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Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review

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  • Pattanaik, Bhabani Prasanna
  • Misra, Rahul Dev

Abstract

Growing demand for fossil fuels and related environmental issues have directed global attention towards development of alternative fuels from renewable sources. In this regard, biodiesel synthesized from vegetable oils and animal fats has shown potential as alternative to diesel fuel owing to its comparable fuel properties and combustion characteristics. However, higher oxygen content in biodiesel has raised some technical issues for its long term utilization in engines. Subsequently, the second generation liquid hydrocarbon fuels are being developed via catalytic deoxygenation of fatty acids present in vegetable oils. Presently, the research focus is on the pathways for catalytic deoxygenation like hydrodeoxygenation, decarboxylation, and decarbonylation. In hydrodeoxygenation, use of hydrogen gas and sulfided metal catalysts ensure higher conversion of vegetable oil into hydrocarbon fuel compared to the other two pathways. On the contrary, decarboxylation and decarbonylation are mostly hydrogen-free processes ensuring economical production of hydrocarbon fuel from vegetable oils. Hence, the techno-economical issues related to deoxygenation process need to be addressed for its commercial viability. Further, key operating parameters like nature of catalysts and supports, catalyst amount, reaction temperature, reaction atmosphere, hydrogen partial pressure, feed type, feed rate, type of solvent, H2/fatty acid molar ratio etc. are reported to have substantial influence on the hydrocarbon yield and selectivity. This review paper expounds a comparative assessment on the various deoxygenation pathways with their reaction mechanisms to opt for the suitable pathway for conversion of vegetable oils into hydrocarbon fuels based on yield and selectivity of the desired product, ease of use, economy etc. It also explicates the influence of various operating parameters to obtain optimum hydrocarbon conversion and selectivity during catalytic deoxygenation of vegetable oils and related feedstock.

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  • Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    • Handle: RePEc:eee:rensus:v:73:y:2017:i:c:p:545-557
    DOI: 10.1016/j.rser.2017.01.018
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    1. Damartzis, T. & Zabaniotou, A., 2011. "Thermochemical conversion of biomass to second generation biofuels through integrated process design--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 366-378, January.
    2. Mohammad, Masita & Kandaramath Hari, Thushara & Yaakob, Zahira & Chandra Sharma, Yogesh & Sopian, Kamaruzzaman, 2013. "Overview on the production of paraffin based-biofuels via catalytic hydrodeoxygenation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 121-132.
    3. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    4. Kwon, Kyung C. & Mayfield, Howard & Marolla, Ted & Nichols, Bob & Mashburn, Mike, 2011. "Catalytic deoxygenation of liquid biomass for hydrocarbon fuels," Renewable Energy, Elsevier, vol. 36(3), pages 907-915.
    5. Naik, S.N. & Goud, Vaibhav V. & Rout, Prasant K. & Dalai, Ajay K., 2010. "Production of first and second generation biofuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 578-597, February.
    6. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2014. "Transesterification of crude Jatropha oil by activated carbon-supported heteropolyacid catalyst in an ultrasound-assisted reactor system," Renewable Energy, Elsevier, vol. 62(C), pages 10-17.
    7. Na, Jeong-Geol & Yi, Bo Eun & Han, Jun Kyu & Oh, You-Kwan & Park, Jong-Ho & Jung, Tae Sung & Han, Sang Sup & Yoon, Hyung Chul & Kim, Jong-Nam & Lee, Hyunjoo & Ko, Chang Hyun, 2012. "Deoxygenation of microalgal oil into hydrocarbon with precious metal catalysts: Optimization of reaction conditions and supports," Energy, Elsevier, vol. 47(1), pages 25-30.
    8. Anselm Eisentraut, 2010. "Sustainable Production of Second-Generation Biofuels: Potential and Perspectives in Major Economies and Developing Countries," IEA Energy Papers 2010/1, OECD Publishing.
    9. Li, Shiwu & Wang, Yunpeng & Dong, Shengwu & Chen, Yang & Cao, Fenghua & Chai, Fang & Wang, Xiaohong, 2009. "Biodiesel production from Eruca Sativa Gars vegetable oil and motor, emissions properties," Renewable Energy, Elsevier, vol. 34(7), pages 1871-1876.
    10. Sawangkeaw, Ruengwit & Ngamprasertsith, Somkiat, 2013. "A review of lipid-based biomasses as feedstocks for biofuels production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 97-108.
    11. Fatih Demirbas, M., 2009. "Biorefineries for biofuel upgrading: A critical review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 151-161, November.
    12. Bezergianni, Stella & Dimitriadis, Athanasios, 2013. "Comparison between different types of renewable diesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 110-116.
    Full references (including those not matched with items on IDEAS)

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