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Designing an AB 2 -Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept

Author

Listed:
  • Julián Puszkiel

    (Department of System Development, Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany
    Department of Physicochemistry of Materials, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Bariloche R8402AGP, Argentina
    Department of Advanced of Materials, IREC Catalonia Institute for Energy Research, 08930 Barcelona, Spain)

  • José M. Bellosta von Colbe

    (Department of System Development, Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • Julian Jepsen

    (Department of System Development, Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany
    Materials Technology, Helmut Schmidt University, Holstenhofweg 85, 22043 Hamburg, Germany)

  • Sergey V. Mitrokhin

    (Chemistry Department, Lomonosov Moscow State University, 119992 Moscow, Russia)

  • Elshad Movlaev

    (Chemistry Department, Lomonosov Moscow State University, 119992 Moscow, Russia)

  • Victor Verbetsky

    (Chemistry Department, Lomonosov Moscow State University, 119992 Moscow, Russia)

  • Thomas Klassen

    (Department of System Development, Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany
    Materials Technology, Helmut Schmidt University, Holstenhofweg 85, 22043 Hamburg, Germany)

Abstract

The hybrid hydrogen storage method consists of the combination of both solid-state metal hydrides and gas hydrogen storage. This method is regarded as a promising trade-off solution between the already developed high-pressure storage reservoir, utilized in the automobile industry, and solid-state storage through the formation of metal hydrides. Therefore, it is possible to lower the hydrogen pressure and to increase the hydrogen volumetric density. In this work, we design a non-stoichiometric AB 2 C14-Laves alloy composed of (Ti 0.9 Zr 0.1 ) 1.25 Cr 0.85 Mn 1.1 Mo 0.05 . This alloy is synthesized by arc-melting, and the thermodynamic and kinetic behaviors are evaluated in a high-pressure Sieverts apparatus. Proper thermodynamic parameters are obtained in the range of temperature and pressure from 3 to 85 °C and from 15 to 500 bar: ΔH abs. = 22 ± 1 kJ/mol H 2 , ΔS abs. = 107 ± 2 J/K mol H 2 , and ΔH des. = 24 ± 1 kJ/mol H 2 , ΔS des. = 110 ± 3 J/K mol H 2 . The addition of 10 wt.% of expanded natural graphite (ENG) allows the improvement of the heat transfer properties, showing a reversible capacity of about 1.5 wt.%, cycling stability and hydrogenation/dehydrogenation times between 25 to 70 s. The feasibility for the utilization of the designed material in a high-pressure tank is also evaluated, considering practical design parameters.

Suggested Citation

  • Julián Puszkiel & José M. Bellosta von Colbe & Julian Jepsen & Sergey V. Mitrokhin & Elshad Movlaev & Victor Verbetsky & Thomas Klassen, 2020. "Designing an AB 2 -Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept," Energies, MDPI, vol. 13(11), pages 1-26, June.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:11:p:2751-:d:365573
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    References listed on IDEAS

    as
    1. Julian Jepsen & Chiara Milanese & Julián Puszkiel & Alessandro Girella & Benedetto Schiavo & Gustavo A. Lozano & Giovanni Capurso & José M. Bellosta von Colbe & Amedeo Marini & Stephan Kabelac & Marti, 2018. "Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (I) Thermodynamic and Heat Transfer Properties," Energies, MDPI, vol. 11(5), pages 1-23, April.
    2. Pragya Jain & Viney Dixit & Ankur Jain & Onkar N. Srivastava & Jacques Huot, 2015. "Effect of Magnesium Fluoride on Hydrogenation Properties of Magnesium Hydride," Energies, MDPI, vol. 8(11), pages 1-11, November.
    3. Julian Jepsen & Chiara Milanese & Julián Puszkiel & Alessandro Girella & Benedetto Schiavo & Gustavo A. Lozano & Giovanni Capurso & José M. Bellosta von Colbe & Amedeo Marini & Stephan Kabelac & Marti, 2018. "Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties," Energies, MDPI, vol. 11(5), pages 1-15, May.
    4. Ewa C. E. Rönnebro & Greg Whyatt & Michael Powell & Matthew Westman & Feng (Richard) Zheng & Zhigang Zak Fang, 2015. "Metal Hydrides for High-Temperature Power Generation," Energies, MDPI, vol. 8(8), pages 1-25, August.
    5. Kasper T. Møller & Drew Sheppard & Dorthe B. Ravnsbæk & Craig E. Buckley & Etsuo Akiba & Hai-Wen Li & Torben R. Jensen, 2017. "Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage," Energies, MDPI, vol. 10(10), pages 1-30, October.
    6. Serge Nyallang Nyamsi & Ivan Tolj & Mykhaylo Lototskyy, 2019. "Metal Hydride Beds-Phase Change Materials: Dual Mode Thermal Energy Storage for Medium-High Temperature Industrial Waste Heat Recovery," Energies, MDPI, vol. 12(20), pages 1-27, October.
    7. Sebastiano Garroni & Antonio Santoru & Hujun Cao & Martin Dornheim & Thomas Klassen & Chiara Milanese & Fabiana Gennari & Claudio Pistidda, 2018. "Recent Progress and New Perspectives on Metal Amide and Imide Systems for Solid-State Hydrogen Storage," Energies, MDPI, vol. 11(5), pages 1-28, April.
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