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Metal Hydrides for High-Temperature Power Generation

Author

Listed:
  • Ewa C. E. Rönnebro

    (Pacific Northwest National Laboratory, Richland, WA 99352, USA)

  • Greg Whyatt

    (Pacific Northwest National Laboratory, Richland, WA 99352, USA)

  • Michael Powell

    (Pacific Northwest National Laboratory, Richland, WA 99352, USA)

  • Matthew Westman

    (Pacific Northwest National Laboratory, Richland, WA 99352, USA)

  • Feng (Richard) Zheng

    (Pacific Northwest National Laboratory, Richland, WA 99352, USA)

  • Zhigang Zak Fang

    (Department of Metallurgical Engineering, University of Utah, 135 S. 1460 E., Room 412, Salt Lake City, UT 84112, USA)

Abstract

Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later, which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600–800 °C to generate heat, as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is the need to produce electricity, such as during night time, a cloudy day or during peak hours. We proceeded from selecting a high-energy density HT-hydride based on performance characterization on gram-sized samples scaled up to kilogram quantities with retained performance. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a ~200-kWh/m 3 bench-scale prototype was designed and fabricated, and we demonstrated the ability to meet or exceed all performance targets.

Suggested Citation

  • Ewa C. E. Rönnebro & Greg Whyatt & Michael Powell & Matthew Westman & Feng (Richard) Zheng & Zhigang Zak Fang, 2015. "Metal Hydrides for High-Temperature Power Generation," Energies, MDPI, vol. 8(8), pages 1-25, August.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:8:p:8406-8430:d:53961
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    References listed on IDEAS

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    1. Meng, Xiangyu & Yang, Fusheng & Bao, Zewei & Deng, Jianqiang & Serge, Nyallang N. & Zhang, Zaoxiao, 2010. "Theoretical study of a novel solar trigeneration system based on metal hydrides," Applied Energy, Elsevier, vol. 87(6), pages 2050-2061, June.
    2. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
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    Cited by:

    1. Qi Xia & Shuaiming Feng & Mingmin Kong & Chen Chen, 2021. "Efficiency Enhancement of an Ammonia-Based Solar Thermochemical Energy Storage System Implemented with Hydrogen Permeation Membrane," Sustainability, MDPI, vol. 13(22), pages 1-13, November.
    2. Anggito P. Tetuko & Bahman Shabani & John Andrews, 2018. "Passive Fuel Cell Heat Recovery Using Heat Pipes to Enhance Metal Hydride Canisters Hydrogen Discharge Rate: An Experimental Simulation," Energies, MDPI, vol. 11(4), pages 1-19, April.
    3. Bruce J. Hardy & Claudio Corgnale & Stephanie N. Gamble, 2021. "Operating Characteristics of Metal Hydride-Based Solar Energy Storage Systems," Sustainability, MDPI, vol. 13(21), pages 1-14, November.
    4. Baigorri, Javier & Zaversky, Fritz & Astrain, David, 2023. "Massive grid-scale energy storage for next-generation concentrated solar power: A review of the potential emerging concepts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).
    5. Vamsi Krishna Kukkapalli & Sunwoo Kim, 2016. "Optimization of Internal Cooling Fins for Metal Hydride Reactors," Energies, MDPI, vol. 9(6), pages 1-12, June.
    6. Dizaji, Hossein Beidaghy & Hosseini, Hannaneh, 2018. "A review of material screening in pure and mixed-metal oxide thermochemical energy storage (TCES) systems for concentrated solar power (CSP) applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 9-26.
    7. Malleswararao, K. & Aswin, N. & Srinivasa Murthy, S. & Dutta, Pradip, 2022. "Studies on long-term and buffer modes of operations of a thermal energy storage system using coupled metal hydrides," Energy, Elsevier, vol. 258(C).
    8. Arias, I. & Cardemil, J. & Zarza, E. & Valenzuela, L. & Escobar, R., 2022. "Latest developments, assessments and research trends for next generation of concentrated solar power plants using liquid heat transfer fluids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    9. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Rood, Mark, 2017. "Thermal energy storage systems for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 82-100.
    10. Craig M. Jensen & Etsuo Akiba & Hai-Wen Li, 2016. "Hydrides: Fundamentals and Applications," Energies, MDPI, vol. 9(4), pages 1-2, April.
    11. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    12. Julián Puszkiel & José M. Bellosta von Colbe & Julian Jepsen & Sergey V. Mitrokhin & Elshad Movlaev & Victor Verbetsky & Thomas Klassen, 2020. "Designing an AB 2 -Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept," Energies, MDPI, vol. 13(11), pages 1-26, June.
    13. Kasper T. Møller & Drew Sheppard & Dorthe B. Ravnsbæk & Craig E. Buckley & Etsuo Akiba & Hai-Wen Li & Torben R. Jensen, 2017. "Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage," Energies, MDPI, vol. 10(10), pages 1-30, October.

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