IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v139y2019icp1391-1399.html
   My bibliography  Save this article

Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts

Author

Listed:
  • Yoosuk, Boonyawan
  • Sanggam, Paphawee
  • Wiengket, Sakdipat
  • Prasassarakich, Pattarapan

Abstract

Second generation biodiesel, so-called bio-hydrogenated diesel (BHD), can be produced from hydrotreatment of vegetable oils. The hydrogenation (HDO) of oleic acid and palmitic acid as model compounds of palm oil over unsupported Ni-Mo and Co-Mo sulfide catalysts was performed in a Parr reactor to produce BHD. The effects of reaction parameters: temperature, hydrogen pressure and the atomic ratio of catalysts (Ni/(Ni + Mo) or Co/(Co + Mo)) on the conversion and product yields (mainly n-C15, n-C16, n-C17 and n-C18 hydrocarbons) were evaluated. The results show that the high pressure favored HDO pathway, while high temperature strongly affected the decarboxylation and decarbonylation pathways. At optimal conditions for oleic acid HDO, the efficient catalyst was NiMoS2 catalyst (Ni/(Ni + Mo) = 0.2) which gave high oleic acid conversion (100%), n-C18 selectivity (78.8%) and n-C18 yield (70.3%) whereas, for palmitic acid HDO, NiMoS2 catalyst (Ni/(Ni + Mo) = 0.2) also gave high palmitic acid conversion (95.2%), n-C16 selectivity (78.5%) and n-C16 yield (65.6%).

Suggested Citation

  • Yoosuk, Boonyawan & Sanggam, Paphawee & Wiengket, Sakdipat & Prasassarakich, Pattarapan, 2019. "Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 139(C), pages 1391-1399.
    • Handle: RePEc:eee:renene:v:139:y:2019:i:c:p:1391-1399
    DOI: 10.1016/j.renene.2019.03.030
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119303350
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.03.030?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    2. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Yasir, Madiha, 2017. "Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1072-1088.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Marinič, Dana & Grilc, Miha & Hočevar, Brigita & Delrue, Florian & Likozar, Blaž, 2023. "Liquefaction, cracking and hydrogenation of microalgae biomass resources to CO2 negative advanced biofuels: Mechanisms, reaction microkinetics and modelling," Renewable Energy, Elsevier, vol. 203(C), pages 382-393.
    2. Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.
    3. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    4. Li, Xingyong & Wu, Yankun & Wang, Qi & Li, Shuirong & Ye, Yueyuan & Wang, Dechao & Zheng, Zhifeng, 2022. "Effect of preparation method of NiMo/γ-Al2O3 on the FAME hydrotreatment to produce C15–C18 alkanes," Renewable Energy, Elsevier, vol. 193(C), pages 1-12.
    5. Cao, Xincheng & Long, Feng & Wang, Fei & Zhao, Jiaping & Xu, Junming & Jiang, Jianchun, 2021. "Chemoselective decarboxylation of higher aliphatic esters to diesel-range alkanes over the NiCu/Al2O3 bifunctional catalyst under mild reaction conditions," Renewable Energy, Elsevier, vol. 180(C), pages 1-13.
    6. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    7. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    2. Chen, Yu-Kai & Lin, Cheng-Han & Wang, Wei-Cheng, 2020. "The conversion of biomass into renewable jet fuel," Energy, Elsevier, vol. 201(C).
    3. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    4. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
    5. Resende, K.A. & Noronha, F.B. & Hori, C.E., 2020. "Hydrodeoxygenation of phenol over metal supported niobia catalysts," Renewable Energy, Elsevier, vol. 149(C), pages 198-207.
    6. Hafriz, R.S.R.M. & Shafizah, I. Nor & Arifin, N.A. & Salmiaton, A. & Yunus, R. & Yap, Y.H. Taufiq & Shamsuddin, A.H., 2021. "Effect of Ni/Malaysian dolomite catalyst synthesis technique on deoxygenation reaction activity of waste cooking oil," Renewable Energy, Elsevier, vol. 178(C), pages 128-143.
    7. Barbera, Elena & Naurzaliyev, Rustem & Asiedu, Alexander & Bertucco, Alberto & Resurreccion, Eleazer P. & Kumar, Sandeep, 2020. "Techno-economic analysis and life-cycle assessment of jet fuels production from waste cooking oil via in situ catalytic transfer hydrogenation," Renewable Energy, Elsevier, vol. 160(C), pages 428-449.
    8. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.
    9. Hancsók, Jenő & Visnyei, Olivér & Holló, András & Leveles, László & Thernesz, Artur & Varga, Géza & Valyon, József, 2019. "Alternative diesel fuels with high hydrogen content in their molecular structures," Renewable Energy, Elsevier, vol. 142(C), pages 239-248.
    10. Araújo, Aruzza Mabel de Morais & Lima, Regineide de Oliveira & Gondim, Amanda Duarte & Diniz, Juraci & Souza, Luiz Di & Araujo, Antonio Souza de, 2017. "Thermal and catalytic pyrolysis of sunflower oil using AlMCM-41," Renewable Energy, Elsevier, vol. 101(C), pages 900-906.
    11. Li, Xiangping & Chen, Guanyi & Liu, Caixia & Ma, Wenchao & Yan, Beibei & Zhang, Jianguang, 2017. "Hydrodeoxygenation of lignin-derived bio-oil using molecular sieves supported metal catalysts: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 296-308.
    12. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    13. Zheng, Yunwu & Wang, Jida & Liu, Can & Lu, Yi & Lin, Xu & Li, Wenbin & Zheng, Zhifeng, 2020. "Efficient and stable Ni-Cu catalysts for ex situ catalytic pyrolysis vapor upgrading of oleic acid into hydrocarbon: Effect of catalyst support, process parameters and Ni-to-Cu mixed ratio," Renewable Energy, Elsevier, vol. 154(C), pages 797-812.
    14. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Yasir, Madiha, 2017. "Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1072-1088.
    15. Chen, Bi-Shuang & Zeng, Yong-Yi & Liu, Lan & Chen, Lei & Duan, Peigao & Luque, Rafael & Ge, Ran & Zhang, Wuyuan, 2022. "Advances in catalytic decarboxylation of bioderived fatty acids to diesel-range alkanes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    16. Wang, Fei & Pace, Robert & Ji, Yaying & Jiang, Jianchun & Jiang, Xiaoxiang & Krystianiak, Anna & Heintz, Olivier & Caboche, Gilles & Santillan-Jimenez, Eduardo & Crocker, Mark, 2022. "Effect of Pd promotion and catalyst support on the Ni-catalyzed deoxygenation of tristearin to fuel-like hydrocarbons," Renewable Energy, Elsevier, vol. 195(C), pages 1468-1479.
    17. Ho, Calvin K. & McAuley, Kimberley B. & Peppley, Brant A., 2019. "Biolubricants through renewable hydrocarbons: A perspective for new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    18. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Shahbaz, Muhammad & Aqsha, Aqsha, 2020. "Process optimization of green diesel selectivity and understanding of reaction intermediates," Renewable Energy, Elsevier, vol. 149(C), pages 1092-1106.
    19. Thongkumkoon, Skonrach & Kiatkittipong, Worapon & Hartley, Unalome Wetwatana & Laosiripojana, Navadol & Daorattanachai, Pornlada, 2019. "Catalytic activity of trimetallic sulfided Re-Ni-Mo/γ-Al2O3 toward deoxygenation of palm feedstocks," Renewable Energy, Elsevier, vol. 140(C), pages 111-123.
    20. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:139:y:2019:i:c:p:1391-1399. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.