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Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (I) Thermodynamic and Heat Transfer Properties

Author

Listed:
  • Julian Jepsen

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Strasse 1, 21502 Geesthacht, Germany)

  • Chiara Milanese

    (Pavia H2 Lab, Department of Chemistry, Physical Chemistry Division, University of Pavia, Viale Taramelli 16, 27100 Pavia, Italy)

  • Julián Puszkiel

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Strasse 1, 21502 Geesthacht, Germany
    Department of Physicochemistry of Materials, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Centro Atómico Bariloche, Av. Bustillo km 9500, R8402AGP S.C. de Bariloche, Argentina)

  • Alessandro Girella

    (Pavia H2 Lab, Department of Chemistry, Physical Chemistry Division, University of Pavia, Viale Taramelli 16, 27100 Pavia, Italy)

  • Benedetto Schiavo

    (Dipartimento dell’Innovazione Industriale e Digitale (DIID)—Ingegneria Chimica Gestionale Informatica Meccanica, Università degli Studi di Palermo, Viale delle Scienze—Ed. 6, 90128 Palermo, Italy
    Istituto per le Tecnologie Avanzate (ITA), SS. 113 174, 91100 Trapani, Italy)

  • Gustavo A. Lozano

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Strasse 1, 21502 Geesthacht, Germany
    BASF SE, Carl Bosch Str 38, 67056 Ludwigshafen, Germany)

  • Giovanni Capurso

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Strasse 1, 21502 Geesthacht, Germany)

  • José M. Bellosta von Colbe

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Strasse 1, 21502 Geesthacht, Germany)

  • Amedeo Marini

    (Pavia H2 Lab, Department of Chemistry, Physical Chemistry Division, University of Pavia, Viale Taramelli 16, 27100 Pavia, Italy)

  • Stephan Kabelac

    (Institute for Thermodynamics, Leibniz Universität Hannover, Callinstraße 36, 30167 Hannover, Germany)

  • Martin Dornheim

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Strasse 1, 21502 Geesthacht, Germany)

  • Thomas Klassen

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Strasse 1, 21502 Geesthacht, Germany)

Abstract

Thermodynamic and heat transfer properties of the 2LiBH 4 -MgH 2 composite (Li-RHC) system are experimentally determined and studied as a basis for the design and development of hydrogen storage tanks. Besides the determination and discussion of the properties, different measurement methods are applied and compared to each other. Regarding thermodynamics, reaction enthalpy and entropy are determined by pressure-concentration-isotherms and coupled manometric-calorimetric measurements. For thermal diffusivity calculation, the specific heat capacity is measured by high-pressure differential scanning calorimetry and the effective thermal conductivity is determined by the transient plane source technique and in situ thermocell. Based on the results obtained from the thermodynamics and the assessment of the heat transfer properties, the reaction mechanism of the Li-RHC and the issues related to the scale-up for larger hydrogen storage systems are discussed in detail.

Suggested Citation

  • Julian Jepsen & Chiara Milanese & Julián Puszkiel & Alessandro Girella & Benedetto Schiavo & Gustavo A. Lozano & Giovanni Capurso & José M. Bellosta von Colbe & Amedeo Marini & Stephan Kabelac & Marti, 2018. "Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (I) Thermodynamic and Heat Transfer Properties," Energies, MDPI, vol. 11(5), pages 1-23, April.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:5:p:1081-:d:143641
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    References listed on IDEAS

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    1. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
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    Cited by:

    1. Vamsi Krishna Kukkapalli & Sunwoo Kim & Seth A. Thomas, 2023. "Thermal Management Techniques in Metal Hydrides for Hydrogen Storage Applications: A Review," Energies, MDPI, vol. 16(8), pages 1-27, April.
    2. Artem Chesalkin & Petr Kacor & Petr Moldrik, 2021. "Heat Transfer Optimization of NEXA Ballard Low-Temperature PEMFC," Energies, MDPI, vol. 14(8), pages 1-17, April.
    3. Hai Li & Xueteng Gao & Chongzhi Jia & Wan Chen & Bei Liu & Lanying Yang & Changyu Sun & Guangjin Chen, 2018. "Enrichment of Hydrogen from a Hydrogen/Propylene Gas Mixture Using ZIF-8/Water-Glycol Slurry," Energies, MDPI, vol. 11(7), pages 1-13, July.
    4. Julián Puszkiel & José M. Bellosta von Colbe & Julian Jepsen & Sergey V. Mitrokhin & Elshad Movlaev & Victor Verbetsky & Thomas Klassen, 2020. "Designing an AB 2 -Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept," Energies, MDPI, vol. 13(11), pages 1-26, June.
    5. Julian Jepsen & Chiara Milanese & Julián Puszkiel & Alessandro Girella & Benedetto Schiavo & Gustavo A. Lozano & Giovanni Capurso & José M. Bellosta von Colbe & Amedeo Marini & Stephan Kabelac & Marti, 2018. "Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties," Energies, MDPI, vol. 11(5), pages 1-15, May.

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