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Hydrogenation Ability of Mg-Li Alloys

Author

Listed:
  • Magda Pęska

    (Institute of Materials Science and Engineering, Faculty of Advanced Technology and Chemistry, Military University of Technology, Kaliskiego 2 Street, 00-908 Warszawa, Poland)

  • Tomasz Czujko

    (Institute of Materials Science and Engineering, Faculty of Advanced Technology and Chemistry, Military University of Technology, Kaliskiego 2 Street, 00-908 Warszawa, Poland)

  • Marek Polański

    (Institute of Materials Science and Engineering, Faculty of Advanced Technology and Chemistry, Military University of Technology, Kaliskiego 2 Street, 00-908 Warszawa, Poland)

Abstract

The Mg-Li binary system is characterized by the presence of α-Mg(Li) and β-Li(Mg) phases, where magnesium exists in ordered and disordered forms that may affect the hydrogenation properties of magnesium. Therefore, the hydrogenation properties of an AZ31 alloy modified by the addition of 4.0 wt.%, 7.5 wt.% and 15.0 wt.% lithium were studied. The morphology (scanning electron microscopy (SEM)), structure, phase composition (X-ray diffraction (XRD)) and hydrogenation properties (differential scanning calorimetry (DSC)) of AZ31 with various lithium contents were investigated. It was found that the susceptibility of magnesium in the form of α-Mg(Li) to hydrogenation was higher than that for the magnesium occupying a disordered position in β-Li(Mg) solid solutions. Magnesium hydride was obtained as a result of hydrogenation of the AZ31 alloy that was modified with 4.0 wt.%, 7.5 wt.% and 15.0 wt.% additions of lithium, and was characterized by high hydrogen desorption activation energies of 250, 187 and 224 kJ/mol, respectively.

Suggested Citation

  • Magda Pęska & Tomasz Czujko & Marek Polański, 2020. "Hydrogenation Ability of Mg-Li Alloys," Energies, MDPI, vol. 13(8), pages 1-11, April.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:8:p:2080-:d:348499
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    References listed on IDEAS

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    1. Hai-Wen Li & Yigang Yan & Shin-ichi Orimo & Andreas Züttel & Craig M. Jensen, 2011. "Recent Progress in Metal Borohydrides for Hydrogen Storage," Energies, MDPI, vol. 4(1), pages 1-30, January.
    2. Kasper T. Møller & Drew Sheppard & Dorthe B. Ravnsbæk & Craig E. Buckley & Etsuo Akiba & Hai-Wen Li & Torben R. Jensen, 2017. "Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage," Energies, MDPI, vol. 10(10), pages 1-30, October.
    3. Momirlan, M. & Veziroglu, T. N., 2002. "Current status of hydrogen energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 6(1-2), pages 141-179.
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