IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v241y2025ics0960148124023474.html
   My bibliography  Save this article

Tailoring nickel precursors on red mud supports for catalytic hydrodeoxygenation of palmitic acid towards green diesel production

Author

Listed:
  • Duan, Jinyi
  • Chen, Sicheng
  • Yao, Quan
  • Wu, Kaiyue
  • Luo, Fenqiang
  • Wang, Dechao
  • Liu, Peng
  • Jiang, Jianchun
  • Zheng, Zhifeng

Abstract

Active metals, especially nickel, play a crucial role in the hydrodeoxygenation (HDO) reaction for green diesel production. However, the choice of nickel precursor significantly impacts the catalytic effect. This study investigates the catalytic performance of six nickel precursors (nickel acetylacetonate, nickel acetate, nickel chloride, nickel carbonate, nickel nitrate, and nickel oxide) supported on red mud (RM) using palmitic acid as a model compound. The results demonstrate that nickel nitrate RM catalyst (Ni-N/RM) and nickel carbonate RM catalyst (Ni-C/RM) exhibit distinct behaviors. Ni-N/RM favors the HDO pathway, yielding cetane, while Ni-C/RM prefers the decarbonylation (DCO) and decarboxylation (DCO₂) pathways, producing pentadecane. Ni-N/RM also shows high stability, with an 81 % conversion rate after six cycles. These findings emphasize the significance of selecting the appropriate nickel precursor in determining the catalytic behavior and product distribution in green diesel production.

