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Enhancing catalytic isomerization ability of SAPO-11 by typical acid modification in preparation of green diesel by one-step hydrotreatment of FAME

Author

Listed:
  • Li, Xingyong
  • Fan, Qiyuan
  • Wu, Kaiyue
  • Liu, Na
  • Zhang, Wei
  • Liu, Ying
  • Chen, Yubao
  • Cheng, Jun
  • Zheng, Zhifeng

Abstract

SAPO-11 molecular sieve is a promising candidate for preparation of hydrocarbon-based biofuels. Herein, two typical acids including citric acid (CA) and nitric acid (NA) are used to modify SAPO-11. The results show that the acid concentration was within the range of 0.05–1.0 mol L−1, SAPO-11 maintained a complete crystal framework structure, and more (002) crystal planes were exposed. The specific surface area, pore diameter and acid content of molecular sieve by acid modification are significantly higher than those of the fresh SAPO-11. The pore size increased from 7 nm to 17 and 18 nm, an increase of the total acid from 104 μmol g−1 to 174 and 162 μmol g−1, respectively, when SAPO-11 was treated by CA with 0.5 mol L−1 and NA with 0.3 mol L−1. Pt–Sn/SAPO-11-CA-0.5 showed the best catalytic activity with selectivity of C15–C18 alkanes of 95.8% and iso-alkanes of 33.1%. Additionally, the deoxygenation ability of Pt–Sn/SAPO-11-CA-0.5 decreased 30% after running 1200 h. Using propionic acid (PA) as the model probe molecule, the DFT reveals steps of the hydrodecarbonylation pathway of PA absorbed on the Pt (111) plane as below: CH3CH2COOH*→CH3CH2CO*→CH3CHCO*→CH3CCO*→CH3C*+CO*, and the rate-limiting step is CH3CH2COOH*→CH3CH2CO*+OH*.

Suggested Citation

  • Li, Xingyong & Fan, Qiyuan & Wu, Kaiyue & Liu, Na & Zhang, Wei & Liu, Ying & Chen, Yubao & Cheng, Jun & Zheng, Zhifeng, 2024. "Enhancing catalytic isomerization ability of SAPO-11 by typical acid modification in preparation of green diesel by one-step hydrotreatment of FAME," Renewable Energy, Elsevier, vol. 224(C).
    • Handle: RePEc:eee:renene:v:224:y:2024:i:c:s096014812400291x
    DOI: 10.1016/j.renene.2024.120226
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    1. Midttun, Atle & Khanieva, Marina & Lia, Magne & Wenner, Eivind, 2022. "The greening of the European petroleum industry," Energy Policy, Elsevier, vol. 167(C).
    2. Ho, Calvin K. & McAuley, Kimberley B. & Peppley, Brant A., 2019. "Biolubricants through renewable hydrocarbons: A perspective for new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    3. Ayoub, Muhammad & Abdullah, Ahmad Zuhairi, 2012. "Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2671-2686.
    4. Li, Xingyong & Chen, Yubao & Hao, Yajie & Zhang, Xu & Du, Junchen & Zhang, Aimin, 2019. "Optimization of aviation kerosene from one-step hydrotreatment of catalytic Jatropha oil over SDBS-Pt/SAPO-11 by response surface methodology," Renewable Energy, Elsevier, vol. 139(C), pages 551-559.
    5. Quaranta, Eugenio & Cornacchia, Daniele, 2020. "Partial hydrogenation of a C18:3-rich FAME mixture over Pd/C," Renewable Energy, Elsevier, vol. 157(C), pages 33-42.
    6. Long, Feng & Zhai, Qiaolong & Liu, Peng & Cao, Xincheng & Jiang, Xia & Wang, Fei & Wei, Linshan & Liu, Chao & Jiang, Jianchun & Xu, Junming, 2020. "Catalytic conversion of triglycerides by metal-based catalysts and subsequent modification of molecular structure by ZSM-5 and Raney Ni for the production of high-value biofuel," Renewable Energy, Elsevier, vol. 157(C), pages 1072-1080.
    7. Shahinuzzaman, M. & Yaakob, Zahira & Ahmed, Yunus, 2017. "Non-sulphide zeolite catalyst for bio-jet-fuel conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1375-1384.
    8. Cao, Xincheng & Long, Feng & Zhai, Qiaolong & Liu, Peng & Xu, Junming & Jiang, Jianchun, 2020. "Enhancement of fatty acids hydrodeoxygenation selectivity to diesel-range alkanes over the supported Ni-MoOx catalyst and elucidation of the active phase," Renewable Energy, Elsevier, vol. 162(C), pages 2113-2125.
    9. Liobikienė, Genovaitė & Matiiuk, Yuliia & Krikštolaitis, Ričardas, 2023. "The concern about main crises such as the Covid-19 pandemic, the war in Ukraine, and climate change's impact on energy-saving behavior," Energy Policy, Elsevier, vol. 180(C).
    10. Yang, Huiru & Du, Xiangze & Lei, Xiaomei & Zhou, Keyao & Tian, Yunfei & Li, Dan & Hu, Changwei, 2021. "Unraveling enhanced activity and coke resistance of Pt-based catalyst in bio-aviation fuel refining," Applied Energy, Elsevier, vol. 301(C).
    11. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    12. Teo, Siow Hwa & Islam, Aminul & Mansir, Nasar & Shamsuddin, Mohd Razali & Joseph, Collin G. & Goto, Motonobu & Taufiq-Yap, Yun Hin, 2022. "Sustainable biofuel production approach: Critical methanol green transesterification by efficient and stable heterogeneous catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    13. Wu, Yankun & Duan, Jinyi & Li, Xingyong & Wu, KaiYue & Wang, Jiacheng & Zheng, Jie & Li, Shuirong & Wang, Dechao & Zheng, Zhifeng, 2023. "Synthesis of Ni/SAPO-11-X zeolites with graded secondary pore structure and its catalytic performance for hydrodeoxygenation-isomerization of FAME for green diesel production," Renewable Energy, Elsevier, vol. 218(C).
    14. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    15. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    16. Abbasi, Kashif Raza & Shahbaz, Muhammad & Zhang, Jinjun & Irfan, Muhammad & Alvarado, Rafael, 2022. "Analyze the environmental sustainability factors of China: The role of fossil fuel energy and renewable energy," Renewable Energy, Elsevier, vol. 187(C), pages 390-402.
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