gajdics, 2021. "High-Pressure Torsion of Non-Equilibrium Hydrogen Storage Materials: A Review," Energies, MDPI, vol. 14(4), pages 1-22, February.
    3. Ádám Révész & Marcell Gajdics, 2021. "Improved H-Storage Performance of Novel Mg-Based Nanocomposites Prepared by High-Energy Ball Milling: A Review," Energies, MDPI, vol. 14(19), pages 1-31, October.
    4. Marcell Gajdics & Tony Spassov & Viktória Kovács Kis & Ferenc Béke & Zoltán Novák & Erhard Schafler & Ádám Révész, 2020. "Microstructural Investigation of Nanocrystalline Hydrogen-Storing Mg-Titanate Nanotube Composites Processed by High-Pressure Torsion," Energies, MDPI, vol. 13(3), pages 1-14, January.
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