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Transition metal compounds in the hydrodeoxygenation of biomass derivatives

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  • Golubeva, M.A.
  • Maximov, A.L.

Abstract

Conventional hydroprocessing catalysts such as transition metal oxides and sulfides were compared to less widespread catalysts such as transition metal phosphides, carbides, and nitrides in the hydrodeoxygenation of biomass derivatives. Interest in using the three latter types of compounds as heterogeneous catalysts has increased significantly in the last 10–20 years. All these transition metal catalysts are united by the presence of active sites responsible for hydrogenation and hydrodeoxygenation. The activity in hydrodeoxygenation is determined by the presence of Lewis and Brønsted acid sites and anion vacancies in the catalysts, while the activity in hydrogenation is determined by the presence and availability of metal sites and the presence of anion vacancies. The catalysts investigated were found to have a great potential for the selective production of aromatic hydrocarbons, used as solvents and gasoline components; diesel-range hydrocarbons, and other valuable products. However, water formation during the hydroprocessing and coke deposition can lead to a reduction in catalyst activity.

Suggested Citation

  • Golubeva, M.A. & Maximov, A.L., 2025. "Transition metal compounds in the hydrodeoxygenation of biomass derivatives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 210(C).
    • Handle: RePEc:eee:rensus:v:210:y:2025:i:c:s1364032124008797
    DOI: 10.1016/j.rser.2024.115153
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    1. Signe S. Grønborg & Norberto Salazar & Albert Bruix & Jonathan Rodríguez-Fernández & Sean D. Thomsen & Bjørk Hammer & Jeppe V. Lauritsen, 2018. "Visualizing hydrogen-induced reshaping and edge activation in MoS2 and Co-promoted MoS2 catalyst clusters," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    2. Sajjadi, Baharak & Raman, Abdul Aziz Abdul & Arandiyan, Hamidreza, 2016. "A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: Composition, specifications and prediction models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 62-92.
    3. Elba Ochoa & Daniel Torres & José Luis Pinilla & Isabel Suelves, 2020. "Nanostructured Carbon Material Effect on the Synthesis of Carbon-Supported Molybdenum Carbide Catalysts for Guaiacol Hydrodeoxygenation," Energies, MDPI, vol. 13(5), pages 1-19, March.
    4. Norberto Salazar & Srinivas Rangarajan & Jonathan Rodríguez-Fernández & Manos Mavrikakis & Jeppe V. Lauritsen, 2020. "Site-dependent reactivity of MoS2 nanoparticles in hydrodesulfurization of thiophene," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    5. Cao, Xincheng & Long, Feng & Zhai, Qiaolong & Liu, Peng & Xu, Junming & Jiang, Jianchun, 2020. "Enhancement of fatty acids hydrodeoxygenation selectivity to diesel-range alkanes over the supported Ni-MoOx catalyst and elucidation of the active phase," Renewable Energy, Elsevier, vol. 162(C), pages 2113-2125.
    6. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    7. Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.
    8. Ramesh, Arumugam & Tamizhdurai, Perumal & Shanthi, Kannan, 2019. "Catalytic hydrodeoxygenation of jojoba oil to the green-fuel application on Ni-MoS/Mesoporous zirconia-silica catalysts," Renewable Energy, Elsevier, vol. 138(C), pages 161-173.
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