Suggested Citation

  • Duan, Jinyi & Chen, Sicheng & Yao, Quan & Wu, Kaiyue & Luo, Fenqiang & Wang, Dechao & Liu, Peng & Jiang, Jianchun & Zheng, Zhifeng, 2025. "Tailoring nickel precursors on red mud supports for catalytic hydrodeoxygenation of palmitic acid towards green diesel production," Renewable Energy, Elsevier, vol. 241(C).
    • Handle: RePEc:eee:renene:v:241:y:2025:i:c:s0960148124023474
    DOI: 10.1016/j.renene.2024.122279
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148124023474
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2024.122279?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    2. Li, Xiangping & Chen, Lei & Chen, Guanyi & Zhang, Jianguang & Liu, Juping, 2020. "The relationship between acidity, dispersion of nickel, and performance of Ni/Al-SBA-15 catalyst on eugenol hydrodeoxygenation," Renewable Energy, Elsevier, vol. 149(C), pages 609-616.
    3. Yoosuk, Boonyawan & Sanggam, Paphawee & Wiengket, Sakdipat & Prasassarakich, Pattarapan, 2019. "Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 139(C), pages 1391-1399.
    4. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    5. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Xingyong & Wu, Yankun & Wang, Qi & Li, Shuirong & Ye, Yueyuan & Wang, Dechao & Zheng, Zhifeng, 2022. "Effect of preparation method of NiMo/γ-Al2O3 on the FAME hydrotreatment to produce C15–C18 alkanes," Renewable Energy, Elsevier, vol. 193(C), pages 1-12.
    2. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    3. Ooi, Xian Yih & Gao, Wei & Ong, Hwai Chyuan & Lee, Hwei Voon & Juan, Joon Ching & Chen, Wei Hsin & Lee, Keat Teong, 2019. "Overview on catalytic deoxygenation for biofuel synthesis using metal oxide supported catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 834-852.
    4. Cao, Xincheng & Long, Feng & Wang, Fei & Zhao, Jiaping & Xu, Junming & Jiang, Jianchun, 2021. "Chemoselective decarboxylation of higher aliphatic esters to diesel-range alkanes over the NiCu/Al2O3 bifunctional catalyst under mild reaction conditions," Renewable Energy, Elsevier, vol. 180(C), pages 1-13.
    5. Why, Elaine Siew Kuan & Ong, Hwai Chyuan & Lee, Hwei Voon & Chen, Wei-Hsin & Asikin-Mijan, N. & Varman, Mahendra & Loh, Wen Jing, 2022. "Single-step catalytic deoxygenation of palm feedstocks for the production of sustainable bio-jet fuel," Energy, Elsevier, vol. 239(PB).
    6. Xing, Shiyou & Fu, Junying & Li, Ming & Yang, Gaixiu & Lv, Pengmei, 2024. "Emerging catalysis in solvent-free hydrodeoxygenation of waste lipids under mild conditions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 200(C).
    7. Golubeva, M.A. & Maximov, A.L., 2025. "Transition metal compounds in the hydrodeoxygenation of biomass derivatives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 210(C).
    8. Cabrera-Jiménez, Richard & Mateo, Josep Maria & Jiménez, Laureano & Pozo, Carlos, 2025. "Prospective life-cycle assessment of sustainable alternatives for road freight transport," Renewable and Sustainable Energy Reviews, Elsevier, vol. 211(C).
    9. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    10. Ounsuk, Patravee & Prapainainar, Chaiwat & Hongloi, Nitchakul & Sudsakorn, Kandis & Lalitpattarakit, Montida & Seubsai, Anusorn & Kiatkittipong, Worapon & Wongsakulphasatch, Suwimol & Assabumrungrat, , 2024. "Box-Behnken design optimizing operating conditions in bio-hydrogenated diesel production by using BHD product as a solvent," Renewable Energy, Elsevier, vol. 232(C).
    11. Long, Feng & Zhai, Qiaolong & Liu, Peng & Cao, Xincheng & Jiang, Xia & Wang, Fei & Wei, Linshan & Liu, Chao & Jiang, Jianchun & Xu, Junming, 2020. "Catalytic conversion of triglycerides by metal-based catalysts and subsequent modification of molecular structure by ZSM-5 and Raney Ni for the production of high-value biofuel," Renewable Energy, Elsevier, vol. 157(C), pages 1072-1080.
    12. Hafriz, R.S.R.M. & Shafizah, I. Nor & Arifin, N.A. & Salmiaton, A. & Yunus, R. & Yap, Y.H. Taufiq & Shamsuddin, A.H., 2021. "Effect of Ni/Malaysian dolomite catalyst synthesis technique on deoxygenation reaction activity of waste cooking oil," Renewable Energy, Elsevier, vol. 178(C), pages 128-143.
    13. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    14. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.
    15. Hancsók, Jenő & Visnyei, Olivér & Holló, András & Leveles, László & Thernesz, Artur & Varga, Géza & Valyon, József, 2019. "Alternative diesel fuels with high hydrogen content in their molecular structures," Renewable Energy, Elsevier, vol. 142(C), pages 239-248.
    16. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    17. Li, Xingyong & Fan, Qiyuan & Wu, Kaiyue & Liu, Na & Zhang, Wei & Liu, Ying & Chen, Yubao & Cheng, Jun & Zheng, Zhifeng, 2024. "Enhancing catalytic isomerization ability of SAPO-11 by typical acid modification in preparation of green diesel by one-step hydrotreatment of FAME," Renewable Energy, Elsevier, vol. 224(C).
    18. Zheng, Yunwu & Wang, Jida & Liu, Can & Lu, Yi & Lin, Xu & Li, Wenbin & Zheng, Zhifeng, 2020. "Efficient and stable Ni-Cu catalysts for ex situ catalytic pyrolysis vapor upgrading of oleic acid into hydrocarbon: Effect of catalyst support, process parameters and Ni-to-Cu mixed ratio," Renewable Energy, Elsevier, vol. 154(C), pages 797-812.
    19. Marinič, Dana & Grilc, Miha & Hočevar, Brigita & Delrue, Florian & Likozar, Blaž, 2023. "Liquefaction, cracking and hydrogenation of microalgae biomass resources to CO2 negative advanced biofuels: Mechanisms, reaction microkinetics and modelling," Renewable Energy, Elsevier, vol. 203(C), pages 382-393.
    20. Tai, Lingyu & Hamidi, Roya & de Caprariis, Benedetta & Damizia, Martina & Paglia, Laura & Scarsella, Marco & Karimzadeh, Ramin & De Filippis, Paolo, 2022. "Guaiacol hydrotreating with in-situ generated hydrogen over ni/modified zeolite supports," Renewable Energy, Elsevier, vol. 182(C), pages 647-658.

    More about this item

    Keywords

    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:241:y:2025:i:c:s0960148124023474. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.